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oxicloruro de cobre
** copper oxychloride ** dicopper chloride trihydroxide ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

A widely used copper fungicide that is approved for use in many countries including at EU level. It has a low aqueous solubility and a low volatility. As a heavy metal, copper itself will not degrade in the environment. It is moderately toxic to mammals and most biodiversity.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for copper oxychloride

Descripción: A protectant copper fungicide and bactericide used as a foliar spray

Ejemplos de plagas controladas: Leaf spot; Downy mildew

Ejemplos de aplicaciones: Ornamentals; Beet crops; Olives; Grapes; Tomatoes

Eficacia y actividad: Copper based products have been shown to be affective against many fungal pathogens in field trials.

Availability status: Current

Introduction & key dates: circa 1990

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur France/Germany
Date inclusion expires 31/12/2025
UE Candidatas a sustitución Yes - two 'Persistent-Bioaccumulative-Toxic' criteria
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism None
Fórmula química (ClCu2H3O3)2
Canonical SMILES O(Cl)Cl.[Cu+2]
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) CPOSXJRGXIJOHG-UHFFFAOYSA-I
International Chemical Identifier (InChI) InChI=1S/2ClH.2Cu.3H2O/h2*1H;;;3*1H2/q;;2*+2;;;/p-5
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide, Repellent
Grupo químico Inorganic compound
Minimum active substance purity >569 6/Kg total copper
Known relevant impurities EU 2018 dossier: May contain heavy metals including Pb, Cd, As, Ni, CO, Sb & Hg
Sustancias de origen Sintéticas
Modo de acción Absorbed copper disrupts the enzyme systems of pathogens. Multi-site activity.
CAS RN 1332-40-7
CEE número 215-572-9
Número CIPAC 44.602
EPA américaine chimiques de code -
PubChem CID 18629822
Masa molecular (g mol-1) 427.14
PIN (Preferred Identification Name) dicopper(II) chloride trihydroxide
Nombre IUPAC dicopper chloride trioxide
Nombre CAS copper chloride hydroxide
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) M1/2
Examples of recorded resistance -
Estado físico Blue-green powder
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Headland
  • Unicrop
  • United Phosphorus
  • BASF
  • Rhone-Poulenc
  • Sandoz
Example products using this active
  • Headland Copper
  • Cupravit
  • Pere-col
  • Recop
Estado de UK LERAP None
Formulation and application details Usually supplied as a soluble concentrate or wettable powder that is mixed with water and applied as a spray.


DESTINO AMBIENTAL

for copper oxychloride

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 1.19 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 9.8 A5 - n-Hexano -
10 A5 - Cloruro de metileno -
8.2 A5 - Metanol -
11.0 A5 - Tolueno -
Punto de fusión (oC) Decomposes before melting A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 240 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.75 X 1000 Calculado -
Log P 0.44 A2 Bajo
Masa densidad (g ml-1)/Peso específico - - -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 0.00001 C4 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) - - -
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index - - -
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor - - -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - - -
Maximum UV-vis absorption L mol-1 cm-1 Acidic soln: 205nm=2850, 250nm=1461, 800nm=38, 290nm=260, 295nm=195 A5 -
Surface tension (mN m-1) 72.2 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general Not biodegradable
Degradación de suelo (días) (aerobic) DT50 (típico) 10000 A2 Persistente muy alta
DT50 (laboratorio en 20oC) - - -
DT50 (campo) - - -
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU 2018 dossier: No degradation expected
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor 17.2 R3 -
Nota Potato leaves, n=1
Acuoso fotólisis DT50 (días) en pH 7 Valor Estable A5 -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota -
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) - - -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad -


ECOTOXICOLOGÍA

for copper oxychloride

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) Low risk A5 Based on LogP < 3 Bajo potencial
CT50 (días) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 299 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 173 A5 Colinus virginianus as copper Moderado
Birds - Short term dietary (LC50/LD50) 333 mg Cu/kg bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) > 43.8 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.29 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.006 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 165.9 A5 Pseudokirchneriella subcapitata Bajo
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 44.3 A5 Apis mellifera Moderado
Oral aguda 48 hora LD50 (μg abeja-1) 12.1 A5 Apis mellifera Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 489.6 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) < 40.5 A5 Eisenia foetida, as Cu, 56 días Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 3.97 As Cu
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 14.9 As Cu
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 18.1 kg Cu/ha; 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for copper oxychloride

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 299 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A4 Rat -
Mammals - Inhalation LC50 (mg l-1) 2.83 A5 Rat (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.15 A5 Dog, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) Ningunos asignaron A5 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.072 A5 Rat, SF=30 -
Estudios den la absorción cutánea (%) 1-9 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones [TWA (air) 1 mg Cu/m3] - -
Exposure Routes Public Negligible risk to bystanders for proposed uses
Occupational Acceptable risk to operators and workers for proposed uses with PPE/PPC
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards Statutory EU standard for total copper in drinking water: 2 mg/L
Non-statutory WHO guideline for total copper in drinking water: 2 mg/L
UK EA QS database, 2018 -
Drinking Water MAC (μg l-1) 2000 EU Dir 89/778/EC limit as Cu, A5 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana Potential heavy metal poisoning

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes May emit toxic chlorine gas under certain conditions
Not explosive or oxidising
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H301, H332
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R20, R22
N - Dangerous for the environment: R50-53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU Variable with product, usually 3010, 3077 or 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for copper oxychloride

Idioma Nombre
Inglés copper oxychloride
Francés cuivre de l'oxychlorure de cuivre
Alemán Kupferoxychlorid
Danés kobberoxyklorid
Italiano ossicloruro di rame
Español oxicloruro de cobre
Griego -
Esloveno bakrov oksiklorid
Polaco tlenochlorek miedzi
Sueco -
Húngaro réz-oxiklorid
Holandés -

Última actualización del registro: Wednesday 03 April 2019
Contacto: aeru@herts.ac.uk