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cimoxanilo (Ref: DPX T3217)
** cymoxanil ** cimoxanil ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Cymoxanil is a fungicide approevd for use in the EU and many other countries. It is highly soluble in water and considered quite volatile. It has a low potential for leaching to groundwater, is non persistent in soil and water systems. Cymoxanil is moderately toxic to mammals, may cause adverse effects on reproduction/development and has a high potential to bio-concentrate. It is moderately toxic to most aquatic organisms, earthworms and honeybees but less so to birds.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for cymoxanil

Descripción: A fungicide used to control pathogens on a range of crops including potatoes and other crops.

Example pests controlled: Foliar late blight; Downy mildew; Powdery mildew

Example applications: Potatoes; Tomatoes; Grapes; Hops; Sugarbeet; Vines

Availability status: Current

Introduction & key dates: 1976, first reported; mid 1970s first marketed

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Austria
Date inclusion expires 31/08/2019

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Estados Unidos

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Cyanoacetamide oxime
Minimum active substance purity 970 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Foliar with protective and curative activity.
CAS RN 57966-95-7
CEE número 261-043-0
Número CIPAC 419
EPA américaine chimiques de code 129106
Chiral molecule No
Fórmula química C7H10N4O3
SMILES N#C/C(=N\OC)C(=O)NC(=O)NCC
International Chemical Identifier Key (InChIKey) XERJKGMBORTKEO-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C7H10N4O3/c1-3-9-7(13)10-6(12)5(4-8)11-14-2/h3H2,1-2H3,(H2,9,10,12,13)/b11-5+
¿Es el diagrama de la estructura/imagen disponible?
Masa molecular (g mol-1) 198.18
PIN (Preferred Identification Name) (2E)-2-cyano-N-(ethylcarbamoyl)-2-(methoxyimino)acetamide
Nombre IUPAC 1-[(EZ)-2-cyano-2-methoxyiminoacetyl]-3-ethylurea
Nombre CAS 2-cyano-N-[(ethylamino)carbonyl]-2-(methoxyimino)acetamide
Otra información de estado -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 27
Examples of recorded resistance -
Estado físico White to pale pink crystals
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Belchim
  • DuPont
  • Headland
  • Nufarm
  • Syngenta
Example products using this active
  • Besiege
  • Curzate
  • Matilda WG
  • Option
  • Tanos
  • Wakil XL
Estado de UK LERAP None
Formulation and application details Often supplied as wettable granules or powders that are mixed with water and applied as a spray or used as a seed treatment.


