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fluopicolida (Ref: AE C638206)
** fluopicolide ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for fluopicolide

Descripción: A fungicide used for the control of a range of Oomycete diseases including downy mildew and blight

Ejemplos de plagas controladas: Various Oomycete diseases including downy mildews (Plasmopara, Pseudoperonospara, Peronospora, Bremia), late blight (Phytophthora), and some Pythium species.

Ejemplos de aplicaciones: Grapes; Hops; Potatoes; Various vegetables including onions, roots and tubers

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 2006

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK/Spain
Date inclusion expires 31/05/2023
UE Candidatas a sustitución Yes - two 'Persistent-Bioaccumulative-Toxic' criteria
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C14H8Cl3F3N2O
Canonical SMILES C1=CC(=C(C(=C1)Cl)C(=O)NCC2=C(C=C(C=N2)C(F)(F)F)Cl)Cl
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) GBOYJIHYACSLGN-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C14H8Cl3F3N2O/c15-8-2-1-3-9(16)12(8)13(23)22-6-11-10(17)4-7(5-21-11)14(18,19)20/h1-5H,6H2,(H,22,23)/f/h22H
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Benzamide
Minimum active substance purity 970 g/kg
Known relevant impurities EU dossier - toluene max 0.3%
Sustancias de origen Sintéticas
Modo de acción Protectant, novel mode of action as fluopicolide delocalises spectrin-like proteins
CAS RN 239110-15-7
CEE número -
Número CIPAC 787
EPA américaine chimiques de code 027412
PubChem CID 11159021
Masa molecular (g mol-1) 383.58
PIN (Preferred Identification Name) -
Nombre IUPAC 2,6-dichloro-N-[3-chloro-5-(trifluoromethyl)-2-pyridylmethyl]benzamide
Nombre CAS 2,6-dichloro-N-((3-chloro-5-(trifluoromethyl)-2-pyridinyl)methyl)benzamide
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 43
Examples of recorded resistance -
Estado físico Beige coloured solid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bayer CropScience
Example products using this active
  • Infinito
Estado de UK LERAP None
Formulation and application details Available as dispersible granules that are mixed with water and used as a spray.


DESTINO AMBIENTAL

for fluopicolide

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 2.8 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 200 A5 - n-Hexano -
19200 A5 - Etanol -
20500 A5 - Tolueno -
74700 A5 - Acetona -
Punto de fusión (oC) 150 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 320 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 7.94 X 1002 Calculado -
Log P 2.9 A5 Moderado
Masa densidad (g ml-1)/Peso específico 1.65 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 3.03 X 10-04 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 4.15 X 10-05 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 3.63 Calculado Alta posibilidad de la lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 8.10 X 10-01 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution 203nm = 44519, 271nm = 3601 A5 -
Surface tension (mN m-1) 71.3 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 271 A5 Persistente
DT50 (laboratorio en 20oC) 271 A5 Persistente
DT50 (campo) 138.8 A5 Persistente
DT90 (laboratorio en 20oC) 900 A5 -
DT90 (campo) 720 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier Lab studies DT50 range 194-333 days, DT90 range 644-2216 days; Field studies DT50 range 50-172 days, DT90 range 863-1184 days
Dissipation rate RL50 on plant matrix Valor 4.3 R3 -
Nota Cabbage leaves, n=1
Dissipation rate RL50 on and in plant matrix Valor 7.4 R4 -
Nota Published literature RL50 range 3.6-11.3 days, 2 field crops, various matrices, n=2
Acuoso fotólisis DT50 (días) en pH 7 Valor 64 A4 Estable
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Not pH sensitive
Aqua-Sedimento DT50 (días) 1117 A5 Estable
Fase de agua sola DT50 (días) 91.4 A5 Estable

