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fluxapyroxad (Ref: BAS 700F)
** fluxapyroxad ** BAS 700 000 F ** Xemium ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for fluxapyroxad

Descripción: A new pesticide active substance that effective controls a broad spectrum of fungal pathogens in cereals and other food crops

Ejemplos de plagas controladas: Botrytis mould; Powdery mildew; Early blight; Rust

Ejemplos de aplicaciones: Cereals; Legumes; Oilseeds including OSR, sunflowers; Top and stone fruit; Tuber and root vegetables; Peanuts

Eficacia y actividad: Wheat/Septoria=High; Wheat/Rust=Moderate; Barley/Rhynchosporium=High; Barley/Mildew=Low; Barley/Rust=Moderate, Barley/Net blotch=High

Availability status: Current

Introduction & key dates: 2011, First introduced UK; 2012, European market

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK/France
Date inclusion expires 31/12/2022
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C18H12F5N3O
Canonical SMILES CN1C=C(C(=N1)C(F)F)C(=O)NC2=CC=CC=C2C3=CC(=C(C(=C3)F)F)F
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) SXSGXWCSHSVPGB-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C18H12F5N3O/c1-26-8-11(16(25-26)17(22)23)18(27)24-14-5-3-2-4-10(14)9-6-12(19)15(21)13(20)7-9/h2-8,17H,1H3,(H,24,27)
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Pyrazolium
Minimum active substance purity 950 g/kg
Known relevant impurities EU dossier - toluene max 1g/kg
Sustancias de origen -
Modo de acción Has proventative and curative properties and works by preventing spore gemination and infection development. Succinate DeHydrogenase Inhibitor.
CAS RN 907204-31-3
CEE número -
Número CIPAC 828
EPA américaine chimiques de code 138009
PubChem CID 16095400
Masa molecular (g mol-1) 381.31
PIN (Preferred Identification Name) 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-biphenyl]-2-yl)-1H-pyrazole-4-carboxamide
Nombre IUPAC 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluorobiphenyl-2-yl)pyrazole-4-carboxamide
Nombre CAS 3-(difluoromethyl)-1-methyl-N-(3',4',5'-trifluoro[1,1'-biphenyl]-2-yl)-1H-pyrazole-4-carboxamide
Otra información de estado PAN listed Highly Hazardous Chemical
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 7
Examples of recorded resistance -
Estado físico Crystalline powder
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • BASF Corp
Example products using this active
  • Imbrex
  • Sercadis
  • Acceleron
  • Priaxor
  • Merivon
Estado de UK LERAP Normally Category B
Formulation and application details Supplied as an emulsifiable concentrate and applied as a foliar spray also often used as a seed dressing.


