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amisulbrom
** amisulbrom ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

A sulfonamide fungicide that is approved for use in the EU. It has a low aqueous solubility, is slightly volatile with a calulated moderate mobility. There is not a high risk of the substance leaching to groundwater. It may be persistent in soil systems but is not expected to persist in water systems. It has a low mammalian toxicity but it is considered to be a reproduction toxicant. It is moderately toxic to birds and honey bees but poses a greater risk to aquatic species and earthworms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for amisulbrom

Descripción: A new sulfonamide fungicide for use on potatoes and other crops

Ejemplos de plagas controladas: Late blight (Phytophthora infestans); Downy mildew (Plasmopara viticola)' Fruit rot (Phytophthora capsici)

Ejemplos de aplicaciones: Potatoes; Tomatoes; Grapes; Curcubits; Bell peppers

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: -

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK
Date inclusion expires 30/06/2024
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C13H13BrFN5O4S2
Canonical SMILES CC1=C(C2=C(N1S(=O)(=O)C3=NN(C=N3)S(=O)(=O)N(C)C)C=C(C=C2)F)Br
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) BREATYVWRHIPIY-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C13H13BrFN5O4S2/c1-8-12(14)10-5-4-9(15)6-11(10)20(8)25(21,22)13-16-7-19(17-13)26(23,24)18(2)3/h4-7H,1-3H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Sulfonamide
Minimum active substance purity 985 g/Kg
Known relevant impurities EU dossier - 3-bromo-6-fluoro-2-methyl-1-(1H-1,2,4-triazole-3-ylsulfonyl)indole (metabolite IT-4) < 2 g/kg
Sustancias de origen Sintéticas
Modo de acción Qil (Quinone Inside Inhibitor) action. Respiration inhibitor.
CAS RN 348635-87-0
CEE número -
Número CIPAC 789
EPA américaine chimiques de code -
PubChem CID 10238657
Masa molecular (g mol-1) 466.31
PIN (Preferred Identification Name) 3-(3-bromo-6-fluoro-2-methyl-1H-indole-1-sulfonyl)-N,N-dimethyl-1H-1,2,4-triazole-1-sulfonamide
Nombre IUPAC 3-(3-bromo-6-fluoro-2-methylindol-1-ylsulfonyl)-N,N-dimethyl-1,2,4-triazole-1-sulfonamide
Nombre CAS 3-((3-bromo-6-fluoro-2-methyl-1H-indol-1-yl)sulfonyl)-N,N-dimethyl-1H-1,2,4-triazole-1-sulfonamide
Otra información de estado PAN listed Highly Hazardous Chemical
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 21
Examples of recorded resistance -
Estado físico Pale yellow crystalline solid
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Nissan
Example products using this active
  • Shinkon
  • Leimay
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Usually supplied as a suspension concentrate that is mixed with water and used as a spray. No UK approval for aerial use.


