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penthiopyrad (Ref: MTF 753)
** penthiopyrad ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for penthiopyrad

Descripción: Used to control rust, Rhizoctonia diseases and other fungal diseases on cereals and other crops

Ejemplos de plagas controladas: Rust; Rhizoctonia diseases; Grey mould; Powdery mildew; Applie scab; Septoria leaf blotch

Ejemplos de aplicaciones: Cereals including wheat; Potatoes; Sugarbeet; Turf; Legumes; Vegetables; Soybeans

Eficacia y actividad: Wheat/Septoria=High; Wheat/Rust=Moderate; Barley/Rhynchosporium=Moderate; Barley/Mildew=Low; Barley/Rust=Moderate; Barley/Net blotch=Moderate; Barley/Ramularia=Moderate

Availability status: Current

Introduction & key dates: circa 2003

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK
Date inclusion expires 30/04/2024
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Penthiopyrad is a chiral molecule. The technical material is an isomeric mixture of the R- and S-enantiomers..
Fórmula química C16H20F3N3OS
Canonical SMILES CC(C)CC(C)C1=C(C=CS1)NC(=O)C2=CN(N=C2C(F)(F)F)C
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) PFFIDZXUXFLSSR-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C16H20F3N3OS/c1-9(2)7-10(3)13-12(5-6-24-13)20-15(23)11-8-22(4)21-14(11)16(17,18)19/h5-6,8-10H,7H2,1-4H3,(H,20,23)/f/h20H
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Carboxamide
Minimum active substance purity 980 g/kg
Known relevant impurities EU dossier - none declared
Sustancias de origen Sintéticas
Modo de acción Broad spectrum, preventative and curative; inhibits mitochondrial functions - Succinate Dehydrogenase Inhibitor (SDHI)
CAS RN 183675-82-3
CEE número -
Número CIPAC 824
EPA américaine chimiques de code -
PubChem CID 11388558
Masa molecular (g mol-1) 359.4
PIN (Preferred Identification Name) rac-1-methyl-N-{2-[(2R)-4-methylpentan-2-yl]thiophen-3-yl}-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide
Nombre IUPAC (RS)-N-[2-(1,3-dimethylbutyl)-3-thienyl]-1-methyl-3-(trifluoromethyl)pyrazole-4-carboxamide
Nombre CAS N-(2-(1,3-dimethylbutyl)-3-thienyl)-1-methyl-3-(trifluoromethyl)-1H-pyrazole-4-carboxamide
Otra información de estado PAN listed Highly Hazardous Chemical
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 7
Examples of recorded resistance -
Estado físico White powder
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • DuPont
  • Mitsui Chemicals
Example products using this active
  • Aphet
  • Fontelis
  • Vertisan
  • Velista
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details -


DESTINO AMBIENTAL

for penthiopyrad

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 1.375 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 402000 A5 - Metanol -
557000 A5 - Acetona -
349000 A5 - Acetato de etilo -
67000 A5 - Tolueno -
Punto de fusión (oC) 108.7 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 314 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 4.17 X 1004 Calculado -
Log P 4.62 A5 Alto
Masa densidad (g ml-1)/Peso específico - - -
Disociación constante (pKa) at 25oC 10.0 A5 -
Nota:
Presión de vapor en 20oC (mPa) 0.000643 A4 - @25 degC Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 7.66 X 10-03 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 2.33 Calculado Estado de transición
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.31 X 10-01 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Neutral soln.: 226nm=14922
Acidic soln.: 226nm=14460
A5 -
Surface tension (mN m-1) 56.7 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 121.5 A5 Persistente
DT50 (laboratorio en 20oC) 121.5 A5 Persistente
DT50 (campo) 9.2 A5 No persistente
DT90 (laboratorio en 20oC) 544 A5 -
DT90 (campo) 47.6 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 50.8-340.5 days, DT90 range 217->1000 days; Field studies DT50 range 0.8-33.3 days, DT90 range 7.2-169 days
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor 3.1 R3 -
Nota Oriental melon fruit, n=1
Acuoso fotólisis DT50 (días) en pH 7 Valor - - -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable at all relevant pH's
Aqua-Sedimento DT50 (días) 269 A5 Lento
Fase de agua sola DT50 (días) 9.9 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 13.2 A5 Móvil un poco
Koc 804
Notas y rango EU dossier Kd range 10-17 mL/g, Koc range 610-1050 mL/g, soils=5
Freundlich Kf 12.52 A5 Móvil un poco
Kfoc 761
1/n 0.96
Notas y rango EU dossier Kf range 9.37-14.9 mL/g, Kfoc range 546-919 mL/g, 1/n range 0.94-0.97, Soils=5
pH senbsibilidad -

