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fluazinam (Ref: IKF 1216)
** fluazinam ** B 1216 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for fluazinam

Descripción: A protective broad spectrum fungicide used to control various soil-borne fungal pathogens on a range of crops. It also has some acaricidal activity.

Ejemplos de plagas controladas: Sclerotinia blight, Late blight, White mould, Clubroot, Downy mildew, Scab, Alternaria blotch, Mites

Ejemplos de aplicaciones: Peanuts; Potatoes; Grape vines; Fruit including citrus and apples; Crucifers

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1990, first marketed

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Austria/Denmark
Date inclusion expires 28/02/2020
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C13H4Cl2F6N4O4
Canonical SMILES C1=C(C=NC(=C1Cl)NC2=C(C=C(C(=C2[N+](=O)[O-])Cl)C(F)(F)F)[N+](=O)[O-])C(F)(F)F
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) UZCGKGPEKUCDTF-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C13H4Cl2F6N4O4/c14-6-1-4(12(16,17)18)3-22-11(6)23-9-7(24(26)27)2-5(13(19,20)21)8(15)10(9)25(28)29/h1-3H,(H,22,23)
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Fluazinam - Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide, Acaricide
Grupo químico Phenylpyridinamine
Minimum active substance purity 960 g/kg
Known relevant impurities -
Sustancias de origen Sintéticas
Modo de acción Protective action with some residual effects. Uncoupler of oxidative phosphorylation
CAS RN 79622-59-6
CEE número -
Número CIPAC 521
EPA américaine chimiques de code 129098
PubChem CID 91731
Masa molecular (g mol-1) 465.14
PIN (Preferred Identification Name) 3-chloro-N-[3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl]-5-(trifluoromethyl)pyridin-2-amine
Nombre IUPAC 3-chloro-N-(3-chloro-5-trifluoromethyl-2-pyridyl)-α,α,α-trifluoro-2,6-dinitro-p-toluidine
Nombre CAS 3-chloro-N-(3-chloro-2,6-dinitro-4-(trifluoromethyl)phenyl)-5-(trifluoromethyl)-2-pyridinamine
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 29
Examples of recorded resistance -
Estado físico Pale yellow crystals
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgriGuard
  • Headland
  • Landgold
  • Makhteshim-Agan
  • Syngenta
Example products using this active
  • Shirlan
  • Tizca
  • Volley
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as a soluble concentrate which is mixed with water and applied as a spray.