DESTINO AMBIENTAL

for amisulbrom

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.11 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 264 A5 - Hexano -
88600 A5 - Tolueno -
10100 A5 - Metanol -
2600 A5 - Octanol -
Punto de fusión (oC) 128.6 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 242 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.51 X 1004 Calculado -
Log P 4.4 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.85 Q2 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 1.8 X 10-05 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 2.8 X 10-05 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -0.49 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 Neutral sol.: 254nm=11300
Acid soln.: 254nm=11500
Basic soln.: 222nm = 26300, 265nm=6520
A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 143 A5 Persistente
DT50 (laboratorio en 20oC) 143 A5 Persistente
DT50 (campo) 8.6 A5 No persistente
DT90 (laboratorio en 20oC) 1011 A5 -
DT90 (campo) 30.6 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 48.4-937.9 days, DT90 range 161-1942 days; Field studies DT50 range 4.3-12.6, DT90 range 14.2-41.9 dats
Dissipation rate RL50 on plant matrix Valor 3.9 R3 -
Nota Cabbage leaves, n=1
Dissipation rate RL50 on and in plant matrix Valor 5.5 R4 -
Nota Published literature RL50 range 3.0-7.9 days, cucumber & melon fruits, n=2
Acuoso fotólisis DT50 (días) en pH 7 Valor 0.8 A5 Rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 87.1 A5 Persistente moderado
Nota pH dependent: 106.1 days @ pH4; 7.0day @ pH9
Aqua-Sedimento DT50 (días) 100.1 A5 Lento
Fase de agua sola DT50 (días) 6.7 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - Q2 Móvil moderado
Koc 284
Notas y rango Estimated
Freundlich Kf 246 A5 No Móvil
Kfoc 16965
1/n 0.94
Notas y rango EU dossier Kf range 147-378 mL/g, Kfoc range 8156-44231 mL/g, 1/n range 0.9-1.0, Soils=6
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-bromo-6-fluoro-2-methyl-1-(1H-1,2,4-triazole-3-ylsulfonyl)indole This metabolite may cause environmental pollution, click here for further information Suelo   0.337   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
3-(3-bromo-6-fluoro-2-hydroxymethylindol-1-ylsulfonyl)-N,N-dimethyl-1,2,4-triazole-1-sulfonamide IT-2 Humans - -
3-(3-bromo-6-fluoro-5-hydroxymethy-2-hydroxymethylindol-1-ylsulfony)-N,N-dimethyl-1,2,4-triazole-1-sulfonamide IT-3 Plants - -
3-(3-bromo-6-fluoro-5-hydroxymethy-1-(1H-1,2,4-triazole-2-ylsulfony)indole IT-5 Plants - -
3-(3-bromo-6-fluoro-5-hydroxymethy-2-hydroxymethyl-1-(1H-1,2,4-triazole-3-ylsulfony)indole IT-6 Plants - -
2-((1-N,N-dimethylaminosulfonyl-1,2,4-triazole-3-yl)sulfonylamino)-4-fluorobenzoic acid IT-9 Animal - -
2-((1H-1,2,4-triazole-3-yl)sulfonylamino)-4-fluorobenzic acid IT-10 - - -
3-(6-fluoro-2-hydroxy-2-methyl-3-oxoindolin-1-ylsulfonyl)-N,N,dimethyl-1,2,4-triazole-1-sulfonamide IT-11 - - -
3-(1H,1,2,4-triazole-3-ylsulfonyl)-6-fluoro-2-methylindole IT-12 - - -
3-bromo-6-fluoro-2-methyl-1-(1-methyl-1,2,4-triazole-3-ylsulfonyl)indole IT-15 Surface water; Sediments - -
2-acetylamino-4-fluorobenzoic acid I-2 Surface water - -
2-acetylamino-4-fluoro-hydroxybenzoic acid I-8 (hydroxylated I-2) Surface water - -
2,2-oxybis)6-fluoro-2-methylindolin-3-one) I-9 (I-5 dimer) - - -
1-(N,N-dimethylaminosulfonyl)-1,2,4-triazole-3-sulfonic-acid T-1 Surface water - -
1-(N,N-dimethylaminosulfonyl)-1,2,4-triazole T-2 - - -
1H-1,2,4-triazole-3-sulfonic acid T-3 Surface water - -
1H-1,2,4-triazole T-4 Surface water - -
2-amino-3-(1H-1,2,4-triazol-1-yl)propanoic acid T-5 - - -
2-(1H-1,2,4-triazol-1-yl)acetic acid T-6 - - -
5-(N,N-dimethylaminosulfonyl)-1H-1H-1,2,4-triazole T-7 (T-2 isomer) Surface water - -
3-bromo-6-fluoro-2-methylindole I-1 - - -


ECOTOXICOLOGÍA

for amisulbrom

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 176 A5 Umbral de importancia
CT50 (días) 0.40 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 1080.5 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.0515 A5 Oncorhychus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.037 A5 Pimephales promelas, 28-día growth Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.037 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0197 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.1114 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.20 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 87.5 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 1000 >
A5 Typhlodromus pyri
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 1000 >
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 1.6mg kg-1, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for amisulbrom

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 2.85 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.1 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.3 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.15 A5 Rabbit, SF=100 -
Estudios den la absorción cutánea (%) 0.6-12 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public Acceptable for proposed uses
Occupational Acceptable for proposed uses
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

-

Cuestiones generales de la salud humana Possible liver toxicant
May cause eye damage

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
CLP classification 2013 Health: H319, H351
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Reproduction risk cat 3: R61
Xn - Harmful: R62, Xi - Irritant: R41
N - Dangerous for the environment; R50/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S35, S57
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) - -
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for amisulbrom

Idioma Nombre
Inglés amisulbrom
Francés -
Alemán -
Danés -
Italiano -
Español -
Griego -
Esloveno -
Polaco amisulbrom
Sueco amisulbrom
Húngaro -
Holandés -

Última actualización del registro: Friday 14 September 2018
Contacto: aeru@herts.ac.uk