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flutianil (Ref: OK-5303)
** flutianil ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Flutianil is a horticultural fungicide awaiting EU approval for use. It has a very low solubility and is volatile. It is persistent in soils. It has a low mammalian toxicity but there are some concerns regarding effects on reproduction and carginogenicity. It exhibits moderate to low toxicity to most aquatic and terrestrial organisms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for flutianil

Descripción: A fungicide with contact action used for a range of horticultural crops

Ejemplos de plagas controladas: Uncinula necator, Golovinomyces spp.

Ejemplos de aplicaciones: Grapevines; Ornamentals

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 2008

CEE Regulación 1107/2009 ( 91/414):
Estado Pending
Dossier rapporteur/co-rapporteur United Kingdom
Date inclusion expires No aplicable
UE Candidatas a sustitución No aplicable
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Isomeric
Fórmula química C19H14F4N2OS2
Canonical SMILES COC1=CC=CC=C1N2CCSC2=C(C#N)SC3=C(C=CC(=C3)C(F)(F)F)F
Isomeric SMILES COC1=CC=CC=C1N\2CCS/C2=C(/C#N)\SC3=C(C=CC(=C3)C(F)(F)F)F
International Chemical Identifier Key (InChIKey) KGXUEPOHGFWQKF-ZCXUNETKSA-N
International Chemical Identifier (InChI) InChI=1S/C19H14F4N2OS2/c1-26-15-5-3-2-4-14(15)25-8-9-27-18(25)17(11-24)28-16-10-12(19(21,22)23)6-7-13(16)20/h2-7,10H,8-9H2,1H3/b18-17-
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Thiazolidine
Minimum active substance purity 985 g/kg
Known relevant impurities EU dossier - none declared
Sustancias de origen -
Modo de acción Contact action - both fungitoxic and fungistatic
CAS RN 958647-10-4
CEE número -
Número CIPAC 835
EPA américaine chimiques de code -
PubChem CID 44151818
Masa molecular (g mol-1) 426.45
PIN (Preferred Identification Name) (2Z)-{[2-fluoro-5-(trifluoromethyl)phenyl]sulfanyl}[3-(2-methoxyphenyl)-1,3-thiazolidin-2-ylidene]acetonitrile
Nombre IUPAC (Z)-(3-(2-methoxyphenyl)-1,3-thiazolidin-2-ylidene)(a,a,a,4-tetrafluoro-m-tolylthio)acetonitrile
Nombre CAS (2Z)-2-((2-fluoro-5-(trifluoromethyl)phenyl)thio)-2-(3-(2-methoxyphenyl)-2-thiazolidinylidene)acetonitrile
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) U13
Examples of recorded resistance -
Estado físico White crystalline powder
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Otsuka Chemical Co
Example products using this active
  • Pinpoint
  • Gatten
  • Flutianil 5% EC
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually supplied as an emulsifiable concentrate.


DESTINO AMBIENTAL

for flutianil

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.1 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 11200 A5 - Tolueno -
169000 A5 - Cloruro de metileno -
66400 A5 - Acetona -
56200 A5 - Metanol -
Punto de fusión (oC) 178 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 242 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.26 X 1003 Calculado -
Log P 3.1 A4 Alto
Masa densidad (g ml-1)/Peso específico - - -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 1.53 X 10-04 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 8.26 X 10-03 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -1.36 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 Neutral: 282nm=17500, 244.5nm=16900; [Acidic: 283nm=17100, 245nm=16300; [Basic: 282nm=17600, 245nm=16700 A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 286 A5 Persistente
DT50 (laboratorio en 20oC) 297.3 A5 Persistente
DT50 (campo) 14.4 A5 No persistente
DT90 (laboratorio en 20oC) 1162 A5 -
DT90 (campo) 48.0 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 262.6-338.4 days, DT90 range 1031-1256 days, Field studies DT50 range 1.2-159 days, DT90 range 4.1-529 days
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 1.1 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable at all environmentally relevant pHs
Aqua-Sedimento DT50 (días) 607 A5 Estable
Fase de agua sola DT50 (días) 1.0 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 794 A5 No Móvil
Kfoc 35492
1/n 0.99
Notas y rango EU dossier Kf range 533-1093 mL/g, Kfoc range 20631-79448 mL/g, 1/n range 0.96-1.10, soils=5
pH senbsibilidad None