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-trifluoromethyl-1H-pyrazole-4-carboxylic acid (Ref: IN-DRJ75) This metabolite may cause environmental pollution, click here for further information Suelo   0.168   Major fraction; Relevant
N-(2-(3-hydroxy-1,3-dimethyl-butyl)thiophen-3-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide (Ref: 753-T-OH) Suelo   0.072   Minor fraction, Relevant
N-(5-hydroxy-5-(1,3-dimethylbutyl)-2-oxo-2,5-dihydrothiophen-4-yl)-1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide (Ref: 753-T-DO) Suelo   0.081   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
- dehydro-753-A-OH Rats - -
- hydroxy-MTF-753 Animals; Rats - -
- 753-A-COOH Rats - -
- DM-753-A-COOH Rats - -
- PDA Rats - -
- hydroxy-MTF-753-glucuronide Rats - -
- hydroxy-DM-MTF-753-glucuronide Rats - -
- hydroxy-DM-MTF-753-glucoside Plants - -
- hydroxy-MTF-753-malonyl-glucoside Plants - -
- cys-T-DO Animals - -
- hydroxy-cys-T-DO Rats - -
- dihydroxy-cys-T-DO Animals - -
- GSH-T-DO Rats - -
- N-acetyl-cys-T-DO Rats - -
- cys-F-Do Rats; Animals - -
- dehydro-cys-F-Do Rats; Animals - -
- hydroxy-cys-F-DO Rats; Animals - -
(Ref: IN-DRJ75)
Nota: MW=180.08
DM-PCA Soil; Water; Plants; Rats; Animals - -
1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxylic acid
(Ref: IN-MR507)
Nota: MW=194.11
PCA Soil; Water; Plants; Animals; Rats - -
(Ref: IN-PGH32)
Nota: MW=179.10
DM-PAM Rats; Plants; Animals - -
1-methyl-3-trifluoromethyl-1H-pyrazole-4-carboxamide
(Ref: IN-PGH45)
Nota: MW=193.13
PAM Soil; Plant; Animal; Rats - -
(Ref: IN-PGH59)
Nota: MW=375.34
753-F-DO Soil; Water; Plants; Animals; Rats - -
(Ref: IN-PGH60)
Nota: MW=345.39
dihydroxy-753 Plants; Rats; Animals - -


ECOTOXICOLOGÍA

for penthiopyrad

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 186 A5 Umbral de importancia
CT50 (días) 0.65 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2250 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.29 A5 Pimephales promelas Moderado
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 1.38 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) - - -
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants > 1563 A5 Lolium perenne
Seedling emergence, EC50
as g/ha
-
> 1563 A5 Triticum aestivum
Vegetative vigour, EC50
as g/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 1.58 A5 Pseudokirchneriella subcapitata 96hr growth Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 500 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 500 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) > 48 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 327.1 A5 Typhlodromus pyri, as product -
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 2800 A5 Aphidius rhopalosiphi -
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: EC25 100-333 mg kg-1
Carbon mineralisation: No significant adverse effect
A5 -
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for penthiopyrad

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.59 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.1 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.75 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.1 A5 Rat, SF=100 -
Estudios den la absorción cutánea (%) Up to 53% A5 -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public Acceptable for proposed uses
Occupational PPE/PPC recommended
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Possible liver toxicant
USEPA - some evidence to suggest possible human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
CLP classification 2013 Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 2: R40
N - Dangerous for the environment: R50/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases None allocated at this time
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) - -
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for penthiopyrad

Idioma Nombre
Inglés penthiopyrad
Francés -
Alemán -
Danés -
Italiano -
Español -
Griego -
Esloveno -
Polaco -
Sueco -
Húngaro -
Holandés -

Última actualización del registro: Friday 14 September 2018
Contacto: aeru@herts.ac.uk