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acetamiprid
** acetamiprid ** ethanimidamide ** NI-25 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Acetamiprid is an insecticide that is currently approved for EU use. It is highly soluble in water and is volatile. Based on its chemical properties it would not be expected to leach to groundwater. It is not persistence in soil systems but may be very persistent in aquatic systems under certain conditions. It has a moderate mammalian toxicity and it has a high potential for bioaccumulation. Acetamiprid is a recognised irritant. It is highly toxic to birds and earthworms and moderately toxic to most aquatic organisms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for acetamiprid

Descripción: A pyridylmethylamine insecticide used for the control of Hemiptera spp. especially aphids.

Ejemplos de plagas controladas: Aphids; Thrips; Mirids; Spider mites; Whiteflies; European pine sawflies; Leaf miners; Leaf hoppers; Vine weevil

Ejemplos de aplicaciones: Leafy Vegetables; Fruiting Vegetables; Fruit including citrus, apples, pears, grapes; Cotton; Ornamental Plants and Flowers

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1995, Japón

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Netherlands/Spain
Date inclusion expires 28/02/2023
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism There are 2 isomeric forms in acetamiprid with E and Z-configurations of the cyano-imino group
Fórmula química C10H11ClN4
Canonical SMILES CC(=NC#N)N(C)CC1=CN=C(C=C1)Cl
Isomeric SMILES -
International Chemical Identifier Key (InChIKey) WCXDHFDTOYPNIE-RIYZIHGNSA-N
International Chemical Identifier (InChI) InChI=1S/C10H11ClN4/c1-8(14-7-12)15(2)6-9-3-4-10(11)13-5-9/h3-5H,6H2,1-2H3/b14-8+
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Acetamiprid Unstated isomer Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Neonicotinoid
Minimum active substance purity 990 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Systemic with translaminar activity having both contact and stomach action. Acetylcholine receptor (nAChR) agonist.
CAS RN 135410-20-7
CEE número Ningunos asignaron
Número CIPAC 649
EPA américaine chimiques de code 099050
PubChem CID 213021
Masa molecular (g mol-1) 222.67
PIN (Preferred Identification Name) (1E)-N-[(6-chloropyridin-3-yl)methyl]-N'-cyano-N-methylethanimidamide
Nombre IUPAC (E)-N1-[(6-chloro-3-pyridyl)methyl]-N2-cyano-N1-methylacetamidine
Nombre CAS (1E)-N-[(6-chloro-3-pyridinyl)methyl]-N'-cyano-N-methylethanimidamide
Otra información de estado NOTE ban or usage restriction may be in place for use on flowering crops in some Member States
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 4A
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Acarus siro
Bemisia tabaci
Leptinotarsa decemlineata
Estado físico A white to pale yellow crystalline solid
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgroCare
  • Certis
  • Aventis
  • Nisso Chemical Europe
Example products using this active
  • Acetamiprid WP
  • Gazelle
  • Insyst
  • Beticol
  • Mospilan 20 SG
  • Antilop SG
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Usually formulated as soluble granules for spray application.


