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etoprofos; etoprop
** ethoprophos ** ethoprop ** phosethoprop ** mocap ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for ethoprophos

Descripción: A broad-spectrum nematicide and insecticide used pre-planting to control nematodes and soil dwelling insects

Ejemplos de plagas controladas: Free-form nematodes; Millipedes; Centipedes; Weevils; Wireworms; Cutworms; Noctuids larvae; Symphylids; Caterpillars; White grubs

Ejemplos de aplicaciones: Ornamentals; Fruit including bananas, pineapples; Tobacco; Potatoes; Vegetables; Sugarcane

Eficacia y actividad: Research and testing has shown ethoprophos to offer effective control for soil nematodes and insects when used according to label guidelines.

Availability status: Current

Introduction & key dates: 1966, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Italy/Ireland
Date inclusion expires 31/07/2019
UE Candidatas a sustitución Yes - low ADI / ARfD / AOEL
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C8H19O2PS2
Canonical SMILES CCCSP(=O)(OCC)SCCC
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) VJYFKVYYMZPMAB-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C8H19O2PS2/c1-4-7-12-11(9,10-6-3)13-8-5-2/h4-8H2,1-3H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Nematicide
Grupo químico Organophosphate
Minimum active substance purity 940 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact action. Acetylcholinesterase (AChE) inhibitor.
CAS RN 13194-48-4
CEE número 236-152-1
Número CIPAC 218
EPA américaine chimiques de code 041101
PubChem CID 3289
Masa molecular (g mol-1) 242.3
PIN (Preferred Identification Name) O-ethyl S,S-dipropyl phosphorodithioate
Nombre IUPAC O-ethyl S,S-dipropyl phosphorodithioate
Nombre CAS O-ethyl S,S-dipropyl phosphorodithioate
Otra información de estado Marine Pollutant
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 1B
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance None recorded
Estado físico Clear to pale yellow liquid
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bayer CropScience
  • Mobil Chemicals
  • Rhone-Poulenc
Example products using this active
  • Mocap 10G
  • Mocap 15G
  • Sanimul
  • Prophos
Estado de UK LERAP None
Formulation and application details Often supplied as granules that are applied directly to the soil or incorporated. It is also available as an emulsifiable concentrate.


DESTINO AMBIENTAL

for ethoprophos

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 1300 A5 Alto
Solubilidad - en solventes organicos en 20oC (mg l-1) 500000 A5 - Acetona -
500000 A5 - Metanol -
500000 A5 - Acetato de etilo -
500000 A5 - Tolueno -
Punto de fusión (oC) 70 A5 -
Punto de ebullición (oC) 244.3 A5 -
El punto de degradación (oC) 244.3 A5 -
Punto de inflamación (oC) 141 A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 9.77 X 1002 Calculado -
Log P 2.99 A5 Moderado
Masa densidad (g ml-1)/Peso específico 1.09 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 78.0 A5 Altamente volátil
Constante de Henry a 25oC (Pa m3 mol-1) 1.35 X 10-02 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 2.22 Calculado Estado de transición
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 6.50 X 10-02 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 Neutral soln: 231.0nm=725
Acid soln: 269.0nm=1724
Basic soln: 268.0nm=3815
A5 -
Surface tension (mN m-1) 45.1 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 13.6 A5 No persistente
DT50 (laboratorio en 20oC) 13.6 A5 No persistente
DT50 (campo) 1.3 A5 No persistente
DT90 (laboratorio en 20oC) 63.0 A5 -
DT90 (campo) 15.1 A5 -
Endpoint de modelado DT50 13.6 A5 normalised geometric mean -
Nota EU 2017 dossier Lab studies DT50 range 4.8-21.1 days, DT90 range 26.2-89.9 days, Soils = 5; Field study DT50 range 0.61-2.1 days, DT90 range 9.3-20.8 days, Soils =2
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor Estable A5 -
Nota Estable
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable pH 5 to pH 7, DT50 83 days at pH 9, 25 degC
Aqua-Sedimento DT50 (días) 83 A5 Moderado rápido
Fase de agua sola DT50 (días) 20 A5 Lento

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - DW3 Móvil
Koc 70.0
Notas y rango -
Freundlich Kf 2.0 A5 Móvil moderado
Kfoc 111
1/n 0.894
Notas y rango EU dossier kf range 0.56-5.60, Kfoc range 38-186 mL/g,1/n range 0.82-0.96, Soils=11
pH senbsibilidad No

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
ethyl phosphate - Plant; Animal - -
O-ethyl-S-propyl-phosphorothioate
Nota: Rat LD50 246 mg kg-1 bw
EPPA Plant; Animal - -
O-ethyl-S-methyl-S-propyl-phosphorothioate
Nota: Rat LD50 41.0 mg kg-1 bw
SME Plant - -
O-ethyl-O-methyl-S-propyl-phosphorothioate
Nota: Rat LD50 19.2 mg kg-1 bw
OME Plant - -
O-ethyl-S-propylphosphorothioic acid AE 0592496 Soil (Aerobic, Anaerobic) - -
N-propyl mercaptan - Rat - -


ECOTOXICOLOGÍA

for ethoprophos

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 225 Q2 Estimado Umbral de importancia
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) 40 A4 Rata Alto
Mamíferos - a corto plazo NOEL (mg kg-1) 0.1 A5 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 6.04 A5 Colinus virginianus Alto
Birds - Short term dietary (LC50/LD50) 6.51 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.32 A5 Lepomis macrochirus Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.064 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.2 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) - - -
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.015 F3 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 28.3 K3 Unknown species Bajo
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 3.2 Q2 Unknown species Bajo
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 5.56 A5 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) - - -
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 39.6 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 8.3 A5 Eisenia foetida, 56 días Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 7 kg ha-1
A5 Poecilus cupreus, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 10 kg ha-1
A5 Aleochara bilineata, adult
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 33.3 mg kg-1 soil, 44 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for ethoprophos

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 40 A4 Rata Alto
Mammals - Dermal LD50 (mg kg-1 body weight) 7.9 A5 Rabbit -
Mammals - Inhalation LC50 (mg l-1) 0.123 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.0004 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.01 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.001 A5 Dog, SF=100 -
Estudios den la absorción cutánea (%) 10 A5 -
Directivo 76/464 Sustancias Peligrosas List I; List II - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational Exposure possible but acceptable under label recommendations for use concerning personal protection clothing and equipment
Dermal exposure likely to be low
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana Very toxic by inhalation and dermal absorption
USEPA - probable human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H301, H310, H317, H330
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T+ - Very toxic: R26/27
T - Toxic: R25
Xn - Harmful: R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S27/28, S36/37/39, S45, S60, S61
Clasificación de OSM Ia - Peligroso extremo
US EPA Classification (formulation) II - Warning - Moderately toxic
Número de las NU 3018
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group II (medium danger)


TRADUCCIONES

for ethoprophos

Idioma Nombre
Inglés ethoprophos
Francés ethoprophos
Alemán Ethoprophos
Danés ethoprophos
Italiano etoprofos
Español etoprofos; etoprop
Griego ethoprophos
Esloveno etoprofos
Polaco etoprofos
Sueco -
Húngaro -
Holandés ethoprofos

Última actualización del registro: Thursday 23 August 2018
Contacto: aeru@herts.ac.uk