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camfeclor (Ref: Hercules 3956)
** camphechlor ** toxaphene ** polychlorocamphene ** chlorocamphene ** toxafeen ** octachlorocamphene ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio
Otros datos se pueden encontrar en el VSDB

RESUMEN

Camphechlor is an obsolete insecticide and acaricide that is not approved for use in the EU. It has a low aqueous solubility, is quite volatile and moderately mobile. Based on its chemical properties, it has a high risk of leaching to groundwater. It is not expected to be persistent in soil but may be persistent in water systems. Camphechlor is highly toxic to mammals and is likely to bioaccumulate. It is highly toxic to birds and most aquatic organisms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for camphechlor

Descripción: An obsolete insecticide that was often used in conjunction with other active substances to control a wide range on insects on crops and livestock

Ejemplos de plagas controladas: Lygus bugs; Aphids; Spidermites; Ticks; Fleas; Mange mites; Lice; Scab mites; Grasshoppers; Armyworms; Cutworms

Ejemplos de aplicaciones: Cotton; Ornamentals; Pineapples; Corn and small grains; Vegetables; Oilseeds; Livestock

Eficacia y actividad: -

Availability status: Obsolete/Banned

Introduction & key dates: 1947, first developed

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur No aplicable
Date inclusion expires Expired
UE Candidatas a sustitución -
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A chiral molecule
Fórmula química C10H10Cl8
Canonical SMILES C1C2C(C(C(C1(Cl)Cl)(C2(CCl)C(Cl)Cl)CCl)Cl)Cl
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) YNEKMCSWRMRXIR-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C10H10Cl8/c11-2-8(7(15)16)4-1-10(17,18)9(8,3-12)6(14)5(4)13/h4-7H,1-3H2
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Acaricide, Veterinary substance
Grupo químico Chlorinated hydrocarbon
Minimum active substance purity -
Known relevant impurities -
Sustancias de origen Sintéticas
Modo de acción A non-systemic contact and stomach insecticide. It acts on the neurons, causing an imbalance in sodium and potassium ions, similar to that of the cyclodiene insecticides.
CAS RN 8001-35-2
CEE número 232-283-3
Número CIPAC 23
EPA américaine chimiques de code 080501
PubChem CID 58167
Masa molecular (g mol-1) 413.96
PIN (Preferred Identification Name) -
Nombre IUPAC reaction mixture of chlorinated camphenes containing 67–69% chlorine
Nombre CAS 2,2,5-endo,6-exo,8,8,9,10-Octachlorobornane
Otra información de estado Chemical subject to PIC regulations; OSPAR soc; POP - regulated by Stockholm Convention; Severe Marine Pollutant; Rotterdam Convention (Class O)
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) Not known
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance -
Estado físico Yellow to amber waxy solid
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Hercules
  • BCF
Example products using this active
  • Agrones Hepta
  • Altox
  • Attac
  • Toxaphene
  • Phenacide
  • Phenatox
  • Toxakil
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually formulated as a wettable power, dust or emulsifiable concentrate.


DESTINO AMBIENTAL

for camphechlor

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 3.0 F4 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 4500000 CA3 - Benceno -
4500000 CA3 - Tetracloruro de carbono -
4500000 CA3 - Xileno -
2800000 CA3 - Queroseno -
Punto de fusión (oC) 78 V2 - Gama 65-90 -
Punto de ebullición (oC) - - -
El punto de degradación (oC) - - -
Punto de inflamación (oC) - - -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.00 X 1003 Calculado -
Log P 3.3 F4 Alto
Masa densidad (g ml-1)/Peso específico 1.65 F4 -
Disociación constante (pKa) at 25oC - - -
Nota:
Presión de vapor en 20oC (mPa) 0.67 Q3 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 6.08 X 10-01 V3 Volátil moderado
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 3.92 Calculado Alta posibilidad de la lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.21 X 10+00 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 365 L1 Persistente muy alta
DT50 (laboratorio en 20oC) - - -
DT50 (campo) 9 F3 No persistente
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota Literature sources highly variable: DT50 2 months and 14 years; US sources: 9 days (DW3, US3); Field DT50 9 to 500 days (R3)
Dissipation rate RL50 on plant matrix Valor 3.6 R4 -
Nota Published literature RL50 range 1.6-5.0 days, 4 field crops, various matrices, n=4
Dissipation rate RL50 on and in plant matrix Valor 12.6 R4 -
Nota Published literature RL50 range 2.3-25.2 days, 4 field crops, various matrices, n=7
Acuoso fotólisis DT50 (días) en pH 7 Valor - - -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable R3 -
Nota -
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) - - -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - F2 Móvil moderado
Koc 295
Notas y rango Literature range for log Koc = 2.47-5.00; Other sources: Koc 100000 mL/g (US2)
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad -

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
strobane (Ref: ENT 19442)   -   -


ECOTOXICOLOGÍA

for camphechlor

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 76000 R4 Alto potencial
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) 50 V3 Rata Alto
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 15 V3 Anas platyrhynchos Alto
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.0044 F4 Lepomis macrochirus Alto
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.0141 F4 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) - - -
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.0021 F3 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.38 F4 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) - - -
Oral aguda 48 hora LD50 (μg abeja-1) > 19.1 F4 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) - - -
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad - - -
Soil micro-organisms - - -
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for camphechlor

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 50 V3 Rata Alto
Mammals - Dermal LD50 (mg kg-1 body weight) - - -
Mammals - Inhalation LC50 (mg l-1) - - -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) - - -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) - - -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) - - -
Estudios den la absorción cutánea (%) - - -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones [LT TLV-TWS (US): 0.5 mg/m3] F3 -
Exposure Routes Public Possible risk via food contamination
Occupational Absorbed by the intact skin and from the gastrointestinal tract
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana IARC group 2B carcinogen
Ingestion may be fatal
May cause convulsions
Potential kidney toxicant
May cause allergic bronchopneumonia
Endocrine issues - Increase of estrogen-sensitive cells proliferation

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Corrosive
Not compatible with strongly alkaline pesticides
CLP classification 2013 Health: H301, H312, H315, H335, H351
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
T - Toxic: R25
Xn - Harmful: R21
Xi - Irritant: R40
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S36/37, S45, S61, S60
Clasificación de OSM O - Sustancia obsoletos
US EPA Classification (formulation) II - Warning - Moderately toxic
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for camphechlor

Idioma Nombre
Inglés camphechlor
Francés bamphéchlore
Alemán Camphechlor
Danés camphechlor, toxaphen
Italiano camfeclor
Español camfeclor
Griego -
Esloveno kamfeklor
Polaco kamfechlor
Sueco -
Húngaro -
Holandés toxafeen

Última actualización del registro: Tuesday 22 May 2018
Contacto: aeru@herts.ac.uk