DESTINO AMBIENTAL

for fluazinam

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.135 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 8000 A5 - n-Hexano -
192000 A5 - Metanol -
451000 A5 - Tolueno -
853000 A5 - Acetona -
Punto de fusión (oC) 117 A5 -
Punto de ebullición (oC) - - -
El punto de degradación (oC) - - -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.07 X 1004 Calculado -
Log P 4.03 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.81 A5 -
Disociación constante (pKa) at 25oC 7.34 A5 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 7.5 A5 Volátil moderado
Constante de Henry a 25oC (Pa m3 mol-1) 25.9 A5 Volátil moderado
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 1.32 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 3.15 X 10-02 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) 66.3 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 11 B5 No persistente
DT50 (laboratorio en 20oC) 72.5 A5 Persistente moderado
DT50 (campo) 16.4 A5 No persistente
DT90 (laboratorio en 20oC) 441 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 17-263 days, DT90 range 210-873 days, field studies DT50 range 67-254 days; Other studies: DT50 (1) Lab range 37-224 days, field range 6-15 days (B5), (2) 29 days (DW4)
Dissipation rate RL50 on plant matrix Valor 4.3 R3 -
Nota Grape berries, n=1
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 2.5 A5 Moderado rápido
Nota Degradation in daylight, stable in the dark
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 3.6 A5 No persistente
Nota pH sensitive: stable at pH 4, DT50 3.7 days at pH 9
Aqua-Sedimento DT50 (días) 3.1 A5 Rápido
Fase de agua sola DT50 (días) 2.7 A4 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 220 A5 No Móvil
Koc 16430
Notas y rango EU dossier Kd range 126-264 mL/g, Koc range 10245-26250 mL/g, Soils=4
Freundlich Kf 26.6 A5 Móvil un poco
Kfoc 1958
1/n 0.65
Notas y rango EU dossier Kf range 11.12-43.48 mL/g, Kfoc range 1705-2316 mL/g, 1/n range 0.6204-0.6813, Soils=4
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
5-((3-chloro-5-(trifluoromethyl)-2-pyridyl)amino)-alpha,alpha,alpha-trifluoro-4,6-dinitro-o-cresol This metabolite may cause environmental pollution, click here for further information Suelo   0.139   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
3-chloro-N1-[3-chloro-5-(trifluoromethyl)-2-pyridinyl]-6-nitro-4-(trifluoromethyl)-1,2-benzenediamine MAPA Animal; Water/sediment - -
5-chloro-6-[3-chloro-2, 6-dinitro-4-trifluoromethylanilino) nicotinic acid CAPA Water 0.940 -
6-(4-carboxy-3-chloro-2,6-dinitroanilino)-5-chloronicotinic acid DCPA Water - -
- G-504 Water - -
3-chloro-2-(2,6-diamino-3-chloro-alpha,alpha,alpha-trifluoro-p-toluidino)-5-(trifluoromethyl) pyridine DAPA Rat (Urinary, Faeces, Bile); Animal; Plant; Soil; Water/sediment - -
4-chloro-N2-[3-chloro-5-(trifluoromethyl)-2-pyridyl]-3-nitro- 5-(trifluoromethyl)-1,2-benzenediamine AMPA Rat (Urinary, Faeces, Bile); Animal; Plant; Soil; Water/sediment - -
- AMPA mercapturate Rat (Urinary, Faeces, Bile) - -
- DAPA glucuronide Rat (Urinary, Faeces, Bile) - -
- DAPA cysteine conjugate Rat (Urinary, Faeces, Bile) - -
2-chloro-6-[(3-chloro-5-(trifluoromethyl)-2-pyridyl)-alpha,alpha,alpha-trifluoro-5-nitro-m-cresol
(Ref: SDS-67200/SDS-67230)
- Water/sediment; Water (Anaerobic) - -


ECOTOXICOLOGÍA

for fluazinam

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 1025 A5 Umbral de importancia
CT50 (días) 5.5 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 4100 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) > 3.48 A4 Perro Alto
(ppm dieta) > 1.0 -
Pájaros/aves - Agudos LD50 (mg kg-1) 1782 A5 Colinus virginianus Moderado
Birds - Short term dietary (LC50/LD50) > 1230 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.055 A5 Lepomis macrochirus Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.012 Q2 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.22 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0125 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.00625 A5 Chironomus riparius, emergence Alto
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 53.6 P4 Lemna gibba Bajo
Non-target plants > 1500 A5 Cucumber
Vegetative vigour, ER50
as g/ha
-
> 1500 A5 Cucumber
Seedling emergence, ER50
as g/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.16 A5 Pseudokirchneriella subcapitata, 96 hora Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.048 Q2 Unknown species Moderado
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 200 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) < 0.48 A5 Eisenia andrei Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad 1.57 A5 Folsomia candida, 28 día NOEC mg kg-1 -
Otro arthropoda (1) LR50 g ha-1 200 Mortalidad
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 2.27 mg kg-1, 28 días
-
Mesocosm study data NOEAEC mg l-1 0.01 A5 Zooplankton -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for fluazinam

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 4100 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 0.463 A5 Rat, 4 hr -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 Mouse, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.07 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.004 A5 Dog, SF=100 -
Estudios den la absorción cutánea (%) 1.5-7.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public Acceptable for proposed uses
Occupational Acceptable risk for operators for proposed uses with PPE/PPC
Acceptable risk for other farm workers for proposed uses
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Potential liver toxicant
May cause allergic contact dermatitis and occupational asthma
USEPA - some evidence to suggest possible human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive
IMDG Transport Code is usually 9
CLP classification 2013 Health: H317, H318, H332, H361d
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Reproduction risk category 3: R63
T - Toxic: R23
Xn - Harmful: R41, R43
N - Dangerous for the environment: R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU Usually 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for fluazinam

Idioma Nombre
Inglés fluazinam
Francés fluazinam
Alemán Fluazinam
Danés fluazinam
Italiano fluazinam
Español fluazinam
Griego -
Esloveno fluazinam
Polaco fluazynam
Sueco fluazinam
Húngaro fluazinam
Holandés -

Última actualización del registro: Wednesday 03 April 2019
Contacto: aeru@herts.ac.uk