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clordano (Ref: OMS 1437)
** chlordane ** M140 ** ENT 9932 ** aspon-chlordane ** kypchlor ** chlorodane ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Chlordane is an insecticide that is not approved for use in the EU. It has a low aqueous solubility, is quite volatile and is not normally expected to leach to groundwater. It can be very persistent in both soil and water systems. It is moderately toxic to mammals and has a high potential for bio-concentration. It is also neurotoxic and a skin and eye irritant. It is highly toxic to birds, fish and moderately toxic to honeybees.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for chlordane

Descripción: An organochlorine insecticide once commonly used to control a range of pests but now obsolete and banned

Ejemplos de plagas controladas: Termites; Ants; Wasps; Cockroaches

Ejemplos de aplicaciones: Corn; Citrus; Vegetables; Turf & laens

Eficacia y actividad: -

Availability status: Obsolete

Introduction & key dates: circa 1950

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur -
Date inclusion expires Expired/Banned
UE Candidatas a sustitución -
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A chiral molecule. Chlordane is a a complex mixture of isomers, other chlorinated hydrocarbons, and a range of by-products
Fórmula química C10H6Cl8
Canonical SMILES C1C2C(C(C1Cl)Cl)C3(C(=C(C2(C3(Cl)Cl)Cl)Cl)Cl)Cl
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) BIWJNBZANLAXMG-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C10H6Cl8/c11-3-1-2-4(5(3)12)9(16)7(14)6(13)8(2,15)10(9,17)18/h2-5H,1H2
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Organochlorine
Minimum active substance purity -
Known relevant impurities Technical chlordane may contain a large number of different compounds including chlordane isomers
Sustancias de origen Sintéticas
Modo de acción Non systemic with contact, stomach and respiratory action. GABA-gated chloride channel antagonist.
CAS RN 57-74-9
CEE número 200-349-0
Número CIPAC 13
EPA américaine chimiques de code 058201
PubChem CID 5993
Masa molecular (g mol-1) 409.78
PIN (Preferred Identification Name) (1E,2E,3aE,4E,7E,7aE)-1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene
Nombre IUPAC 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-hexahydro-4,7-methanoindene
Nombre CAS 1,2,4,5,6,7,8,8-octachloro-2,3,3a,4,7,7a-hexahydro-4,7-methano-1H-indene
Otra información de estado Chemical subject to PIC regulations; POP - regulated by Stockholm Convention; PAN Dirty Dozen; LRTAP Annex I; OSPAR soc; Marine Pollutant; Rotterdam Convention (Class II)
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 2A
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Blattella germanica
Conoderus falli
Ctenocephalides felis
Epitrix tuberis
Psilia rosae
plus others
Estado físico Straw coloured viscous liquid in raw state but powder in product form
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Velsicol
  • Dow
Example products using this active
  • Toxichlor
  • Kypchlor
  • Dowchlor
  • Octachlor
  • Belt
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Available in a variety of different formulations including enulsifiable concentrates, granules, dusts, wettable powders and oils.


DESTINO AMBIENTAL

for chlordane

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.1 G4 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) Miscible L3 - Acetona -
Miscible L3 - Etanol -
Miscible L3 - Ciclohexanona -
Miscible L3 - Isopropanol -
Punto de fusión (oC) 106 F4 -
Punto de ebullición (oC) - - -
El punto de degradación (oC) - - -
Punto de inflamación (oC) - - -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 6.03 X 1002 Calculado -
Log P 2.78 G4 Moderado
Masa densidad (g ml-1)/Peso específico 1.61 F4 -
Disociación constante (pKa) at 25oC No aplicable Q3 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 1.3 G4 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 0.00039 Q3 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -0.77 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 365 L3 Persistente muy alta
DT50 (laboratorio en 20oC) - - -
DT50 (campo) - - -
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota Other sources: DT50 approx 1 year - persistent (R2); 283 days to 3.8 years (R3); FAO state DT50 = 4 years
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor 26.6 R4 -
Nota Published literature RL50 range 2.3-76.0 days, 4 field crops, various matrices, n=4
Acuoso fotólisis DT50 (días) en pH 7 Valor Stable P2 -
Nota Not significant degradation route but rate increases in presence of other chemicals such as acetone
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable P2 -
Nota Not significant degradation route
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) - - -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - G3 No Móvil
Koc 20000
Notas y rango -
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad -

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
oxychlordane Suelo   -   Not assessed under 91/414 or 1107/2009


ECOTOXICOLOGÍA

for chlordane

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 8460 F3 (Whole body, Literature values log BCF range 4.3-4.4 (R3)) Alto potencial
CT50 (días) 1 -
Mamíferos - Agudos oral LD50 (mg kg-1) 460 F4 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 5 G3 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 83 L3 Colinus virginianus Alto
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.09 L3 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.59 L3 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.07 J3 Daphnia magna, LOEC Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) 0.01 R3 Chironomus plumosus Alto
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) - - -
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 6.0 F3 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) - - -
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) - - -
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad - - -
Soil micro-organisms - - -
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for chlordane

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 460 F4 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) 200 L3 Rabbit -
Mammals - Inhalation LC50 (mg l-1) 0.56 L3 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.0005 JMPR 1994 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) - - -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) - - -
Estudios den la absorción cutánea (%) - - -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public Via inhalation and dermal absorption but exposure unlikely as substance obsolete
Source: US EPA
Occupational May be absorbed from the gastrointestinal tract, by inhalation and through the intact skin
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards Non-statutory WHO drinking water guideline 0.0002 mg/L UK EA QS database, 2018 -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana May cause mental confusion and convulsions
IARC Group 2B carcinogen
Possible liver & kidney toxicant
Endocrine issues - Competitive binding to androgen receptors

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Prevent generation of mists
Flammable
Corrosive to some metals
CLP classification 2013 Health: H302, H312, H351
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
Xn - Harmful: R21/22
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S36/37, S60, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) II - Warning - Moderately toxic
Número de las NU 2996
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for chlordane

Idioma Nombre
Inglés chlordane
Francés chlordane
Alemán Chlordan
Danés chlordane
Italiano clordano
Español clordano
Griego chlordane
Esloveno klordan
Polaco chlordan
Sueco -
Húngaro -
Holandés chloordaan

Última actualización del registro: Tuesday 22 May 2018
Contacto: aeru@herts.ac.uk