DESTINO AMBIENTAL

for cymoxanil

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 780 A5 Alto
Solubilidad - en solventes organicos en 20oC (mg l-1) 28000 A5 - Acetato de etilo -
65300 A5 - Acetona -
5290 A5 - Tolueno -
37 A5 - n-Hexano -
Punto de fusión (oC) 161 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 156 A3 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 4.68 X 1000 Calculado -
Log P 0.67 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.31 L3 -
Disociación constante (pKa) at 25oC 9.3 A5 -
Nota: Ácido débil
Presión de vapor en 25oC (mPa) 0.15 A5 Volátil
Constante de Henry a 25oC (Pa m3 mol-1) 3.80 X 10-05 A5 No volátil
Constante de Henry a 20oC (dimensionless) 6.40 X 10-12 K3 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.34 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.15 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 244nm = 9333 & 9297 A5 -
Surface tension (mN m-1) 68.7 A5 at 19oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Degradación de suelo (días) (aerobic) DT50 (típico) 0.7 Click here to see a warning relating to modelling and this active substance K4 No persistente
DT50 (laboratorio en 20oC) 1.4 A5 No persistente
DT50 (campo) 3.5 H4 No persistente
DT90 (laboratorio en 20oC) 4.7 A5 -
DT90 (campo) - - -
Nota EU dossier Lab studies DT50 range 0.2-7.3 days, DT90 range 0.5-33.3 days
Matriz de la planta DT50 (días) Valor 1.2 R3 -
Nota DT50 range 1.1 - 1.3 days, potato, tuber matrix
Acuoso fotólisis DT50 (días) en pH 7 Valor 1.7 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 1.1 A5 No persistente
Nota Stable at pH 4 and pH 5 @20deg C, DT50 0.02 days at pH 9 and 25 degC
Aqua-Sedimento DT50 (días) 0.3 A5 Rápido
Fase de agua sola DT50 (días) 0.3 A5 Rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 0.580 A5 Móvil
Kfoc 43.6
1/n 0.86
Notas y rango EU dossier kf range 0.09-0.91, Kfoc range 15.1-87.1 mL/g, 1/n range 0.81-0.88, Soils=4
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 91/414 Importancia Click here for further information on 91/414 relevancy
1-ethyl 5,6-di-2,4(1H,3H)pyridenedione (Ref: IN-U3204) This metabolite may cause environmental pollution, click here for further information Suelo   0.247   Major fraction, Relevant
2-cyano-2-methoxyiminoacetic acid (Ref: IN-W3595) This metabolite may cause environmental pollution, click here for further information Suelo   0.101   Major fraction, Relevant
3-ethyl-4-(methoxyamino)-2,5-dioxoimidazolidine-4-carboxamide (Ref: IN-KQ960) Suelo   0.063   Minor fraction, Relevant
3-ethyl-4-(methoxyamino)-2,5-dioxoimidazolidine-4-carbonitrile (Ref: IN-JX915) Suelo   0.076   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
ethylimidazolidinetrione-5-(o-methyloxime) - Soil (Aerobic) - -
{[(ethylamino)carbonyl]}ethylamino)carbonyl]amino}oxoacetic acid
(Ref: IN-KP533)
- - - -
cyano(methoxyimino)acetic acid
(Ref: IN-U3595)
- - - -
1-ethyl-5-(methoxyimino)2,4-imidazolidin-2,4-dione
(Ref: R3273)
- - - -


ECOTOXICOLOGÍA

for cymoxanil

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) Low risk A5 Based on LogP < 3 Bajo potencial
CT50 (días) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 760 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 47.6 F4 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2945 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 29 A5 Lepomis macrochirus Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.22 F4 Oncorhynchus mykiss, LOEC Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 27 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.067 F4 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 44.4 F3 Americamysis bahia Moderado
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 0.7 A5 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.254 A5 Anabaena flos-aquae Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 85.3 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 1000 A5 Eisenia foetida Bajo
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 6.6 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 >480 A5 Aphidius rhopalosiphi, adult -
% Causalidad 0
34
Mortalidad
Fecundity
Dose: 0.26 kg ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 >480 A5 Typhlodromus pyri -
% Causalidad 98.9
100
Mortalidad
Reproducción
Dose: 0.13 kg ha-1
A5 Typhlodromus pyri
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 1.44 kg ha-1
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for cymoxanil

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 760 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.6 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.013 A5 Dog, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.08 A5 Rabbit, SF=100 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.01 A5 Dog, SF=100 -
Estudios den la absorción cutánea (%) 1.0-75.0 A5 concentration dependant -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Acceptable risk to bystanders for intended uses
Occupational Acceptable risk to operators wearing protective clothing
European MRLs Click here for the EU MRL pesticide database
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; A5 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana No further information available

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 9
CLP classification 2013 Health: H302, H317, H361fd, H373
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22, R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S36/37, S60, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU Usually 3077
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for cymoxanil

Idioma Nombre
Inglés cymoxanil
Francés cymoxanil
Alemán Cymoxanil
Danés cymoxanil
Italiano cimoxanil
Español cimoxanilo
Griego -
Esloveno cimoksanil
Polaco cymoksanil
Sueco cymoxanil
Húngaro cymoxanil
Holandés cymoxanil

Última actualización del registro: Saturday 13 August 2016
Contacto: aeru@herts.ac.uk