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
(Z)-2-(2-fluoro-5-(trifluoromethyl)phenylsulfinyl)-2-(3,2-methoxyphenyl)thiazolidin-2-ylidene)acetonitrile (Ref: OC 53276) Suelo   0.086   Minor fraction, Relevant
(Z)-2-(2-fluoro-5-(trifluoromethyl)phenylsulfinyl)-2-(3,2-methoxyphenyl) 1-oxo-thiazolidin-2-ylidene)acetonitrile (Ref: OC 56574) This metabolite may cause environmental pollution, click here for further information Suelo   0.189   Major fraction, Relevant
(Z)-2-(2-fluoro-5-(trifluoromethyl)phenylthio)-2-(4-hydroxy-3-(2-methoxyphenyl)thiazolin-2-ylidene)acetonitrile (Ref: OC 53279) Suelo   0.003   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
(Z)-2-(2-fluoro-5-(methyl)phenylthio)-2-(3-(2-methoxyphenyl) 2-thiazolidinylidene] acetonitrile OC 53982 Rat - -
(2-cysteinyl-3-hydroxy-5-trifluoromethyl) S-acetylthiophenol -1,1 dioxide - Rat - -
2-fluoro-3-cysteinyl-4-hydroxy-5-trifluoromethyl benzene sulponic acid - Rat - -
2-S-acetylthiophenol -1,1 dioxo-4-trifluoromethyl-6-hydroxy phenylthio(methyl-2-(1,4 piperazine-3,6-dione) - Rat - -
methyl 2-fluoro-3-cysteinylmethyl benzene sulphonic acid - Rat - -
2-cysteinylglutamyl-3-fluoro-4-sulphonic acid-6-trifluoromethyl phenyl acetate - Rat - -
92-S(N-acetyl)cysteinyl-5-trifluoromethyl) S-acetylthiophenol -1,1 dioxide - Rat - -
2-acetamido-3-(-2-hydroxy-3-(methylsulfinyl)-5-)trifluoromethyl)phenylthio)propanoic acid - Rat - -
(Z)-2-(2-fluoro-5-(trifluoromethyl)phenylsulfonyl)-2-(3,2-methoxyphenyl)thiazolidin-2-ylidene)acetonitrile OC 53277 Plant - -
(Z)-2-(2-fluoro-5-(trifluoromethyl)phenylthio)-2-(3,2-hydroxyphenyl)thiazolidin-2-ylidene)acetonitrile OC 42121 Plant - -
2-fluoro-5-(trifluoromethyl)benzenesulfonic acid OC 56635 Plant; Soil; Water; Rat - -
1,2-bis(2-fluoro-5-(trifluoromethyl)phenyl)disulfane OC 56634 Plant - -
2-methoxybenzenamine OC 56631 Plant; Rat - -
(Z)-2-(2-fluoro-5-(methyl)phenylsulfinyl)-2-(3-(2-methoxyphenyl) thiazolidin-2-ylidene] acetonitrile OC 53429 Rat - -


ECOTOXICOLOGÍA

for flutianil

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 339 A5 Umbral de importancia
CT50 (días) 1.97 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2250 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 5620 mg kg diet-1 A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) > 0.90 A5 Oncorhynchus Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.000781 A5 Pimephales promelas Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 1.0 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.007 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 396 A5 Chironomus riparius Bajo
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.085 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) > 100 A5 Bajo
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) > 200 A5 Bajo
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 6.25 A5 Eisenia foetida corr Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 31.7 48hr LR50
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 583.74 7-día LR50
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.75 mg kg-1, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for flutianil

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.17 A5 Rat, 4 hr (nose only, aerosol) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.82 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 1.0 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.05 A5 Rat, SF=2000 -
Estudios den la absorción cutánea (%) 75 A3 Default -
Directivo 76/464 Sustancias Peligrosas - - -
Exposure Routes Public Low risk
Occupational PPE/PPC advised to minimise exposure
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A3; B0; C0; D0; E3

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Possible liver & kidney toxicant
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
CLP classification 2013 Environment: H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Reproduction risk category 3: R63
Xn - Harmful: R22, R41, R43
Xi - Irritant: R38
N - Dangerous to the environment: R50/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S26, S36/37, S39, S60, S61
Clasificación de OSM NL - No inscripto en la lista
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for flutianil

Idioma Nombre
Inglés flutianil
Francés -
Alemán -
Danés -
Italiano -
Español -
Griego -
Esloveno -
Polaco -
Sueco -
Húngaro -
Holandés -

Última actualización del registro: Thursday 31 May 2018
Contacto: aeru@herts.ac.uk