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cletodin (Ref: RE 45601)
** clethodim ** cletodime ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for clethodim

Descripción: A herbicide used to control annual and perennial grasses for use on sugarbeet and other crops

Ejemplos de plagas controladas: Barnyardgrass; Brome; Canarygrass; Crabgrass; Foxtail; Goosegrass; Ryegrass; Foxtails; Shattercane; Volunteer cereals

Ejemplos de aplicaciones: Sugarbeet; Soybeans; Potatoes; Sunflowers; Alfalfa; Vegetables including beans & peas, asparagus, carrots, eggplant; Cotton; Fax; Peanuts; Fruit including melons, peaches; Herbs

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1987, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Netherlands
Date inclusion expires 31/05/2021
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A chiral molecule existing in the (E) and (Z) isomeric forms
Fórmula química C17H26ClNO3S
Canonical SMILES CCC(=C1C(=O)CC(CC1=O)CC(C)SCC)NOCC=CCl
Isomeric SMILES CCC(=C1C(=O)CC(CC1=O)CC(C)SCC)NOC/C=C/Cl
International Chemical Identifier Key (InChIKey) SILSDTWXNBZOGF-JWGBMQLESA-N
International Chemical Identifier (InChI) InChI=1S/C17H26ClNO3S/c1-4-14(19-22-8-6-7-18)17-15(20)10-13(11-16(17)21)9-12(3)23-5-2/h6-7,12-13,20H,4-5,8-11H2,1-3H3/b7-6?,19-14+
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Herbicida
Grupo químico Cyclohexanedione
Minimum active substance purity >930 g/kg
Known relevant impurities EU dossier - toluene < 4g/kg
Sustancias de origen Sintéticas
Modo de acción Selective, systemic. An acetyl CoA carboxylase inhibitor (ACCase).
CAS RN 99129-21-2
CEE número -
Número CIPAC 508
EPA américaine chimiques de code 121011
PubChem CID 6444391
Masa molecular (g mol-1) 359.92
PIN (Preferred Identification Name) (5?)-2-[(1?)-N-{[(2E)-3-chloroprop-2-en-1-yl]oxy}propanimidoyl]-5-[(2?)-2-(ethylsulfanyl)propyl]-3-hydroxycyclohex-2-en-1-one
Nombre IUPAC (5RS)-2-{(E)-1-[(2E)-3-chloroallyloxyimino]propyl}-5-[(2RS)-2-(ethylthio)propyl]-3-hydroxycyclohex-2-en-1-one
Nombre CAS 2-[(1E)-1-[[[(2E)-3-chloro-2-propenyl]oxy]imino]propyl]-5-[2-(ethylthio)propyl]-3-hydroxy-2-cyclohexen-1-one
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) A
Herbicide Resistance Classification (WSSA) 1
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Many recorded cases
Alopecurus myosuroides
Avena fatua
Bromus tectorum
Hordeum leporinum
Estado físico Viscous amber to green-yellow coloured liquid depending upon purity
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Arysta LifeSciences FRANCE
  • Agan Chemicals
  • Loveland Products
Example products using this active
  • Select 12 SC
  • Select 240
  • Centurion
Estado de UK LERAP None
Formulation and application details Usually available as an emulsifiable concentrate that is mixed with water and used as a spray.


