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deltametrin (Ref: OMS 1998)
** deltamethrin ** decamethrin ** deltamethrine ** AE F032640 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio
Otros datos se pueden encontrar en el VSDB

RESUMEN

Deltamethrin is a pyrethroid insecticide and veterinary treatment that is approved for use in the EU, Australia and the USA. It has a low aqueous solubility, is semi-volatile and has a low potential to leach to groundwater. It is not persistent in soil and is non-mobile. Deltamethrin is highly toxic to humans and other mammals and is a neurotoxin. It is relatively non-toxic to birds and earthworms although it presents a high risk to most aquatic organisms and honeybees.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for deltamethrin

Descripción: A fast-acting insecticide used to control a wide range of sucking and chewing pests

Ejemplos de plagas controladas: Cockroaches; Spiders; Ants; Fleas; Aphids; Silverfish; Bed bugs; Bird mites; Mosquitoes; House flies; beetles

Ejemplos de aplicaciones: Sugar beet; Cauliflower; Wheat; Tomatoes; Lettuce; Maize; Sweetcorn; Potatoes; Olives; Top fruit; Commercial, industrial and public buildings; Public health situations; Stored produce

Eficacia y actividad: Efficiacy is demonstrated from extensive use and field trials

Availability status: Current

Introduction & key dates: 1974, first described

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK/Austria
Date inclusion expires 31/10/2020
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A chiral molecule. Deltamethrin is the cis-isomer of 8 stereoisomeric esters of the dibromo analogue of chrysanthemic acid.
Fórmula química C22H19Br2NO3
Canonical SMILES CC1(C(C1C(=O)OC(C#N)C2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Br)Br)C
Isomeric SMILES CC1([C@H]([C@H]1C(=O)O[C@H](C#N)C2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Br)Br)C
International Chemical Identifier Key (InChIKey) OWZREIFADZCYQD-NSHGMRRFSA-N
International Chemical Identifier (InChI) InChI=1S/C22H19Br2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-5-9-15/h3-12,17-18,20H,1-2H3/t17-,18+,20-/m0/s1
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Deltamethrin Isomer Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Metabolite, Veterinary substance
Metabolite Type Suelo
Grupo químico Pyrethroid
Minimum active substance purity 985 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action. Sodium channel modulator.
CAS RN 52918-63-5
CEE número 258-256-6
Número CIPAC 333
EPA américaine chimiques de code 978051
PubChem CID 40585
Masa molecular (g mol-1) 505.2
PIN (Preferred Identification Name) (S)-cyano(3-phenoxyphenyl)methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropane-1-carboxylate
Nombre IUPAC (S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate
Nombre CAS (S)-cyano(3-phenoxyphenyl)methyl (1R,3R)-3-(2,2-dibromoethenyl)-2,2-dimethylcyclopropanecarboxylate
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 3A
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Aphis gossypii
Cavariella salicicola
Cydia pomonella
Leptinotarsa decemlineata
Musca domestica
Earias vittella
many others
Estado físico Colourless crystals
Related substances & organisms -

Puede ser un metabolito de
Padre/origen Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
tralomethrin Soil   0.400   Major fraction, Relevancy unknown

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgriGuard
  • Bayer CropScience
  • Certis
  • Headland
  • Landgold
Example products using this active
  • Bandu
  • Decis
  • Decis Protect
  • Decis Protech
  • Pearl Micro
  • Decis EW15
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as an emulsifiable concentrate which is mixed with water and applied as a spray, pour-on or spot-on.


DESTINO AMBIENTAL

for deltamethrin

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.0002 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 450000 A5 - Acetona -
175000 A5 - Xileno -
8150 A5 - Metanol -
2470 A5 - n-Heptano -
Punto de fusión (oC) 101 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) - - -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 3.98 X 1004 Calculado -
Log P 4.6 A5 Alto
Masa densidad (g ml-1)/Peso específico 0.55 L3 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 0.0000124 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 3.10 X 10-02 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -3.98 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 267, 271 and 278nm, Low to very low absorption at 290-300nm A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 58.2 A5 Persistente moderado
DT50 (laboratorio en 20oC) 28.2 A5 No persistente
DT50 (campo) 21 A5 No persistente
DT90 (laboratorio en 20oC) 87 A5 -
DT90 (campo) 60 A3 -
Endpoint de modelado DT50 - - -
Nota EU dossier 2017 lab studies (normalised) DT50 range 12.5-231 days, Soils=22; EU 2002 dossier Lab studies DT50 range 18-35 days, DT90 range 58-117 days, field studies DT50 1-4 wks with realistic estimate of 3 wks (Germany), DT90 estimates range 1 month to 1 year; Other sources: 104 days (DW4)
Dissipation rate RL50 on plant matrix Valor 6.5 R4 -
Nota Published literature RL50 range 1.6-15.0 days, 34 field & undercover grown crops, various matrices, n=43
Dissipation rate RL50 on and in plant matrix Valor 3.0 R4 -
Nota Published literature RL50 range 0.5-7.7 days, 14 field & undercover grown crops, various matrices, n=23
Acuoso fotólisis DT50 (días) en pH 7 Valor - - -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota pH sensitive: Stable pH 5 to pH 7, DT50 8 to 9 days at pH 9, 20 degC
Aqua-Sedimento DT50 (días) 65 A5 Moderado rápido
Fase de agua sola DT50 (días) 17 A5 Lento

