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clorbenzilato (Ref: ENT 18596)
** chlorobenzilate ** chlorbenzylate ** chlorobenzylate ** G 23992 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Chlorobenzilate is an insecticide with a narrow range of uses and is not approved for use in the EU. It has a low aqueous solubility but miscible with many organic solvents. It is volatile and has a low potential for leaching to groundwater. It is not expected to persist in soil systems. Chlorobenzilate has a low mammalian toxicity but there are some concerns regarding its potential for bio-concentration. It has a low toxicity to birds, a moderate toxicity for fish and honeybees.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for chlorobenzilate

Descripción: An obsolete non-systemic acaricide that was used to control mites on fruit and also in bee hives

Ejemplos de plagas controladas: Mites; Ticks

Ejemplos de aplicaciones: Citrus; Walnuts; Beehives; Cotton; Grapes

Eficacia y actividad: -

Availability status: Obsolete

Introduction & key dates: circa 1953

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur No aplicable
Date inclusion expires Expired
UE Candidatas a sustitución -
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism None
Fórmula química C16H14Cl2O3
Canonical SMILES CCOC(=O)C(C1=CC=C(C=C1)Cl)(C2=CC=C(C=C2)Cl)O
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) RAPBNVDSDCTNRC-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C16H14Cl2O3/c1-2-21-15(19)16(20,11-3-7-13(17)8-4-11)12-5-9-14(18)10-6-12/h3-10,20H,2H2,1H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Acaricide, Miticide
Grupo químico Organochlorine
Minimum active substance purity -
Known relevant impurities -
Sustancias de origen Sintéticas
Modo de acción Nervous system toxin with contact action
CAS RN 510-15-6
CEE número 208-110-2
Número CIPAC 119
EPA américaine chimiques de code 028801
PubChem CID 10522
Masa molecular (g mol-1) 325.19
PIN (Preferred Identification Name) ethyl bis(4-chlorophenyl)hydroxyacetate
Nombre IUPAC ethyl 4,4'-dichlorobenzilate
Nombre CAS ethyl 4-chloro-α-(4-chlorophenyl)-a-hydroxybenzeneacetate
Otra información de estado Chemical subject to PIC regulations; Rotterdam Convention (Class O); Phytotoxic to some top fruit.
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 2A
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Aculus pelekassi
Panonychus ulmi
Tetranychus mcdanieli
Tetranychus urticae
Galerucella birmanica
plus others
Estado físico Colourless solid when pure
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Makhteshim-Agan
  • Ciba-Geigy AG
  • Nippon Kayaku
Example products using this active
  • Folbex smoke-strips
  • Kop-Mite
  • Akar
  • Acaraben
  • Folbex
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually supplied as an emulsifiable concentrate or as a wettable powder.


DESTINO AMBIENTAL

for chlorobenzilate

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 10 G4 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) Miscible A4 - Acetona -
Miscible A4 - Metanol -
600000 A4 - Hexano -
Miscible A4 - Tolueno -
Punto de fusión (oC) 37 A4 -
Punto de ebullición (oC) - - -
El punto de degradación (oC) - - -
Punto de inflamación (oC) - - -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 3.80 X 1004 Calculado -
Log P 4.58 H4 Alto
Masa densidad (g ml-1)/Peso específico 1.33 Q2 -
Disociación constante (pKa) at 25oC - - -
Nota:
Presión de vapor en 20oC (mPa) 0.12 G4 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 2.27 X 10-02 H4 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.72 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.27 X 10-02 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 23 G4 No persistente
DT50 (laboratorio en 20oC) 20 Q2 No persistente
DT50 (campo) - - -
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota Best available data
Dissipation rate RL50 on plant matrix Valor 10.8 R4 -
Nota Published literature RL50 range 4.8-18.0 days, 2 citrus crops, various matrices, n=5
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor - - -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor - - -
Nota -
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) - - -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - H3 Móvil un poco
Koc 2810
Notas y rango Best available data
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad -


ECOTOXICOLOGÍA

for chlorobenzilate

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 750 Q2 Estimado Umbral de importancia
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2784 G4 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 2250 F4 Anas platyrhynchos Bajo
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.7 G4 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.01 F2 Daphnia magna, LT50 Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) - - -
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) - - -
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) - - -
Oral aguda 48 hora LD50 (μg abeja-1) - - -
Modo desconocido aguda 48 hora LD50 (μg abeja-1) 1.01 A3 Moderado
Lombrices - Agudos 14 día LC50 (mg kg-1) - - -
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad - - -
Soil micro-organisms - - -
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for chlorobenzilate

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2784 G4 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) - - -
Mammals - Inhalation LC50 (mg l-1) - - -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.02 JMPR 1980 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) - - -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) - - -
Estudios den la absorción cutánea (%) - - -
Directivo 76/464 Sustancias Peligrosas List I; List II - -
Limites de exposiciones - - -
Exposure Routes Public -
Occupational -
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

-

Cuestiones generales de la salud humana IARC Group 3 carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Incompatible with highly alkaline materials
CLP classification 2013 Health: H302
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S60, S61
Clasificación de OSM O - Sustancia obsoletos
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for chlorobenzilate

Idioma Nombre
Inglés chlorobenzilate
Francés chlorobenzilate
Alemán Chlorbenzilat
Danés chlorobenzilat
Italiano clorobenzilato
Español clorbenzilato
Griego chlorobenzilate
Esloveno klorbensilat
Polaco chlorobenzylat
Sueco -
Húngaro -
Holandés chloorbenzilaat

Última actualización del registro: Tuesday 22 May 2018
Contacto: aeru@herts.ac.uk