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meptildinocap (Ref: DE 126)
** meptyldinocap ** GF-1478 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Meptyldinocap is a protectant, curative and eradicant fungicide approved for use in the EU. It has a low aqueous solubility, it is volatile and, based on its chemical propoerties, is unlikely to leach to groundwater. It is not persistent in soil and will usually degrade in water systems quickly. It is modertaely toxic to mammals and bioaccumlation may be a concern. Whilst it is not highly to toxic to birds is is toxic to many aquatic species including fish and algae.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for meptyldinocap

Descripción: A dinitrophenol fungicide that is a single isomer of dinocap and active against powdery mildew mainly on fruit and other crops

Ejemplos de plagas controladas: Powdery mildew

Ejemplos de aplicaciones: Vines; Curcubits; Fruit including apples, pears, peaches, plums, straberries, grapes,

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 2007

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK
Date inclusion expires 31/03/2025
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Chile; Africa; India

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism The single isomer of the existing active substance dinocap
Fórmula química C18H24N2O6
Canonical SMILES CCCCCCC(C)C1=CC(=CC(=C1OC(=O)C=CC)[N+](=O)[O-])[N+](=O)[O-]
Isomeric SMILES CCCCCCC(C)C1=CC(=CC(=C1OC(=O)/C=C/C)[N+](=O)[O-])[N+](=O)[O-]
International Chemical Identifier Key (InChIKey) NIOPZPCMRQGZCE-WEVVVXLNSA-N
International Chemical Identifier (InChI) InChI=1S/C18H24N2O6/c1-3-5-6-7-8-9-11-14-12-15(19(22)23)13-16(20(24)25)18(14)26-17(21)10-4-2/h4,10,12-13H,3,5-9,11H2,1-2H3/b10-4+
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Dinitrophenol
Minimum active substance purity 900 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Protectant, curative and eradicant activity by inhibiting spore germination. Uncoupler of oxidative phosphorylation
CAS RN 131-72-6
Alternative/old CAS RN 6119-92-2
CEE número 228-088-8
Número CIPAC 811
EPA américaine chimiques de code 036000
PubChem CID 5284389
Masa molecular (g mol-1) 364.39
PIN (Preferred Identification Name) -
Nombre IUPAC (RS)-2-(1-methylheptyl)-4,6-dinitrophenyl crotonate
Nombre CAS 2-(1-methylheptyl)-4,6-dinitrophenyl (2E)-2-butenoate
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 29
Examples of recorded resistance -
Estado físico Yellowish brown liquid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Dow AgroSciences
  • Landseer
Example products using this active
  • Kindred
  • karathane
  • GF-1478
Estado de UK LERAP None
Formulation and application details Usually supplied as an emulsifiable concentrate that is mixed with water and used as a spray.