DESTINO AMBIENTAL

for clethodim

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 5450 A5 Alto
Solubilidad - en solventes organicos en 20oC (mg l-1) 100000 A5 - Xileno -
100000 A5 - Metanol -
900000 A5 - Acetona -
900000 A5 - Acetato de etilo -
Punto de fusión (oC) -80 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 100.5 A5 -
Punto de inflamación (oC) - - -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.38 X 1004 Calculado -
Log P 4.14 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.16 A5 -
Disociación constante (pKa) at 25oC 4.47 A5 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 2.08 X 10-03 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 1.4 X 10-07 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -0.69 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 6.26 X 10-04 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 256nm = 13183, 203nm = 13490; [Acidic solution: 258nm = 12882, 207nm = 12589; [Basic solution: 210nm = ??, 282nm = 21878 A5 -
Surface tension (mN m-1) 52.9 A5 at 21oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 0.55 Click here to see a warning relating to modelling and this active substance A5 No persistente
DT50 (laboratorio en 20oC) 0.55 A5 No persistente
DT50 (campo) 3 Y4 No persistente
DT90 (laboratorio en 20oC) 2.61 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 0.17-3.04 days, DT90 range 0.76-8.50 days; Other studies: DT50 1-3 days (R3)
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 5.45 A4 - @ 25degC Moderado rápido
Nota pH sensitive: DT50 1.6 @ pH 5, 7.79 @ pH 9 all @ 25 degC
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota pH sensitive: DT50 41 days at pH 5, stable pH 7 and pH 9 all at 25 degC
Aqua-Sedimento DT50 (días) 16.7 A4 Rápido
Fase de agua sola DT50 (días) 7.0 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 0.39 A5 Móvil
Kfoc 22.7
1/n 1.01
Notas y rango EU dossier Kf range 0.065-0.112, Kfoc range 2.71-43.17, 1/n range 0.97-1.04, Soils=3
pH senbsibilidad Yes

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
clethodim sulfoxide This metabolite may cause environmental pollution, click here for further information Suelo   0.730   Major fraction, Relevant
clethodim sulfone This metabolite may cause environmental pollution, click here for further information Suelo   0.16   Major fraction, Relevant
clethodim oxazole sulfone This metabolite may cause environmental pollution, click here for further information Suelo   0.100   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
- clethodim imine ketone Water (Photolysis) - -
- clethodim isoxazole Soil (Anaerobic) - -
- clethodim oxazole sulfoxide Water (Photolysis); Soil (Aerobic) - -
- clethodim oxazole Soil (Aerobic) - -
- clethodim imine sulfoxide Soil (Aerobic) - -
- 3-chloropropenal Water (Photolysis) - -
- clethodim oxazole sulfide Water (Photolysis) - -
- clethodim trione sulfoxide Water (Photolysis) - -
- clethodim chloroallyl alcohol Water (Photolysis) - -


ECOTOXICOLOGÍA

for clethodim

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 2.1 A5 Whole fish Bajo potencial
CT50 (días) 4.9 -
Mamíferos - Agudos oral LD50 (mg kg-1) 1133 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 30 Z2 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 1640 A5 Colinus virginianus Moderado
Birds - Short term dietary (LC50/LD50) > 851 mg kg-1 bw/día A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 25 A5 Salmo gairdneri Moderado
Pez - Crónico 21 días NOEC (mg l-1) 3.9 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 100 A5 Daphnia magna Bajo
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 49 A5 Daphnia magna Bajo
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 1.9 A5 Lemna gibba Moderado
Non-target plants 6.7 A5 Ryegrass
Vegetative vigour, ER50
as g/ha
-
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 12.0 A5 Pseudokirchneriella subcapitata Bajo
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 51 A5 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) > 43 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 454 L3 Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 240 >
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 9.6 <
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 2.7 mg kg-1, effects may be significant at higher doses
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for clethodim

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 1133 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 4167 A5 Rabbit -
Mammals - Inhalation LC50 (mg l-1) < 3.25 A5 Rat, 4 hr (whole body) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.16 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.20 A2 Dog, SF=100 -
Estudios den la absorción cutánea (%) 15-42 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Acceptable risk for proposed uses
Occupational Acceptable risk for proposed uses
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; A5 Calc MAC=25.0 μg l-1 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Moderately toxic
Possible liver and blood toxicant

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxiding
CLP classification 2013 Health: H302, H317
Environment: H412
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for clethodim

Idioma Nombre
Inglés clethodim
Francés clethodim
Alemán Clethodim
Danés clethodim
Italiano cletodim
Español cletodin
Griego -
Esloveno kletodim
Polaco kletodym
Sueco kletodim
Húngaro kletodim
Holandés -

Última actualización del registro: Thursday 13 September 2018
Contacto: aeru@herts.ac.uk