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ditianona (Ref: BAS 216F)
** dithianon ** IT 931 ** CME 107 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for dithianon

Descripción: A dicarbonitrile fungicide for control of scab and other foliar diseases excluding powdery mildew

Ejemplos de plagas controladas: Scab (reduction); Downy mildew

Ejemplos de aplicaciones: Apples; Pears; Grapes (table & wine); Blackcurrants

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: circa 1965

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Austria/Spain
Date inclusion expires 31/05/2021
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C14H4N2O2S2
Canonical SMILES C1=CC=C2C(=C1)C(=O)C3=C(C2=O)SC(=C(S3)C#N)C#N
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) PYZSVQVRHDXQSL-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C14H4N2O2S2/c15-5-9-10(6-16)20-14-12(18)8-4-2-1-3-7(8)11(17)13(14)19-9/h1-4H
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Quinone
Minimum active substance purity 930 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Protectant with some curative activity. Multi-site activity.
CAS RN 3347-22-6
CEE número 222-098-6
Número CIPAC 153
EPA américaine chimiques de code 099201
PubChem CID 18771
Masa molecular (g mol-1) 296.32
PIN (Preferred Identification Name) 5,10-dioxo-5,10-dihydronaphtho[2,3-b][1,4]dithiine-2,3-dicarbonitrile
Nombre IUPAC 5,10-dihydro-5,10-dioxonaphtho[2,3-b]-1,4-dithiine-2,3-dicarbonitrile
Nombre CAS 5,10-dihydro-5,10-dioxonaphtho(2,3-b)-1,4-dithiin-2,3-dicarbonitrile
Otra información de estado Marine pollutant; PAN listed Highly Hazardous Chemical
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) M9
Examples of recorded resistance -
Estado físico Dark brown fibrous crystals
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • BASF
  • Celamerck
Example products using this active
  • Dithianon Flowable
  • Dithianon WG
  • Delan 70WG
Estado de UK LERAP None
Formulation and application details Often supplied as a soluble concentrate or wettable granules that are mixed with water and applied as a spray.


DESTINO AMBIENTAL

for dithianon

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.22 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 14700 A5 - Tolueno -
22200 A5 - Acetona -
10600 A5 - Acetato de etilo -
8.77 A5 - Hexano -
Punto de fusión (oC) 215 A5 -
Punto de ebullición (oC) - - -
El punto de degradación (oC) 222 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.58 X 1003 Calculado -
Log P 3.2 A4 - @ pH 2.0 Alto
Masa densidad (g ml-1)/Peso específico 1.58 L3 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 1.0 X 10-07 A3 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 1.347 X 10-07 A4 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.45 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 8.09 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 In CH3CN: 199nm = 35932, 233nm = 20542, 330nm = 5083, 290.5nm = 6535; [pH 1.3: 199nm = 18102, 237nm = 15110, 342nm = 4489, 290.5nm = 5100; [pH 6.9: 199nm = 22380, 250nm = 15110, 350nm = 7204, 290.5nm = 8724 A5 -
Surface tension (mN m-1) 72.7 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 10.5 A5 No persistente
DT50 (laboratorio en 20oC) 10.5 A5 No persistente
DT50 (campo) 35 Y4 Persistente moderado
DT90 (laboratorio en 20oC) 69.2 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 2.6-33.3 days, DT90 range 8.5-135 days
Dissipation rate RL50 on plant matrix Valor 18.3 R4 -
Nota Published literature RL50 range 14.9-21.4 days, fruit from 3 field crops, n=3
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 0.01 A5 Rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 0.6 A5 No persistente
Nota pH sensitive: DT50 10.7 days at pH 5, 9.8 minutes at pH 9 all at 20 degC
Aqua-Sedimento DT50 (días) 0.05 A4 Rápido
Fase de agua sola DT50 (días) 0.05 A4 Rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 86.4 - Móvil un poco
Koc 3627
Notas y rango EU dossier Kd range 9-157 mL/g, Koc range 1167-6004 mL/g, Soils=5
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad Not stable under wet conditions pH > 4

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
2-amino-1,4-naphthoquinone dithianon metabolite D33 Rat (Faeces) - -
phthalic acid
Nota: Not genotoxic
- Soil (Photolysis, Anaerobic); Plant - -
phthadialdehdye - Water (Hydrolysis, Photolysis) - -
1,2-benzenedimethanol - Water (Hydrolysis, Photolysis) - -
- - - - -
- - - - -
(Ref: CL 1017911) - Water (Hydrolysis) - -
(Ref: CL 1025) dithianon metabolite D2 Soil (Anaerobic) - -
(Ref: CL 153880) dithianon metabolite D5 Soil (Anaerobic) 0.046 -
(Ref: CL 231509) - Plant - -
4,9-dioxo-4,9-dihydronaphtho(2,3-b)thiophene-2,3-dicarbonitrile
(Ref: CL 902198)
dithianon metabolite D8 a = Rat (Faeces); b = Soil (Aerobic) b=0.039 -
(Ref: CL 902200) dithianon metabolite D15 Soil (Anaerobic); Plant - -


ECOTOXICOLOGÍA

for dithianon

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 27 A5 Whole fish Bajo potencial
CT50 (días) 1 -
Mamíferos - Agudos oral LD50 (mg kg-1) 300 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) - L2 Rata, 2 año -
(ppm dieta) 20 -
Pájaros/aves - Agudos LD50 (mg kg-1) 309 A5 Colinus virginianus Moderado
Birds - Short term dietary (LC50/LD50) > 1198.5 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.07 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.02 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.26 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.05 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) > 0.5 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) > 0.125 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.09 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.025 A5 Pseudokirchneriella subcapitata Moderado
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 25.4 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 578 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 22.3 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 6000 >, as g product
ha (Delan 70 WG: Conc 700 g/L)
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 960 as g product
ha (Delan 70 WG: Conc 700 g/L)
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 14 kg ha-1, 28 días
-
Mesocosm study data NOEAEC mg l-1 0.004 A5 Fish -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for dithianon

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 300 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 0.31 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.12 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.0135 A5 Dog, SF=100 -
Estudios den la absorción cutánea (%) 0.26-3.1 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational Possible risk to operators identified even with PPE
Minimal risk to other workers with PPE
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; A5 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Toxic
Possible liver and kidney toxicant
May cause nausea, vomiting and diarrhea if ingested
USEPA - possible human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 6.1 or 9
CLP classification 2013 Health: H302
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
T - Toxic: R23
Xn - Harmful: R22, R41, R43
Xi - Irritant: R66
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S13, S36/37/39, S45
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU Variable with product, usually 3077 or 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for dithianon

Idioma Nombre
Inglés dithianon
Francés dithianon
Alemán Dithianon
Danés dithianon
Italiano ditianon
Español ditianona
Griego dithianon
Esloveno ditianon
Polaco ditianon
Sueco ditianon
Húngaro ditianon
Holandés dithianon

Última actualización del registro: Thursday 23 August 2018
Contacto: aeru@herts.ac.uk