DESTINO AMBIENTAL

for meptyldinocap

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.248 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 252000 A5 - Acetona -
256000 A5 - Acetato de etilo -
251000 A5 - n-Heptano -
256000 A5 - Xileno -
Punto de fusión (oC) -22.5 A5 - Freezing point -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 200 A5 -
Punto de inflamación (oC) 30 A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 3.55 X 1006 Calculado -
Log P 6.55 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.11 R4 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 0.00792 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 1.16 X 10-02 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -2.33 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Neutral & Acidic solution: 240nm = 16727, 310nm = 2155; [Basic solution: 260nm = 6575, 372nm = 12980, 405nm = 10969 A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 12.0 A5 No persistente
DT50 (laboratorio en 20oC) 12.0 A5 No persistente
DT50 (campo) 15 R4 No persistente
DT90 (laboratorio en 20oC) 64.7 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 4.1-22.4 days, DT90 range 13.7-122 days; Manufacturers published lab studies range 4-24 days (E3)
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor 2.8 R3 -
Nota Mango fruit, n=1
Acuoso fotólisis DT50 (días) en pH 7 Valor 0.4 A5 Rápido
Nota Natural light 40 deg N
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 43 A5 Persistente moderado
Nota pH sensitive: 447 days @ pH4, 229 days @ pH5, 56 and 30.4 days @ pH7, 0.7 and 9.3 days @ pH9, all at 20 deg C
Aqua-Sedimento DT50 (días) 3.54 A5 Rápido
Fase de agua sola DT50 (días) 5.7 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 705 A4 No Móvil
Kfoc 958245
1/n 1.05
Notas y rango EU dossier Kf range 52-3102mL/g, Kfoc range 2889-310200 mL/g, 1/n range 0.9-1.73, Soils=6; EU dossier and Manufacturers published data gives Kfoc/Koc range 2889-310200 mL/g
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
2,4-dinitro-6-octylphenol This metabolite may cause environmental pollution, click here for further information Suelo   0.22   Major fraction, Relevant
dinocap (Ref: ENT 24727) This metabolite may cause environmental pollution, click here for further information Suelo   0.832   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
2,4-dinitro-6-(1-methyl-beta-hydroxypentanoate)phenol - Rat (Urinary) - -
2,4-dinitro-6-(1-methyl-alpha,beta-pentanoate)phenol - Rat (Urinary) - -
2,4-diacetaminonitro-6-(1-methylpentanoate)phenol - Rat (Urinary) - -
2-acetoamino-4-nitro-6-(1-methyl-alpha,beta-pentenoate)phenol - Rat (Urinary) - -
2,4-dinitro-6-(1-methylpentanoate)phenol - Rat (Urinary) - -
2,4-dinitro-6-(1-methylbutanoate)phenol - Rat (Urinary) - -


ECOTOXICOLOGÍA

for meptyldinocap

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 992 A5 Whole fish Umbral de importancia
CT50 (días) 0.6 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2150 A4 Colinus virginianus, for dinocap Bajo
Birds - Short term dietary (LC50/LD50) 344 mg kg-1 bw/día A4 Colinus virginianus, as dinocap -
Pez - agudo 96 hora LC50 (mg l-1) 0.0569 A5 Lepomis macrochirus Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.00286 A5 Pimephales promelas, 34 día Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.0041 A4 Daphnia pulicaria Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.00076 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 2.12 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 84.8 A5 Moderado
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 90 A5 Moderado
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Lombrices - Agudos 14 día LC50 (mg kg-1) 302 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms Agudos LC50 (mg kg-1) - - -
Crónicos NOEC (mg kg-1) - - -
Otro arthropoda (1) LR50 g ha-1 10.91 A5 Typhlodromus pyri -
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 16.7
28.8
Mortalidad
Parasitismo
Dose: 0.84 kg ha-1
R4 Aphidius rhopalosiphi
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.62 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for meptyldinocap

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 1.24 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.016 A3 proposed Dog, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.12 A3 proposed Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.008 A3 proposed Dog, SF=200 -
Estudios den la absorción cutánea (%) 1.0-10.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Exposure Routes Public Acceptable risks for proposed uses
Occupational Acceptable risks for proposed uses
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A3; B0; C3; D0; E0

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana Possible liver and thyroid toxicant
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Flammable
Not explosive or oxidising
IMDG Transport Code is usually 3
CLP classification 2013 Health: H302, H315, H317, H319, H332, H336, H360, H373
Handling: H226
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R43
H - Handling risks: R10
N - Dangerous for the environment: R50/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S24, S37, S60, S61
Clasificación de OSM NL - No inscripto en la lista
Número de las NU Usually 1993
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for meptyldinocap

Idioma Nombre
Inglés meptyldinocap
Francés meptyldinocap
Alemán Meptyldinocap
Danés meptyldinocap
Italiano meptyldinocap
Español meptildinocap
Griego -
Esloveno meptildinokap
Polaco meptyldinokap
Sueco -
Húngaro -
Holandés -

Última actualización del registro: Wednesday 27 November 2019
Contacto: aeru@herts.ac.uk