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thiencarbazone-methyl (Ref: BYH 18636 )
** thiencarbazone-methyl ** TCM ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for thiencarbazone-methyl

Descripción: A herbicide that is often used in mixtures with isoxaflutole for pre-emergence control of grassy and broad-leaved weeds

Ejemplos de plagas controladas: Smartweed; Velvetleaf; Barnyardgrass; Morning glory; Dead nettle; Curly Dock; Hemp; Wild mustard; Foxtail; Lambsquarter

Ejemplos de aplicaciones: Corn; Sweetcorn; Soybean; Beet; Wheat (Spring & Durum); Turf; Ornamentals

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 2008, Estados Unidos

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK
Date inclusion expires 30/06/2024
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Estados Unidos (esperado 2009)

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C12H14N4O7S2
Canonical SMILES CC1=C(C(=CS1)C(=O)OC)S(=O)(=O)NC(=O)N2C(=O)N(C(=N2)OC)C
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) XSKZXGDFSCCXQX-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C12H14N4O7S2/c1-6-8(7(5-24-6)9(17)22-3)25(20,21)14-10(18)16-12(19)15(2)11(13-16)23-4/h5H,1-4H3,(H,14,18)/f/h14H
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Herbicida
Grupo químico Triazolone
Minimum active substance purity 950 g/kg
Known relevant impurities EU dossier - none declared
Sustancias de origen Sintéticas
Modo de acción ALS inhibitor, systemic, absorbed by roots and leaves, contact and residual action
CAS RN 317815-83-1
CEE número -
Número CIPAC 797
EPA américaine chimiques de code 015804
PubChem CID 11205153
Masa molecular (g mol-1) 390.44
PIN (Preferred Identification Name) methyl 4-[(3-methoxy-4-methyl-5-oxo-4,5-dihydro-1H-1,2,4-triazole-1-carbonyl)sulfamoyl]-5-methylthiophene-3-carboxylate
Nombre IUPAC methyl 4-[(4,5-dihydro-3-methoxy-4-methyl-5-oxo-1H-1,2,4-triazol-1-yl)carbonylsulfamoyl]-5-methylthiophene-3-carboxylate
Nombre CAS methyl 4-[[[(4,5-dihydro-3-methoxy-4-methyl-5-oxo-1H-1,2,4-triazol-1-yl)carbonyl]amino]sulfonyl]-5-methyl-3-thiophenecarboxylate
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) B
Herbicide Resistance Classification (WSSA) -
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance -
Estado físico White crystalline powder
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bayer CropScience
Example products using this active
  • Adengo
  • velocity
  • Capreno
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Available in a wide range of different formulations including oil dispersions, flowable concentrates and water dispersable granules.


DESTINO AMBIENTAL

for thiencarbazone-methyl

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 436 A5 Moderado
Solubilidad - en solventes organicos en 20oC (mg l-1) 230 A5 - Etanol -
0.15 A5 - n-Hexano -
190 A5 - Tolueno -
9540 A5 - Acetona -
Punto de fusión (oC) 205 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 231 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.05 X 10-02 Calculado -
Log P -1.98 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.51 F4 -
Disociación constante (pKa) at 25oC 3.0 A5 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 8.8 X 10-11 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 7.88 X 10-14 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 3.42 Calculado Alta posibilidad de la lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.27 X 10-01 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 Acid: 214nm = 27519, 228nm = 13125
Neutral: 214nm = 28596, 234nm = 14058
Basic: 211nm = 34453, 228nm = 29144
A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 11.6 A5 No persistente
DT50 (laboratorio en 20oC) 51.5 A5 Persistente moderado
DT50 (campo) 17 E4 No persistente
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 3.1-38.8 days, DT90 range 10.6-176.7 days; Field studies: DT50 17days mean, 45days max, n=17; Other data: DT50 range 3.2 to 55 days (F4)
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 90.6 A5 Estable
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 146 A5 - @ 25 degC Persistente
Nota pH4: 118 days, PH9 153 days at 25 DegC
Aqua-Sedimento DT50 (días) 26.2 A5 Rápido
Fase de agua sola DT50 (días) 21.3 A5 Lento

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - E4 Móvil moderado
Koc 100
Notas y rango Other data: Koc range 59.9 to 236 mL/g (F4)
Freundlich Kf 2.01 A5 Móvil moderado
Kfoc 100
1/n 0.906
Notas y rango EU dossier kf range 0.40-6.23 mL/g, Kfoc range 43-190 mK/g, 1/n range 0.886-0.932, soils = 5
pH senbsibilidad -