DESTINO AMBIENTAL

for acetamiprid

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 2950 A5 Alto
Solubilidad - en solventes organicos en 20oC (mg l-1) 6.54 A5 - Hexano -
200000 A5 - Cloroformo -
200000 A5 - Cloruro de metileno -
200000 A5 - Acetona -
Punto de fusión (oC) 98.9 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 200 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 6.31 X 1000 Calculado -
Log P 0.8 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.33 A5 -
Disociación constante (pKa) at 25oC 0.7 A5 -
Nota: Ácido fuerte
Presión de vapor en 20oC (mPa) 1.73 X 10-04 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 5.30 X 10-08 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.40 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 9.83 X 10-04 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 247nm = 19700, 217nm = 12100 A5 -
Surface tension (mN m-1) 70.9 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 1.6 A5 No persistente
DT50 (laboratorio en 20oC) 1.6 A5 No persistente
DT50 (campo) 3 A5 No persistente
DT90 (laboratorio en 20oC) 8.8 A5 -
DT90 (campo) 20.2 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier Lab studies DT50 range 0.8-5.4 days, DT90 range 2.8-67.3 days, field studies (2015 RAR) DT50 range 0.8-4.7 days, DT90 range 2.7-28 days; Other sources: 2-20 days
Dissipation rate RL50 on plant matrix Valor 6.3 R4 -
Nota Published literature RL50 range 3.0-12.3 days, 3 field crops, various matrices, n=3
Dissipation rate RL50 on and in plant matrix Valor Published literature RL50 range 1.9-15.4 days, 14 field & undercover grown crops, various matrices, n=19 - -
Nota R4
Acuoso fotólisis DT50 (días) en pH 7 Valor 34 A5 Estable
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable pH 4 to pH 7 at temps 22-45 deg C. Degradation does occur at higher pHs and elevated temps e.g. DT50 420 days at pH 9, 25 degC, 13 days pH9, 45 degC
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) 4.7 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - US3 Móvil moderado
Koc 200
Notas y rango -
Freundlich Kf 1.58 A5 Móvil moderado
Kfoc 106.5
1/n 0.86
Notas y rango EU dossier (2015 RAR) Kf range 0.6-3.13 mL/g, Kfoc range 71.38-138.39 mL/g, 1/n range 0.825-0.807, Soils=5
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
N-methyl(6-chloro-3-pyridyl)methylamine This metabolite may cause environmental pollution, click here for further information Suelo   0.720   Major fraction, Relevant
(E)-N2-carbamoyl-N1-(6-chloro-3-pyridyl)methyl-N2-cyano-N1-methylacetamidine This metabolite may cause environmental pollution, click here for further information Suelo   0.549   Major fraction, Relevant
6-chloro-nicotinic acid This metabolite may cause environmental pollution, click here for further information Suelo   0.113   Major fraction, Relevant
N-(6-chloropyridin-3-ylmethyl)-N-methyl-acetamidine This metabolite may cause environmental pollution, click here for further information Suelo   0.200   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
(Ref: IB-1-1) - - - -
6-chloro-pyridilmethyl alcohol
(Ref: IM-0)
Nota: Toxic
- Animal; Plant - -
N-{(6-chloro-3-pyridyl)methyl}-N-methylacetamide
(Ref: IM-1-3)
Nota: Toxic
- Animal; Water (Hydrolysis) - -
(Ref: IM-2-3)
Nota: Toxic
- Animal - -


ECOTOXICOLOGÍA

for acetamiprid

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) Low risk A5 Based on LogP < 3 Bajo potencial
CT50 (días) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 146 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 15 A5 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 98 A5 Anas platyrhynchos Alto
Birds - Short term dietary (LC50/LD50) > 741 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) > 100 A5 Oncorhynchus mykiss Bajo
Pez - Crónico 21 días NOEC (mg l-1) 19.2 A5 Pimephales promelas, 32 día Bajo
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 49.8 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 5 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.005 A5 Chironomus riparius Alto
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 1 A5 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 98.3 A4 Scenedemus subspicatus, 72 hora Bajo
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 8.09 A5 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) 14.53 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 9 A5 Eisenia foetida Alto
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 1.26 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 0.2-0.4 kg ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 0.09-0.18 kg ha-1
A5 Typhlodromus pyri, protonymph
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.2 kg ha-1
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for acetamiprid

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 146 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 1.15 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.025 A5 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.025 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.07 A5 -
Estudios den la absorción cutánea (%) 15.9-33.7 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Minimal risk from dietary exposure
Source: US EPA/EU
Occupational Occupational exposure may occur through inhalation and dermal contact. Operator health should be monitored
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana No further information available

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Combustable
Not explosive or oxidising
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H302
Environment: H412
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22
N - Dangerous for the environment: R52/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S46, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU Usually 2588
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for acetamiprid

Idioma Nombre
Inglés acetamiprid
Francés acetamipride
Alemán Acetamiprid
Danés acetamiprid
Italiano acetamiprid
Español acetamiprid
Griego -
Esloveno acetamiprid
Polaco acetamipryd
Sueco acetamiprid
Húngaro acetamiprid
Holandés acetamiprid

Última actualización del registro: Tuesday 30 October 2018
Contacto: aeru@herts.ac.uk