Seleccione la Opción
Inicio
A a Z Indice
Búsqueda
Términos y Condiciones
Información de Asistencia
Compras y Servicios
GET ADDITIONAL DATA HERE!

metiram (Ref: BAS 222F)
** metiram ** carbatene ** metirame ** zinc metiram ** polyram ** FMC 9102 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for metiram

Descripción: A fungicide used to control a wide range of fungal diseases including damping-off

Ejemplos de plagas controladas: Scab; Downey mildew; Blight

Ejemplos de aplicaciones: Top fruit; Grapes; Potatoes; Tomatoes; Onion & garlic; Celeriac; Cucubits; Lettuce; Field crops; Herbs; Ornamentals; Asparagus; Cotton

Eficacia y actividad: Efficiacy has been demonstrated by its long-term and extensive use in the EU and many other countries as well as via field trials

Availability status: Current

Introduction & key dates: 1958, introduced Germany

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Italy/UK
Date inclusion expires 31/01/2020
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química (C16H33N11S16Zn3)x
Canonical SMILES C(CNC(=S)[S-])NC(=S)S.C(CNC(=S)[S-])NC(=S)S.[NH2-].[Zn]
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) VHQATEKXKUZBLS-UHFFFAOYSA-L
International Chemical Identifier (InChI) InChI=1S/C4H8N2S4.H3N.Zn/c7-3(8)5-1-2-6-4(9)10;;/h1-2H2,(H2,5,7,8)(H2,6,9,10);1H3;/q;;+2/p-2
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Carbamate
Minimum active substance purity 840 g/kg
Known relevant impurities EU dossier - ethylene thiourea my not be toxicologically relevant
Sustancias de origen Sintéticas
Modo de acción Broad spectrum, non-systemic with protective action. Multi-site activity.
CAS RN 9006-42-2
Alternative/old CAS RN 9063-14-3
CEE número -
Número CIPAC 478
EPA américaine chimiques de code 014601
PubChem CID No data
Masa molecular (g mol-1) (1088.6)x
PIN (Preferred Identification Name) -
Nombre IUPAC zinc ammoniate ethylenebis(dithiocarbamate) - poly(ethylenethiuram disulfide)
Nombre CAS metiram
Otra información de estado Marine pollutant
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) M3
Examples of recorded resistance -
Estado físico Yellow powder
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • BASF
  • FMC
Example products using this active
  • Carbatene
  • Polyram
  • Polyram-Combi
Estado de UK LERAP None
Formulation and application details Usually supplied as a wettable powder.


DESTINO AMBIENTAL

for metiram

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 2 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 100 A3 - Metanol -
100 A3 - Acetona -
100 A3 - Tolueno -
100 A3 - Acetato de etilo -
Punto de fusión (oC) 156 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 156 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.14 X 1000 Calculado -
Log P 0.33 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.86 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 1.0 X 10-05 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 4.0 X 10-05 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -0.22 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 259nm = 64000, 281nm = 48000, 29 nm = 30000 A5 -
Surface tension (mN m-1) 71.8 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 1.3 A5 No persistente
DT50 (laboratorio en 20oC) 1.3 A5 No persistente
DT50 (campo) 7 A3 No persistente
DT90 (laboratorio en 20oC) 4.7 A5 -
DT90 (campo) 14 A3 -
Endpoint de modelado DT50 - - -
Nota EU 2017 dossier lab studies DT50 (normalised) range 0.5-2.2 days, DT90 range 1.7-17.3 days, Soils=5, EU 2001 Dossier field studies DT50 ~7days, DT90 <14 days; Other sources: 20 days (DW4)
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 0.3 A5 Rápido
Nota 6.3 hours in continuous irradiation, 0.6 days central Europe scenario, March
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 0.1 A5 No persistente
Nota pH sensitive
Aqua-Sedimento DT50 (días) 0.2 A5 Rápido
Fase de agua sola DT50 (días) 0.4 A5 Rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 8800 A5 No Móvil
Koc 903012
Notas y rango EU 2017 dossier Kd range 4553-11891 mL/g, Koc range 393044-1801689mL/g, Soils=5
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
ethylenethiourea This metabolite may cause environmental pollution, click here for further information Suelo   0.112   Major fraction, Relevant
ethylene bisisothiocyanate sulphide This metabolite may cause environmental pollution, click here for further information Suelo   0.257   Major fraction, Relevant
ethyleneurea Suelo   0.069   Minor fraction, Relvant
2,3,7,8-tetrahydroiimidazo(2.1-b:1',2'-e)(1,3,5)thiadizine-5-thione This metabolite may cause environmental pollution, click here for further information Suelo   0.135   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
carbimid
(Ref: )
Nota: Major fraction, Relevant
- Soil - -
- TDIT Soil 0.135 -
- hydantoin Water - -


ECOTOXICOLOGÍA

for metiram

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 3.2 Q3 Bajo potencial
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) > 50 G3 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2150 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) 853 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) 0.336 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.022 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.584 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0043 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) > 144 A5 Chironomus tentans Bajo
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.221 A5 Chironomus tentans Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) 21.6 A5 Chironomus tentans Moderado
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 0.517 A5 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.191 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 80 A5 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) > 80 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 1000 A5 Bajo
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) > 23.3 A5 Eisenia foetida, 56día Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 14 Lethal
Dose: 4 kg ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 100 Lethal
Dose: 0.7 kg ha-1
A5 Typhlodromus pyri
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 48 kg ha-1
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for metiram

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.7 A5 Rat 4 hr, (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.03 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.4 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) Ningunos asignaron A5 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.016 A5 Dog, SF=100 -
Estudios den la absorción cutánea (%) 0.2-3.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public -
Occupational -
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

Cuestiones generales de la salud humana USEPA - probable human carcinogen
Possible thyroid toxicant

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
CLP classification 2013 Health: H317, H373
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22
Xi - Irritant: R38
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S13, S37, S46
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
US EPA Classification (formulation) IV - Caution - Not acutely toxic
Número de las NU 3077
Waste disposal & packaging Click here for a description of UN packaging marks Packging Group III (minor danger)


TRADUCCIONES

for metiram

Idioma Nombre
Inglés metiram
Francés métirame zinc
Alemán Metiram
Danés metiram
Italiano metiram
Español metiram
Griego -
Esloveno metiram
Polaco metiram
Sueco -
Húngaro metiram
Holandés -

Última actualización del registro: Wednesday 03 April 2019
Contacto: aeru@herts.ac.uk