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fenitrotion (Ref: OMS 43)
** fenitrothion ** MEP ** OMS 223 ** ENT 25715 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Fenitrothion is an insecticide that is no longer approved for use in the EU. It has a low aqueous solubility, is highly soluble in many organic solvents and is volatile. Fenitrothion has a low potential for leaching to groundwater and is not expected to be persistent in soil or water systems. It is moderately toxic to mammals, considered to be an endocrine disrupter and a cholinesterase inhibitor. It is highly toxic to birds, aquatic invertebrates and honeybees, and moderately toxic to fish, algae and earthworms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for fenitrothion

Descripción: An insecticide used to control chewing, sucking and boring pests on a range of cr

Ejemplos de plagas controladas: Leafminers, Locusts, Stem borers, Wheat bugs, Flour beetles, Grain beetles, Grain weevils

Ejemplos de aplicaciones: Cereals; Cotton; Rice; Top fruit; Vegetables; Forestry; Ornamentals

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1960, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur UK
Date inclusion expires Expired
UE Candidatas a sustitución -
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C9H12NO5PS
Canonical SMILES CC1=C(C=CC(=C1)OP(=S)(OC)OC)[N+](=O)[O-]
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) ZNOLGFHPUIJIMJ-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C9H12NO5PS/c1-7-6-8(4-5-9(7)10(11)12)15-16(17,13-2)14-3/h4-6H,1-3H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Organophosphate
Minimum active substance purity 930 g/kg
Known relevant impurities EU dossier - S-methyl fenitrothion <5g/Kg
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action. Cholinesterase inhibitor.
CAS RN 122-14-5
CEE número 204-524-2
Número CIPAC 35
EPA américaine chimiques de code 105901
PubChem CID 31200
Masa molecular (g mol-1) 277.23
PIN (Preferred Identification Name) O,O-dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate
Nombre IUPAC O,O-dimethyl O-4-nitro-m-tolyl phosphorothioate
Nombre CAS O,O-dimethyl O-(3-methyl-4-nitrophenyl) phosphorothioate
Otra información de estado Chemical subject to PIC regulations
Relevant Environmental Water Quality Standards UK Statutory standard for the protection of aquatic life in inland waters, coastal and territorial waters: 0.01 ug/L as annual average
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 1B
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Many recorded cases
mosquitoes
Adoxophyes orana
Boophilus microplus
Lucilia cuprina
Myzus persicae
Spodoptera littoralis
Estado físico Yellow brown liquid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • FCC
  • Agropharm
  • King Tech Corp
  • Bayer
  • Sumitomo
  • Denka
Example products using this active
  • IPM 400
  • Fenitrocap IPM400
  • Fenifos
  • Nition
  • Accothion
  • Novathion
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Supplied in a variety of formulations including emulsifiable concentrates, wettable powders, granules and dusts as well as ULV .


DESTINO AMBIENTAL

for fenitrothion

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 19 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 25000 A5 - n-Hexano -
500000 A5 - Metanol -
500000 A5 - Acetona -
500000 A5 - Acetato de etilo -
Punto de fusión (oC) 1 A3 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 210 A5 -
Punto de inflamación (oC) 157 L3 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.09 X 1003 Calculado -
Log P 3.32 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.33 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 0.676 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 9.86 X 10-03 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.48 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.25 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 290nm = 4210; [Acidic solution: 290nm = 4390; [Basic solution: 290nm = 2370 A5 -
Surface tension (mN m-1) 68.5 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 2.7 A5 No persistente
DT50 (laboratorio en 20oC) 2.7 A5 No persistente
DT50 (campo) - - -
DT90 (laboratorio en 20oC) 4.48 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 0.04-1.98 days, DT90 range 2.16-6.58 days
Dissipation rate RL50 on plant matrix Valor 8.0 R4 -
Nota Published literature RL50 range 0.5-4.2 days, 7 field & undercover grown crops, various matrices, n=8
Dissipation rate RL50 on and in plant matrix Valor 5.3 R4 -
Nota Published literature RL50 range 1.5-10.6 days, 15 field & undercover grown crops, various matrices, n=23; lettuce in cold storage RL50=27 days.
Acuoso fotólisis DT50 (días) en pH 7 Valor 3.5 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 183 A5 Persistente
Nota Slightly sensitive to pH: DT50 195 days at pH5, 100 days at pH 9
Aqua-Sedimento DT50 (días) 1.57 A5 Rápido
Fase de agua sola DT50 (días) 1.1 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - DW2 Móvil un poco
Koc 2000
Notas y rango -
Freundlich Kf 180 A5 Móvil un poco
Kfoc 791
1/n 0.982
Notas y rango EU dossier Kf range 4.9-830 mL/g, Kfoc range 252-1966 mL/g, 1/n range 0.86-1.10, Soils=5
pH senbsibilidad Some indication that adsorption may increase with decreasing pH