DESTINO AMBIENTAL

for fluxapyroxad

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 3.44 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 250000 A5 - Acetona -
123300 A5 - Acetato de etilo -
53400 A5 - Metanol -
20000 A5 - Tolueno -
Punto de fusión (oC) 156.8 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 230 A4 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable - -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.35 X 1003 Calculado -
Log P 3.13 A5 Alto
Masa densidad (g ml-1)/Peso específico - - -
Disociación constante (pKa) at 25oC 12.58 A5 -
Nota:
Presión de vapor en 20oC (mPa) 2.7 X 10-06 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 3.03 X 10-07 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 2.57 Calculado Estado de transición
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.85 X 10-01 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Acidic soln: 199nm = 35913, 230nm = 24137; [Neutral soln: 203nm = 31582, 229nm = 23928; [Basic soln: 229 nm = 23473, 215nm = 23227 A5 -
Surface tension (mN m-1) 73.3 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 183 A5 Persistente
DT50 (laboratorio en 20oC) 183 A5 Persistente
DT50 (campo) - - -
DT90 (laboratorio en 20oC) 650 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 53.0-424 days, DT90 range 229 - >1000 days
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor - - -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor - - -
Nota -
Aqua-Sedimento DT50 (días) >847 A5 -
Fase de agua sola DT50 (días) 4.4 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 8.3 A5 Móvil un poco
Kfoc 728
1/n 0.914
Notas y rango EU dossier Kf range 2.5-17.9, Kfoc range 320-1101 mL/g, 1/n range 0.875-0.942, Soils=8
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxylic acid (Ref: M700F001) This metabolite may cause environmental pollution, click here for further information Suelo   0.139   Major fraction, Relevant
3-(difluoromethyl)-1H-pyrazole-4-carboxylic acid (Ref: M700F002) This metabolite may cause environmental pollution, click here for further information Suelo   0.389   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
3-(difluoromethyl)-1-methyl-N-(4-hydroxy-3,4,5-trifluoro[1,1-biphenyl]-2-yl)-1H-pyrazole-4-carboxamide
(Ref: M700F005)
- Animal, Plant - -
3-(difluoromethyl)-1-methyl-N-(hydroxy-3,4,5-trifluoro[1,1-biphenyl]-2-yl)-1H-pyrazole-4-carboxamide
(Ref: M700F006)
- Animal, Plant - -
3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide
(Ref: M700F007)
- Surface water - -
3-(difluoromethyl)-1-methyl-1H-pyrazole-4-carboxamide
(Ref: M700F007)
- Plant - -
3-(difluoromethyl)-N-(3,4,5-trifluoro[1,1-biphenyl]-2-yl)-1H-pyrazole4-carboxamide
(Ref: M700F008)
- Animal - -
3-(difluoromethyl)-N-(hydroxy-3,4,5-trifluoro[1,1-biphenyl]-2-yl)-1H-pyrazole-4-carboxamide
(Ref: M700F008)
- Animal, Plant - -
3-(difluoromethyl)-1-(beta-D-glucopyranosyl)-N-(3,4,5-trifluoro[1,1-biphenyl]-2-yl)-1H-pyrazole-4-carboxamide
(Ref: M700F048)
- Plant - -


ECOTOXICOLOGÍA

for fluxapyroxad

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 36 A5 Bajo potencial
CT50 (días) 0.73 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 912 mg kg-1/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.546 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.036 A5 Pimephales promelas Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 6.78 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.5 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 3.43 A5 Lemna gibba Moderado
Non-target plants > 2.0 A4 Unknown species
Vegetative vigour, ER50
as L product/ha (BAS 700 00 F: Conc 62.5 g/L)
-
> 2.0 A4 Unknown species
Seedling emergence, ER50
as L product/ha (BAS 700 00 F: Conc 62.5 g/L)
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.70 A5 Pseudokirchnella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 110.9 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 1000 A5 Eisenia foetida Bajo
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 0.128 Mortality, as L product ha-1 (BAS 700 00 F: Conc 62.5 g/L)
A5 Typhlodromus pyri
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 4.70 Mortality, as L product ha-1 (BAS 700 00 F: Conc 62.5 g/L)
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 2.01 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for fluxapyroxad

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.31 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.02 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.25 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.04 A5 Rat, SF=100 -
Estudios den la absorción cutánea (%) 0.16-8 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Moderate to low risk for bystanders suggested
Occupational PPE/PPC advised
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

-

Cuestiones generales de la salud humana Possible liver, prostrate and thyroid toxicant

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Non-oxidising and non-explosive
CLP classification 2013 Health: H317, H319, H332, H351, H361d
Environment: H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
N - Dangerous for the environment: R50/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S13, S20/21, S36/37, S46, S60, S61
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) III or IV - -
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for fluxapyroxad

Idioma Nombre
Inglés fluxapyroxad
Francés fluxapyroxade
Alemán -
Danés -
Italiano -
Español -
Griego -
Esloveno -
Polaco -
Sueco -
Húngaro -
Holandés -

Última actualización del registro: Friday 14 September 2018
Contacto: aeru@herts.ac.uk