Seleccione la Opción
Inicio
A a Z Indice
Búsqueda
Términos y Condiciones
Información de Asistencia
Compras y Servicios
GET ADDITIONAL DATA HERE!

pyridalyl (Ref: S-1812)
** pyridalyl ** pyridalil ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Pyridalyl is an insectide recently granted EU approval for use. It is practically insoluble and slightly volatile. It may be persistent in soil and aquatic systems under certain conditions. It has a low mammalian toxicity, not expected to bioaccumulate and no serious health concerns have been identified. It is highly toxic to all aquatic life

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for pyridalyl

Descripción: A pyridalyl insecticide active against a range of Lepidopterous and Thysanopterous insects

Ejemplos de plagas controladas: Thrips; Caterpillars; Armyworm; Loopers; Gypsy moth; Budworms; Hornworms

Ejemplos de aplicaciones: Ornamental shrubs and flowers; Ornamental tress; Nut trees; Vines; Cotton

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 2002, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Netherlands
Date inclusion expires 30/06/2024
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C18H14Cl4F3NO3
Canonical SMILES C1=CC(=NC=C1C(F)(F)F)OCCCOC2=C(C=C(C=C2Cl)OCC=C(Cl)Cl)Cl
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) AEHJMNVBLRLZKK-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C18H14Cl4F3NO3/c19-12-9-11(27-8-5-15(21)22)10-13(20)17(12)29-7-2-6-28-16-4-1-3-14(26-16)18(23,24)25/h1,3-5,9-10H,2,6-8H2
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Pyridalyl
Minimum active substance purity 910 g/kg
Known relevant impurities -
Sustancias de origen Sintéticas
Modo de acción Unclear but appears to inhibit insect vigour
CAS RN 179101-81-6
CEE número -
Número CIPAC 792
EPA américaine chimiques de code 295149
PubChem CID 11488729
Masa molecular (g mol-1) 491.12
PIN (Preferred Identification Name) 2-(3-{2,6-dichloro-4-[(3,3-dichloroprop-2-en-1-yl)oxy]phenoxy}propoxy)-5-(trifluoromethyl)pyridine
Nombre IUPAC 2,6-dichloro-4-(3,3-dichloroallyloxy)phenyl 3-[5-(trifluoromethyl)-2-pyridyloxy]propyl ether
Nombre CAS 2-[3-[2,6-dichloro-4-[(3,3-dichloro-2-propenyl)oxy]phenoxy]propoxy]-5-(trifluoromethyl)pyridine
Otra información de estado PAN listed Highly Hazardous Chemical
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) Not known
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance -
Estado físico Yellow liquid with faint odour
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Valent USA Corporation
Example products using this active
  • Pyridalyl 10EW
  • Overture
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually supplied as a wettable powder formulation packaged in water soluble packets containing 35% active ingredient.


DESTINO AMBIENTAL

for pyridalyl

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.00015 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) Miscible A5 - n-Octanol -
Miscible A5 - Xileno -
Miscible A5 - Cloroformo -
Miscible A5 - Acetona -
Punto de fusión (oC) -17 A5 -
Punto de ebullición (oC) 227 A5 -
El punto de degradación (oC) - - -
Punto de inflamación (oC) 111 A5 - (closed cup) -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.26 X 1008 Calculado -
Log P 8.1 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.450 L3 -
Disociación constante (pKa) at 25oC - - -
Nota:
Presión de vapor en 20oC (mPa) 6.24 X 10-05 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 0.205 A5 Volátil moderado
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -2.10 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 pH 1.1: 208nm=44668, 274nm=4898; [pH 7.2-7.9: 208nm=44668, 274nm=4898; [pH 10.3: 208nm=44668, 274nm=4786; [pH 13.1: 208nm=23998, 274nm=4898; A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 145 A5 Persistente
DT50 (laboratorio en 20oC) 145 A5 Persistente
DT50 (campo) 245 A5 Persistente
DT90 (laboratorio en 20oC) 30000 A4 -
DT90 (campo) 254 A5 -
Endpoint de modelado DT50 - - -
Nota EU Dossier Lab studies DT50 range 53-272 days; DT90 range 465->1000 days; Field studies DT50 range 1.2-39 days, DT90 range 176-350 days; USEPA report Field DT50 range 93.7-346.6 days; General literature DT50 range 93-148 days
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 4 F4 Moderado rápido
Nota Range 2-6 days
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable F4 -
Nota Stable pH5 to pH9
Aqua-Sedimento DT50 (días) 186 A5 Lento
Fase de agua sola DT50 (días) 8.6 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 1812 A5 No Móvil
Kfoc 93481
1/n 1.04
Notas y rango EU dossier Kf range 1373-2596 mL/g, Kfoc range 52435-171574 mL/g, 1/n range 0.98-1.07, soils=3
pH senbsibilidad None

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3,5-dichloro-4-(3-((5-(trifluoromethyl)pyridin-2-yl)oxy)propoxy)phenol (Ref: S-1812-DP) This metabolite may cause environmental pollution, click here for further information Suelo   0.122   Major fraction; Relevant
2-(3-(2,6-dichloro-4-methoxyphenoxy)propoxy)-5-(trifluoromethyl)-pyridine (Ref: S-1812-DP-ME) This metabolite may cause environmental pollution, click here for further information Suelo   0.124   Major fraction; Relevant
5-(trifluoromethyl)pyridin-2(1H)-one This metabolite may cause environmental pollution, click here for further information Suelo   0.147   Major fraction; Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
3-hydroxy-5-trifluoromethylpyridone HPDO Plant - -
[3,5-dichloro-4-(3-{[5-(trifluoromethyl)pyridin-2-yl]oxy}propoxy)phenoxy]acetic acid S-1812-Ph-CH2-COOH - - -
3-{[5-(trifluoromethyl)pyridin-2-yl]oxy}propan-1-ol S-1812-PYP - - -
3-{[5-(trifluoromethyl)pyridin-2-yl]oxy}propanoic acid TPPA - - -
1-methyl-5-(trifluoromethyl)pyridin-2(1H)-one N-methyl-HTFP - - -
3-hydroxy-1-methyl-5-(trifluoromethyl)pyridin-2(1H)-one N-methyl-HPDO - - -
Unknown metabolite - Soil - -


ECOTOXICOLOGÍA

for pyridalyl

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 26858 A5 Whole fish Alto potencial
CT50 (días) 30 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2250 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) 1133 mg kg feed-1 A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.50 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.0038 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0014 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.001 A5 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) 1.10 A4 Chironomus yoshimatsui, 48hr EC50 Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 0.17 A5 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.20 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 31.5 A5 Eisenia foetida corr Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 600 >
A5 Typhlodromus pyri
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 457.6 A5 Aphidius rhopalosiphi -
% Causalidad - - -
Soil micro-organisms - - -
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for pyridalyl

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 2.01 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.03 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.02 A5 Rat, SF=100 -
Estudios den la absorción cutánea (%) 0.7-3.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Low risk if used in acordance with label guidance
Occupational Low risk if used in acordance with label guidance
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Liver & blood toxicant
May cause thickening of arterial and arteoriole walls

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
CLP classification 2013 None allocated at this time
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R43
N - Dangerous for the environment: R50/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for pyridalyl

Idioma Nombre
Inglés pyridalyl
Francés -
Alemán -
Danés -
Italiano -
Español -
Griego -
Esloveno -
Polaco -
Sueco -
Húngaro -
Holandés -

Última actualización del registro: Thursday 31 May 2018
Contacto: aeru@herts.ac.uk