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - A5 No Móvil
Koc 10240000
Notas y rango EU dossier Koc range 460000-16300000 mL/g
Freundlich Kf 17500 A4 No Móvil
Kfoc 10240000
1/n 0.93
Notas y rango EU 2017 dossier kfoc range 460000-16300000 mL/g, 1/n range 0.74-1.2, Soils=4
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
decamethrinic acid (Ref: AE F108565) This metabolite may cause environmental pollution, click here for further information Suelo   0.520   Major fraction, Relevant
3-phenoxybenzoic acid Suelo   0.0056   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
3-(4-hydroxyphenoxy)benzoic acid 4'HO3PBA a = Soil; b = Plant; c = Animal b=0.001 -
4-hydroxydeltamethrin - Plant 0.003 -
3-phenoxybenzoic acid
(Ref: )
Nota: Minor fraction, Relevant
- Animal 0.03 -


ECOTOXICOLOGÍA

for deltamethrin

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 1400 A5 Umbral de importancia
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) 87 A5 Rata Alto
Mamíferos - a corto plazo NOEL (mg kg-1) 2.5 A5 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2250 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 5620 ppm A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.00015 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) < 0.000032 A5 Oncorhynchus mykiss Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.00056 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0000041 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.0000017 F3 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.01 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 0.000405 A5 Lemna gibba Alto
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.00047 A5 Navicula pelliculosa Alto
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.0015 A5 Apis meliifera Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.07 A5 Apis meliifera Alto
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) > 0.2 A5 Bombus terrestris Alto
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) > 0.61 A5 Bombus terrestris Alto
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.057 R4 Osmia bicornis Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) 0.556 R4 Megachile rotundata Alto
Modo de exposición Contact
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) 0.0074 R4 Nomia melanderi Alto
Modo de exposición Contact
Lombrices - Agudos 14 día LC50 (mg kg-1) > 645 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos NOEC, reproducción (mg kg-1) 0.165 A5 Eisenia foetida, corr Moderado
Other soil macro-organisms Agudos LC50 (mg kg-1) - - -
Crónicos NOEC (mg kg-1) 16.0 A5 Folsomia candida, 28d corr -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 13.5 g ha-1
A3 Coccinella septempunctata, larvae
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 100 Parasitismo
Dose: 13.5 g ha-1, 7 día
A4 Trichogramma cacoeciae, adult
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.375 kg ha-1
-
Mesocosm study data NOEAEC mg l-1 0.0032 A5 Aquatic community -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for deltamethrin

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 87 A5 Rata Alto
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 0.6 A5 Rat, 6 hr (aerosol, whole body) -
Other Mammal toxicity endpoints Intraperitoneal LD50 = 10.0 mg kg-1 V3 Mouse -
Intravenosa LD50 = 2.53 mg kg-1 V3 Rata -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 Dog, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.025 A5 Dog, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) 0.019 A5 Dog, SF=133 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.0075 A4 Dog, 90 day, SF=100 -
Estudios den la absorción cutánea (%) 2-10 A5 concentration and formulation dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Exposure Routes Public Slight risk of dietary exposure for small children however ARfD would not normally be exceeded
Occupational PPE/PPC recommended
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A0; B0; C0; D0; E3

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

Cuestiones generales de la salud humana IARC Group 3 carcinogen
Endocrine issues - Weak estrogenic activity
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes IMDG Transport Code is usually 3
CLP classification 2013 Health: H301, H331
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T - Toxic: R23/25
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S24, S28, S36/37/39, S38, S45, S60, S61
Clasificación de OSM II - Peligroso mediano
Número de las NU 3349 for active, products usually 1993
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for deltamethrin

Idioma Nombre
Inglés deltamethrin
Francés deltamethrine
Alemán Deltamethrin
Danés deltamethrin
Italiano deltametrina
Español deltametrin
Griego deltamethrin
Esloveno deltametrin
Polaco deltametryna
Sueco deltametrin
Húngaro deltamethrin
Holandés deltamethrin

Última actualización del registro: Wednesday 11 March 2020
Contacto: aeru@herts.ac.uk