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metconazol
** metconazole ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for metconazole

Descripción: A new fungicide used to control a range of fungal infections on fruit and other crops

Ejemplos de plagas controladas: Alternaria; Rusts; Fusarium; Septoria diseases; Rhynchosporium secalis

Ejemplos de aplicaciones: Cereals including wheat, barley, rye, oats; OSR; Fruit including blueberry, cherry, gooseberry, nectarine, peach, plum; Pistachio; Turf and sod

Eficacia y actividad: Wheat/Mildew=Low; Wheat/Septoria=Low; Wheat/Rust=Moderate; Wheat/Ear blight=Moderate; Barley/Rhynchosporium=Low; Barley/Rust=Moderate; Barley/Net blotch=Low; Barley/Ramularia=Low

Availability status: Current

Introduction & key dates: 1994, France

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Belgium/UK
Date inclusion expires 30/04/2020
UE Candidatas a sustitución Yes - two 'Persistent-Bioaccumulative-Toxic' criteria
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A molecule with two chiral centres giving 4 stereoisomers. The cis-form is a mixture of the (1R,5S) and (1S,5R) isomers and is more bioactive than the trans form.
Fórmula química C17H22ClN3O
Canonical SMILES CC1(CCC(C1(CN2C=NC=N2)O)CC3=CC=C(C=C3)Cl)C
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) XWPZUHJBOLQNMN-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C17H22ClN3O/c1-16(2)8-7-14(9-13-3-5-15(18)6-4-13)17(16,22)10-21-12-19-11-20-21/h3-6,11-12,14,22H,7-10H2,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Triazole
Minimum active substance purity 940 g/kg sum of cis- and trans-isomers
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Systemic, ergosterol biosynthesis inhibitor
CAS RN 125116-23-6
CEE número -
Número CIPAC 706
EPA américaine chimiques de code 125619
PubChem CID 86210
Masa molecular (g mol-1) 319.83
PIN (Preferred Identification Name) -
Nombre IUPAC (1RS,5RS;1RS,5SR)-5-(4-chlorobenzyl)-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol
Nombre CAS 5-[(4-chlorophenyl)methyl]-2,2-dimethyl-1-(1H-1,2,4-triazol-1-ylmethyl)cyclopentanol
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 3
Examples of recorded resistance -
Estado físico Off-white crystals
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • BASF
  • Clayton
  • Kureha Corp
Example products using this active
  • Caramba 90
  • Sunorg Pro
  • Juventus
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as a soluble liquid concentrate that is mixed with water and used as a spray.


DESTINO AMBIENTAL

for metconazole

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 30.4 B5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 1400 A5 - Hexano -
103000 A5 - Tolueno -
403000 A5 - Metanol -
363000 A5 - Acetona -
Punto de fusión (oC) 104.2 A5 -
Punto de ebullición (oC) 315 A5 -
El punto de degradación (oC) - - -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 7.08 X 1003 Calculado -
Log P 3.85 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.14 A5 -
Disociación constante (pKa) at 25oC 11.38 A5 -
Nota: pKa(2) 1.08
Presión de vapor en 20oC (mPa) 2.10 X 10-05 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 2.21 X 10-07 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 2.05 Calculado Estado de transición
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 8.88 X 10-02 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 196nm = 17700, 221nm = 5900, 226nm (shoulder) = 4600, 262nm = 150, 268nm = 190 A5 -
Surface tension (mN m-1) 48.6 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 142.2 A5 Persistente
DT50 (laboratorio en 20oC) 142.2 A5 Persistente
DT50 (campo) 134.7 A5 Persistente
DT90 (laboratorio en 20oC) 745 A5 -
DT90 (campo) 599 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier 2018 lab studies DT50 range 69-569 days, DT90 range 291.3->1000 days, Soils=7, field studies DT50 range 26.6-368.5 days, DT90 range 102.9->1000 days, Soils=6;
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 83 A5 Estable
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable pH 4 to pH 9
Aqua-Sedimento DT50 (días) 465 A5 Estable
Fase de agua sola DT50 (días) 8 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 23.05 A5 Móvil un poco
Kfoc 1116
1/n 0.843
Notas y rango EU dossier Kf range 7.91-39.35 mL/g, Kfoc range 726-1718 mL/g, 1/n range 0.666-1.020, Soils=9
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
(2-hydroxy-3,3-dimethyl-2-(1,2,4)triazol-1-ylmethyl-cyclopentyl)-(4-chlorophenyl)-methanone (Ref: CL 382389) Suelo   0.046   Minor fraction, Relevant
1,2,4-triazole (Ref: CGA 71019) Suelo   0.091   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
- triazolyl alanine Plant - -
- triazolyl acetic acid Plant - -
IMPURITIES: - - - -
(Ref: CL354282) - - - -
(Ref: CL357625) - - - -
3-(4-chlorobenzyl)-2-hydrooy-1-methyl-2-[1,2,4]triazol-1-ylmethyl-cyclopentane-carboxylic acid
(Ref: CL359139)
- Water - -
(Ref: CL395834) hydroxymetconazole Water/sediment - -


ECOTOXICOLOGÍA

for metconazole

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 105.1 A5 Umbral de importancia
CT50 (días) 1 -
Mamíferos - Agudos oral LD50 (mg kg-1) 595 B5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 4 A5 Conejo Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 787 A5 Colinus virginianus Moderado
Birds - Short term dietary (LC50/LD50) 167.9 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 2.1 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) 1.14 A4 Oncorhynchus mykiss, 28 día Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 4.2 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.16 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 2.12 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants > 0.112 A5, Lettuce, Radish, Onion, Wheat, Soybean
Seedling emergence, NOEC
as kg/ha
-
0.112 A5, Lettuce, Radish, Onion, Wheat, Soybean
Vegetative vigour, NOEC
as kg/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 1.7 A5 Raphidocelis subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Apis mellifera Bajo
Oral aguda 48 hora LD50 (μg abeja-1) 85 A5 Apis mellifera Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) > 20 A5 Eisenia foetida, corr Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 8.47 Mortalidad
A5 Typhlodromus pyri
-
% Causalidad -45.2 Mortalidad
Dose: 2 x 90 g ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 41.1 Mortalidad
A5 Typhlodromus pyri
-
% Causalidad 3.4 Mortalidad
Dose: 2 x 90 g ha-1
A5 Typhlodromus pyri, protonymph
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.9 kg ha-1, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for metconazole

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 595 B5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.2 A5 Rat, 4hr -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 SF=400 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.01 A5 Rabbit, SF=400 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) 0.01 A5 Rabbit, SF=100 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.01 A5 SF=100 -
Estudios den la absorción cutánea (%) 4.0-28.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Negligible risk to bystanders
Occupational Risk of exposure acceptable under label recommendations for use for personal protection clothing and equipment
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana Possible liver toxicant

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 3
CLP classification 2013 Health: H302, H361d
Environment: H411
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Reproduction risk category 3: R63
Xn - Harmful: R22
N - Dangerous for the environment: R51, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S36/37, S46, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU Variable with product, usually 1993 or 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for metconazole

Idioma Nombre
Inglés metconazole
Francés metconazole
Alemán Metconazol
Danés metconazol
Italiano metconazolo
Español metconazol
Griego -
Esloveno metkonazol
Polaco metkonazol
Sueco -
Húngaro metkonazol
Holandés metconazool

Última actualización del registro: Tuesday 04 June 2019
Contacto: aeru@herts.ac.uk