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hexitiazox (Ref: NA 73)
** hexythiazox ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for hexythiazox

Descripción: An acaricide used for the control of eggs and larvae of many mites on a wide variety of food crops

Ejemplos de plagas controladas: Tetranychid mites

Ejemplos de aplicaciones: Fruit including apples, pears, stone fruit, citrus, grapes; Nuts; Turf; Cotton; Cucumber

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1982, first reported; 1985, first registered Japan

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Finland/Sweden
Date inclusion expires 31/05/2021
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A molecule with 2 chiral centres
Fórmula química C17H21ClN2O2S
Canonical SMILES CC1C(SC(=O)N1C(=O)NC2CCCCC2)C3=CC=C(C=C3)Cl
Isomeric SMILES C[C@H]1[C@@H](SC(=O)N1C(=O)NC2CCCCC2)C3=CC=C(C=C3)Cl
International Chemical Identifier Key (InChIKey) KYOUEHWYDNYHAL-IOORBXIBSA-N
International Chemical Identifier (InChI) InChI=1S/C17H21ClN2O2S/c1-11-15(12-7-9-13(18)10-8-12)23-17(22)20(11)16(21)19-14-5-3-2-4-6-14/h7-11,14-15H,2-6H2,1H3,(H,19,21)/t11-,15+/m0/s1
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Acaricide
Grupo químico Carboxamide
Minimum active substance purity 976 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action
CAS RN 78587-05-0
CEE número -
Número CIPAC 439
EPA américaine chimiques de code 128849
PubChem CID 13218777
Masa molecular (g mol-1) 352.88
PIN (Preferred Identification Name) -
Nombre IUPAC (4RS,5RS)-5-(4-chlorophenyl)-N-cyclohexyl-4-methyl-2-oxo-1,3-thiazolidine-3-carboxamide
Nombre CAS (4R,5R)-rel-5-(4-chlorophenyl)-N-cyclohexyl-4-methyl-2-oxo-3-thiazolidinecarboxamide
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 10A
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Brevipalpus phoenicis
Panonychus ulmi
Tetranychus urticae
Estado físico White to beige coloured powder
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Anorgachim SA
  • Hellafarm SA
  • Nippon
  • FCC
Example products using this active
  • Hexythiazox 10 WP
  • Bulk 10 WP
  • Nissorun 10WP
  • Ocaren
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Often supplied as a wettable powder that is mixed with water and used as a spray.


DESTINO AMBIENTAL

for hexythiazox

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.1 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 159000 A5 - Acetona -
22000 A5 - Etanol -
17000 A5 - Metanol -
4600 A5 - n-Heptano -
Punto de fusión (oC) 105.4 A5 -
Punto de ebullición (oC) 222 A5 -
El punto de degradación (oC) 300 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 4.68 X 1002 Calculado -
Log P 2.67 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.31 L3 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 1.33 X 10-03 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 1.19 X 10-02 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.03 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 202nm = 24220,225nm = 18390; [Acidic solution: 225.5nm = 18310; [Basic solution: 224.5nm = 16990 A5 -
Surface tension (mN m-1) 71.8 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 30 M4 Persistente moderado
DT50 (laboratorio en 20oC) 23.7 A5 No persistente
DT50 (campo) 17.7 A3 No persistente
DT90 (laboratorio en 20oC) 103.5 A5 -
DT90 (campo) 59.6 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier Lab studies DT50 range 7.8-56.0 days, n=6, DT90 range 32.2-117.2 days, field studies DT50 range 10-29 days, DT90 range 35-96 days
Dissipation rate RL50 on plant matrix Valor 12.0 R3 -
Nota Green bean pods, n=1
Dissipation rate RL50 on and in plant matrix Valor 3.6 R3 -
Nota Strawberry fruit, n=1
Acuoso fotólisis DT50 (días) en pH 7 Valor 17 L3 Lento
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable Q3 -
Nota -
Aqua-Sedimento DT50 (días) 37 A5 Moderado rápido
Fase de agua sola DT50 (días) 11.5 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 207 A5 No Móvil
Kfoc 9455
1/n 0.99
Notas y rango EU dossier Kf range 61-416, Kfoc range 6875-12823 mL/g, 1/n range 0.94-1.1, Soils=8
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
5-(4-chlorophenyl)-N-(4-oxocyclohexyl)-4-methyl-2-oxothiazolidine-3-carboxamide (Ref: PT-1-9) This metabolite may cause environmental pollution, click here for further information Suelo   0.211   Major fraction, Not relevant
trans-5-(4-chlorophenyl)-4-methyl-2-oxothiazolidine-3-carboximide (Ref: PT-1-2) This metabolite may cause environmental pollution, click here for further information Suelo   0.395   Major, Relevant
trans-5-(4-chlorophenyl)-4-methyl-2-oxothiazolidine (Ref: PT-1-3) Suelo   0.090   Major, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
5-(4-chlorophenyl)-N-( cis-4-hydroxylcyclohexyl)-4-methyl-trans-2-oxothiazolidine-3-carboxamide PT-1-8 ( cis) Rat (Urinary, Faeces) - -


ECOTOXICOLOGÍA

for hexythiazox

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 1100 A5 Whole fish Umbral de importancia
CT50 (días) 1 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - L3 Rata -
(ppm dieta) > 70 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Anas platyrhynchos Bajo
Birds - Short term dietary (LC50/LD50) > 523 mg kg-1 bw/día A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 3.2 A5 Lepomis macrochirus Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.04 A4 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 0.47 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0061 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 1.7 A5 Chironomus riparius, emergence Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.4 A5 Scenedemus subspicatus Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 200 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 112 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 105 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 300 48 hora
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 65.9 7 día
A4 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect @ 42 días
Carbon mineralisation: No significant adverse effect @ 14 días
A5
Dose: 1.7 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for hexythiazox

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 2.0 A5 Rat, 4 hr (whole body) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.03 A2 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.009 A3 Dog, 1 year, SF=100 -
Estudios den la absorción cutánea (%) 1-10 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public -
Occupational Occupational exposure may occur through inhalation and dermal contact
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; A5 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Possible liver toxicant
USEPA - probable human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Dust may form an explosive mix with air
Not oxidising
CLP classification 2013 Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S60, S61
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
US EPA Classification (formulation) IV - Caution - Not acutely toxic
Número de las NU Usually 3077
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for hexythiazox

Idioma Nombre
Inglés hexythiazox
Francés hexythiazox
Alemán Hexythiazox
Danés hexythiazox
Italiano exitiazox
Español hexitiazox
Griego hexythiazox
Esloveno heksitiazoks
Polaco heksytiazoks
Sueco hexytiazox
Húngaro hexitiazox
Holandés hexythiazox

Última actualización del registro: Thursday 23 August 2018
Contacto: aeru@herts.ac.uk