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 4.20 A5 Móvil moderado
Kfoc 321.1
1/n 0.90
Notas y rango EU dossier Kf range 1.42-9.27, Kfoc range 172-580 mL/g, 1/n range 0.86-0.93, Soils=8
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
4-N-[3-chloro-5-trifluoromethyl-pyridin-2-yl-(hydroxyl)methyl]-2,6-dichlorobenzamide (Ref: AE-0608000) This metabolite may cause environmental pollution, click here for further information Suelo   0.106   Major fraction, Relevant
2,6-dichlorobenzamide (Ref: AE C653711) This metabolite may cause environmental pollution, click here for further information Suelo   0.250   Major fraction, Relevant
3-chloro-5-trifluoromethyl-pyridine-2-carboxylic acid (Ref: AE-C657188) Suelo   0.073   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
2,6-dichloro-N-[(3-chloro-5-trifluoromethylpyridin-2-yl)methyl]-4-hydroxy benzamide
(Ref: AE 0712556)
- Animal - -
3-methylsulfinyl-5-trifluoro-methylpyridine-2-carboxylic acid
(Ref: AE 1344122)
- Plant; Soil; Groundwater - -
3-sulfo-5-trifluoromethylpyridine-2-carboxylic acid
(Ref: AE 1344123)
- Groundwater; Soil - -
3-mesyl-5-(trifluoromethyl)pyridin-2-ol
(Ref: AE 1388273)
- Soil; Groundwater - -
3,5-dichloro-4-[3-chloro-5-trifluoromethylpyridine-2-yl-methyl) carbamoyl] benzenesulfonic acid
(Ref: AE 1413903)
- Soil; Groundwater - -
3-chloro-2-hydroxy-5-trifluoromethylpyridine
(Ref: AE B102859)
- Plant - -
2,6-dichloro-N-((3-chloro-5-trifluoromethylpyridine-2-yl)methyl)-3-hydroxybenzamide
(Ref: AE C643890)
- Plant; Animal - -
3-chloro-5-trifluoromethylpyridine-2-carboxamide
(Ref: AE C653598)
- Plant; Groundwater - -
2,6-dichloro-3-hydroxybenzamide
(Ref: AE C657378)
- Plant; Rat - -


ECOTOXICOLOGÍA

for fluopicolide

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 121 A5 Umbral de importancia
CT50 (días) 0.51 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) 10 A3 Conejo Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2250 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 1744 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.36 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.155 A4 Pimephales promelas, 35 día Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 1.8 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.37 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 49.0 A5 Chironomus riparius Bajo
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 3.2 A5 Lemna gibba Moderado
Non-target plants > 3000 A5 Lettuce, Cucumber
Seedling emergence, ER50
as g/ha
-
> 3000 A5 OSR
Vegetative vigour, ER50
as G/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.029 A5 Navicula pelliculosa, Biomass Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 241 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad 31.25 A5 Folsomia candida, 28 día NOEC -
Otro arthropoda (1) LR50 g ha-1 8230 48 hora
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 7130 7 día
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 1.84 mg kg-1 soil, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for fluopicolide

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.16 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.08 A3 proposed, Mouse, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.18 A3 proposed Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.05 A3 proposed Rat, 90 day, SF=100 -
Estudios den la absorción cutánea (%) 0.24-2.75 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks for bystanders identified
Occupational Potential risk to operators if PPE/PPC not utilised
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; Calc MAC=0.24 μg l-1; A5 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Possible liver, kidney and spleen toxicant

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not flammable, explosive or oxidising
CLP classification 2013 Environment: H400
CEE clasificación de riesgos Click here to view information omn the EU risk phrases N - Dangerous for the environment: R50, 53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S35, S57
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU Usually 3077
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for fluopicolide

Idioma Nombre
Inglés fluopicolide
Francés fluopicolide
Alemán Fluopicolid
Danés fluopicolid
Italiano fluopicolide
Español fluopicolida
Griego -
Esloveno flupokolid
Polaco fluopikolid
Sueco fluopikolid
Húngaro -
Holandés fluopicolide

Última actualización del registro: Thursday 13 September 2018
Contacto: aeru@herts.ac.uk