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-thiophene carboxylic acid, 4((((4,5-dihydro-3-methoxy-4-methyl-5-oxo-1H-1,2,4-triazol-1-yl)carbonyl)amino)sulfonyl)-5-methyl- (Ref: AE1394083) This metabolite may cause environmental pollution, click here for further information Suelo   0.536   Major fraction, Relevant
3H-1,2,4-triazol-3-one, 2,4-dihydro-5-methoxy-4-methyl- (Ref: AE1277106) This metabolite may cause environmental pollution, click here for further information Suelo   0.206   Major fraction, Relevant
3-thiophenecarboxylic acid, 4-(aminosulfonyl)-5-methyl-, methyl ester (Ref: AE1364547) This metabolite may cause environmental pollution, click here for further information Suelo   0.156   Major fraction, Relevant
4-(aminosulfonyl)-5-methyl-3-thiophenecarboxylic acid (Ref: AE1395853) This metabolite may cause environmental pollution, click here for further information Suelo   0.212   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
- Thiencarbazone-methyl-methyl carbamate; M23 Animal; Rat - -
- Thiencarbazone-methyl-hydroxy-sulfonamide; M16 Plant - -
- Thiencarbazone-methyl-hydroxy-sulfonamide-glycoside; M17 Plant - -
- Thiencarbazone-methyl-hydroxy-sulfonamide-acetyl-glycoside; M18 Plant - -
- Thiencarbazone-methyl-hydroxy-sulfonamide-glyceric acid; M19 Plant - -
- Thiencarbazone-methyl-MMT-glucoside; M22 Plant - -
- Dimethyl carbamate; M24 Animal - -
- Thiencarbazone-methyl-triazoldione; M26 Water; Animal - -
- Thiencarbazone-methyl-dicarboxy sulfonamide; M25 Surface water; Groundwater - -
6-methylthienol(3,4-d)isothiazol-3(2H)-one 1,1-dioxide Thiencarbazone-methyl thienosaccharine; M05 Soil; Plant; Rat; Animal - -
4-(((3-methoxy-5-oxo-4,50dihydro-1H-1,2,4-triazol-1-yl)carbonyl)amino)sulfonyl)-5-methylthiophene-3-carboxylic acid Thiencarbazone-methyl N desmethyl carboxylic acid; M02 Plant - -
4-(aminosulfonyl)-5-(hydroxymethyl)thiophene-3-carboxylic acid Thiencarbazone-methyl-hydroxy-sulphonamide-carboxylic acid; MO4 Plant - -
6-(hydroxymethyl)thienol(3,4-d)isothiazol-3(2H)-one 1,1-dioxide Thiencarbazone-methyl-hydroxy-thienosaccharine; M06 Plant - -
- Thiencarbazone-methyl N desmethyl; M07 Plant; Animal - -
- Thiencarbazone-methyl-N-desmethyl-glycoside; M08 Plant - -
- Thiencarbazone-methyl-desmethyl-hydroxy; M09 Plant - -
- Thiencarbazone-methyl-desmethyl-hydroxy-glycoside; M10 Plant - -
5-methoxy-2,4-dihydro-3H-1,2,4-triazol-3-one Thiencarbazone-methyl-OMT; M11; O-methyltriazolinone Plant - -
- Thiencarbazone-methyl-triazolinone carboxamide; M20 Soil; Plant; Rat; Animal - -
- Thiencarbazone-methyl-OMT-glycoside; M12 Plant - -
- Thiencarbazone-methyl-hydroxy; M13 Plant - -
- Thiencarbazone-methyl-hydroxy-glycoside; M14 Plant - -


ECOTOXICOLOGÍA

for thiencarbazone-methyl

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) Low risk A5 Based on LogP < 3 Bajo potencial
CT50 (días) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 699 mg kg-1 BW/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) > 104 A5 Oncorhynchus mykiss Bajo
Pez - Crónico 21 días NOEC (mg l-1) 4.8 A5 Pimehales Promelas Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 98.6 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 3.54 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 0.0008 A5 Lemna gibba Alto
Non-target plants 5.3 A5 Sunflowers
Vegetative vigour, ER50
as mL product/ha (SC450: Conc 0.045 kg/ha)
-
2.9 A5 Ryegrass
Seedling emergence, ER50
as mL product/ha (SC450: Conc 0.045 kg/ha)
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.17 A5 Pseudokircheriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 200 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 199 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 1000 A5 Eisenia foetida Bajo
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 45 >, Mortality
A5 Typhlodromus pyri
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 45 >, Mortality
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.3 mg kg-1 DW soil, 28días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for thiencarbazone-methyl

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 2.018 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.23 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.12 A5 Rat, SF=100 -
Estudios den la absorción cutánea (%) 0.3-2.5 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Very low risk to consumers
Occupational Very low risk to operaters
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

-

Cuestiones generales de la salud humana Possible kidney, bladder and urinary tract toxicant

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not oxidising or explosive
CLP classification 2013 None allocated at this time
CEE clasificación de riesgos Click here to view information omn the EU risk phrases None allocated at this time
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for thiencarbazone-methyl

Idioma Nombre
Inglés thiencarbazone-methyl
Francés -
Alemán -
Danés -
Italiano -
Español -
Griego -
Esloveno -
Polaco -
Sueco tienkarbazon-metyl
Húngaro -
Holandés -

Última actualización del registro: Thursday 23 August 2018
Contacto: aeru@herts.ac.uk