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mancoceb
** mancozeb ** manzeb ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Manacozeb is a commonly used fungicide approved for use in the EU and in manny other countries. It has a low aqueous solubility, is quite volatile and not expected to leach to groundwater. It is not persistent in soil systems but may be persistent in water under certain conditions. Mancozeb has a low mammalian toxicity by has been associated with adverse reproduction/development effects. It is highly toxic to fish and aquatic invertebrates, and moderately toxic to birds and earthworms. The toxicity of mancozeb to honeybees is low.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for mancozeb

Descripción: A fungicide for control of a wide range of pathogens including blights and scabs on crops

Example pests controlled: Potato blight; Leaf spot; Scab; Rust

Example applications: Potatoes; Fruit including apples, pears; Cotton; Corn; Sunflowers; Peanuts; Tomatoes; Cereals; Ornamental shrubs including roses

Availability status: Current

Introduction & key dates: 1961, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Italy
Date inclusion expires 31/01/2018

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, Estados Unidos

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Carbamate
Minimum active substance purity 800 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Broad spectrum, non-systemic, contact with protective action, acts by distrupting lipid metabolism. Multi-site activity.
CAS RN 8018-01-7
Alternative/old CAS RN formerly 8065-67-6
CEE número 006-076-00-1
Número CIPAC 34
EPA américaine chimiques de code 014504
Chiral molecule No
Fórmula química (C4H6MnN2S4)x(Zn)y
SMILES [Mn+2].[Zn+2].[S-]C(=S)NCCNC(=S)[S-].[S-]C(=S)NCCNC([S-])=S
International Chemical Identifier Key (InChIKey) CHNQZRKUZPNOOH-UHFFFAOYSA-J
International Chemical Identifier (InChI) InChl=1S/2C4H8N2S4.Mn.Zn/c2*7-3(8)5-1-2-6-4(9)10;;/h2*1-2H2,(H2,5,7,8)(H2,6,9,10);;/q;;2*+2/p-4
¿Es el diagrama de la estructura/imagen disponible?
Masa molecular (g mol-1) 271.3
PIN (Preferred Identification Name) -
Nombre IUPAC manganese ethylenebis(dithiocarbamate) (polymeric) complex with zinc salt
Nombre CAS [[2-[(dithiocarboxy)amino]ethyl]carbamodithioato]](2-)-kS,kS']manganese mixture with [[2-[(dithiocarboxy)amino]ethyl]carbamodithioato]](2-)-kS,kS']zinc
Otra información de estado Marine Pollutant
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) M3
Examples of recorded resistance -
Estado físico Grey to yellow coloured powder
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgriGuard
  • Certis
  • Dow AgroSciences
  • DuPont
  • Headland
  • Interfarm
  • Nufarm
  • Sipcam
  • Syngenta
Example products using this active
  • Fubol Gold
  • Dithane Dry Flowable
  • Dithane 945
  • Karamate DryFlo
  • Manzate 75WG
  • Matilda WG
  • Penncozeb
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as wettable granules and powders.


DESTINO AMBIENTAL

for mancozeb

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 6.2 G4 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) Insoluble A4 - La mayoría de los solventes orgánicos -
Punto de fusión (oC) Decomposes before melting A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 172 L3 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.14 X 1001 Calculado -
Log P 1.33 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.98 A5 -
Disociación constante (pKa) at 25oC 10.3 A5 -
Nota: Ácido muy débil
Presión de vapor en 25oC (mPa) 0.013 A5 Volátil
Constante de Henry a 25oC (Pa m3 mol-1) 5.90 X 10-04 A5 No volátil
Constante de Henry a 20oC (dimensionless) 1.76 X 10-10 Q2 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -1.00 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 2.84 X 10-06 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Degradación de suelo (días) (aerobic) DT50 (típico) 0.1 Click here to see a warning relating to modelling and this active substance A5 No persistente
DT50 (laboratorio en 20oC) 0.1 A5 No persistente
DT50 (campo) 18 H4 No persistente
DT90 (laboratorio en 20oC) 0.5 A5 -
DT90 (campo) - - -
Nota EU dossier lab studies DT50 range 1-3 hours, Dt90 range 2- 25 hours
Matriz de la planta DT50 (días) Valor 5.9 R4 -
Nota DT50 range 0.7 - 15.0 days, 14 crops/plants, various matrices
Acuoso fotólisis DT50 (días) en pH 7 Valor Estable A3 -
Nota Not a significant route of degradation
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 1.3 A4 No persistente
Nota pH variable: DT50 2-36 hours at pH 5, 5.5-55 hours at pH 7, 15 hours at pH 9
Aqua-Sedimento DT50 (días) 76 Q3 Moderado rápido
Fase de agua sola DT50 (días) 0.2 A5 Rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 9.7 A5 Móvil un poco
Koc 998
Notas y rango EU dossier Kd range 7.26-11.67 mL/g, Koc range 363-2334 mL/g, Soils=4
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 91/414 Importancia Click here for further information on 91/414 relevancy
ethylenethiourea Suelo   0.031   Minor fraction, Relevant
ethyleneurea Suelo   0.085   Minor fraction, Relevant
ethylene bisisothiocyanate sulphide Suelo   0.082   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
ethylene thiuram disulphide ETD Soil Very low -


ECOTOXICOLOGÍA

for mancozeb

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 3.2 A5 Bajo potencial
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A4 Median across species Bajo
Birds - Short term dietary (LC50/LD50) > 860 mg kg-1 bw/día A4 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.074 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.0022 A4 Oncorhynchus mykiss, 34 día NOEC Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.073 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0073 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.044 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 161.7 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) 140.6 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 299.1 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 20.0 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 75 Long term effect
Dose: 36 kg ha-1
A5 Typhlodromus pyri, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad -0.4 Mortalidad
Dose: 2.6 kg ha-1
A5 Aphidius rhopalosiphi
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 4.2 kg ha-1
-
Mesocosm study data NOEAEC mg l-1 0.032 A5 Invertebrates and phytoplankton -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for mancozeb

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.14 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.05 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.6 A5 Rat -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.035 A5 -
Estudios den la absorción cutánea (%) 0.11-0.24 A5 concentration dependant -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public -
Occupational -
European MRLs Click here for the EU MRL pesticide database
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana May cause ovarian hyperthropy
Possible thyroid toxicant
USEPA - probable human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive
IMDG Transport Code is usually 9
CLP classification 2013 Health: H317, H361d
Environment: H400
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Reproduction risk category 3: R63
Xn - Harmful: R43
N - Dangerous for the environment: R50
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S36/37, S46, S61
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
US EPA Classification (formulation) IV - Caution - Not acutely toxic
Número de las NU Variable with product, usually 3077 or 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for mancozeb

Idioma Nombre
Inglés mancozeb
Francés mancozebe
Alemán Mancozeb
Danés mancozeb
Italiano mancozeb
Español mancoceb
Griego mancozeb
Esloveno mankozeb
Polaco mankozeb
Sueco mankozeb
Húngaro mancozeb
Holandés mancozeb

Última actualización del registro: Monday 17 October 2016
Contacto: aeru@herts.ac.uk