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-methyl-4-nitrophenol This metabolite may cause environmental pollution, click here for further information Suelo   0.445   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
desmethylfenitrothion - Water - -
aminofenitrothion - Soil (Aerobic) - -
fenitrooxon - Soil (Aerobic); Water - -
formylaminofenitrothion - Soil (Aerobic) - -
desmethylfenitrooxon - Soil (Aerobic) - -
acetylaminofenitrothion - Water - -
o-methyl o-hydrogen o-(3-methyl-4-nitrophenyl)phosphate DM-SMO Water (Photolysis) - -
o-methyl s-methyl o-(3-methyl-4-nitrophenyl)phosphorothioate SCH3-SMT Water (Photolysis) - -
o,o-dimethyl o-(3-methyl-4-nitrophenyl)phosphorothioate SMO Water (Photolysis) - -
carboxyfenitrothion - Water (Photolysis) - -
O,O-dimethyl O-(3-carboxy-4-nitrophenyl)phosphate COOH-SMO Water (Photolysis) - -
3-methyl-4-nitroanisole - Soil (Aerobic) - -


ECOTOXICOLOGÍA

for fenitrothion

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 29 A5 (Other literature values Log BCF ranger 0.8-2.9 (R3)) Bajo potencial
CT50 (días) 0.19 -
Mamíferos - Agudos oral LD50 (mg kg-1) 330 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) - L2 Rata, 2 año -
(ppm dieta) > 10 -
Pájaros/aves - Agudos LD50 (mg kg-1) 2.3 A5 Phasianidae Alto
Birds - Short term dietary (LC50/LD50) 23 mg kg-1 bw/día A4 Unknown species -
Pez - agudo 96 hora LC50 (mg l-1) 1.3 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.088 A3 Oncorhynchus mykiss, 96 día Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.0086 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.000087 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.0017 A5 Chironomus riparius Alto
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 1.3 A5 Raphidocelis subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.1 Q1 Unknown species Moderado
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.16 A5 Apis mellifera Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.20 A5 Apis mellifera Alto
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.756 R3 Bombus terricola 48 hr Alto
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) 0.1 R4 Andrena erythronii Alto
Modo de exposición Contact
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) 0.039 R4 Megachile rotundata Alto
Modo de exposición Contact
Lombrices - Agudos 14 día LC50 (mg kg-1) 231 A5 Eisenia foetida Moderado
Lombrices - Crónicos NOEC, reproducción (mg kg-1) 25 A5 Eisenia foetida Moderado
Other soil macro-organisms Agudos LC50 (mg kg-1) - - -
Crónicos NOEC (mg kg-1) - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 10.8 Mortalidad
Dose: 2 x 750 g ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 5.6 Mortalidad
Dose: 2 x 750 g ha-1
A5 Typhlodromus pyri, protonymph
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 10 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 0.017 A5 Aquatic invertebrates -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for fenitrothion

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 330 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) 890 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 2.2 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.005 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.013 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) Ningunos asignaron A5 -
Estudios den la absorción cutánea (%) 3.9-20.9 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas List I; List II - -
Exposure Routes Public -
Occupational Possible risk when applied inside glasshouses
Re-entry after application should be avoided
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A3; B3; C3; D0; E3

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Risk of serious eye damage
Bioaccumulates
Endocrine issues - Competitive binding to androgen receptor, inhibition of estrogens action
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Potentially explosive under certain conditions
Prevent generation of mists
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H302
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S60, S61
Clasificación de OSM II - Peligroso mediano
Número de las NU Usually 3018
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for fenitrothion

Idioma Nombre
Inglés fenitrothion
Francés fenitrothion
Alemán Fenitrothion
Danés fenitrothion
Italiano fenitrotion
Español fenitrotion
Griego fenitrothion
Esloveno fenitrotion
Polaco fenitrotion
Sueco fenitrotion
Húngaro fenitrothion
Holandés fenitrothion

Última actualización del registro: Tuesday 25 June 2019
Contacto: aeru@herts.ac.uk