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azinfos-metil
** azinphos-methyl ** azinphosmethyl ** metiltriazotion ** cotnion methyl ** gusathion methyl ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Azinphos-methyl is an organophosphate insecticide that is not approved for use in the EU. It has a low aqueous solubility, is volatile and not expected to leach to groundwater. It is generally not persistent in soil or water systems. Azinphos-methyl is highly toxic to mammals but is not expected to bioaccumulate. It is a neurotoxicant and an acetyl cholinesterase inhibitor. It is highly toxic to birds, honeybees and most aquatic life. It is moderately toxic to earthworms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for azinphos-methyl

Descripción: An organophosphorus insecticide for the control of sucking and chewing pests

Ejemplos de plagas controladas: Mites, Ticks, Aphids; Slugs; Snails

Ejemplos de aplicaciones: Lowland rice; Fruit; vegetables; Tobacco; Nuts; Ornamentals

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1955

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur Germany
Date inclusion expires Expired
UE Candidatas a sustitución -
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism None
Fórmula química C10H12N3O3PS2
Canonical SMILES COP(=S)(OC)SCN1C(=O)C2=CC=CC=C2N=N1
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) CJJOSEISRRTUQB-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C10H12N3O3PS2/c1-15-17(18,16-2)19-7-13-10(14)8-5-3-4-6-9(8)11-12-13/h3-6H,7H2,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Azinphos-methyl - Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Acaricide, Mollusicide
Grupo químico Organophosphate
Minimum active substance purity -
Known relevant impurities -
Sustancias de origen Sintéticas
Modo de acción Non-systemic, contact and stomach action. Cholinesterase inhibitor.
CAS RN 86-50-0
CEE número 201-676-1
Número CIPAC 37
EPA américaine chimiques de code 058001
PubChem CID 2268
Masa molecular (g mol-1) 317.32
PIN (Preferred Identification Name) O,O-dimethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] phosphorodithioate
Nombre IUPAC S-3,4-dihydro-4-oxo-1,2,3-benzotriazin-3-ylmethyl O,O-dimethyl phosphorodithioate
Nombre CAS O,O-dimethyl S-[(4-oxo-1,2,3-benzotriazin-3(4H)-yl)methyl] phosphorodithioate
Otra información de estado Potential groundwater contaminant; Severe Marine Pollutant; Chemical subject to PIC regulations
Relevant Environmental Water Quality Standards UK statutory standard for protection of inland, coastal and territorial waters for aquatic life 0.01 ug/L as annual average
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 1B
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Predatory mites
Aphids
Lacewings
Codling moth
Leaf miners
plus others
Estado físico White crystals
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Makhteshim Agan
  • General Quimica S.A.
  • Bayer
  • Mobay
Example products using this active
  • Gusathion M
  • Co-thion
  • Azinpaz
  • Carfene
  • Guthion
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually supplied as concentrate suspensions, liquids and wettable powders.


DESTINO AMBIENTAL

for azinphos-methyl

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 28 H4 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 250000 L3 - Acetona -
250000 L3 - Acetato de etilo -
170000 L3 - Xileno -
1200 L3 - n-Heptano -
Punto de fusión (oC) 73 L3 -
Punto de ebullición (oC) Decomposes before boiling V3 -
El punto de degradación (oC) 200 L3 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable V3 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 9.12 X 1002 Calculado -
Log P 2.96 H4 Moderado
Masa densidad (g ml-1)/Peso específico 1.52 L3 -
Disociación constante (pKa) at 25oC 5 Q3 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 5.00 X 10-04 L3 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 5.70 X 10-06 L3 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 1.42 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 3.40 X 10-02 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 10 W4 No persistente
DT50 (laboratorio en 20oC) 31 A3 Persistente moderado
DT50 (campo) - - -
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota: -
Dissipation rate RL50 on plant matrix Valor 8.7 R4 -
Nota Published literature RL50 range 1.0-30.0 days, 8 field crops, various matrices, n=11; Apples & lemons in cold storage RL50 range 46-122 days
Dissipation rate RL50 on and in plant matrix Valor 8.8 R4 -
Nota Published literature RL50 range 4.0-16.0 days, 6 field crops, various matrices, n=6
Acuoso fotólisis DT50 (días) en pH 7 Valor 3 E4 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 50 L3 Persistente moderado
Nota DT50 87 days at pH 4, 4 days at pH 9
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) - - -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 10.9 A5 Móvil un poco
Koc 1112
Notas y rango EU dossier Kd range 3.33-28.5 mL/g, Koc range 425-1282 mL/g, Soils=10
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad No


ECOTOXICOLOGÍA

for azinphos-methyl

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 40 P4 Bajo potencial
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) 9 L3 Rata Alto
Mamíferos - a corto plazo NOEL (mg kg-1) - L2 Rata, 2 año -
(ppm dieta) 5 -
Pájaros/aves - Agudos LD50 (mg kg-1) 32 L3 Colinus virginianus Alto
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.02 L3 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.00017 J3 Pimephales promelas Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.0011 J4 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.0004 F3 Daphnia magna, LOEC Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.00022 F4 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 7.15 L3 Raphidocelis subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 0.42 R4 Alto
Oral aguda 48 hora LD50 (μg abeja-1) - - -
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 59 L3 Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad Nocivo Dose: 300 g ha-1
AA3 Typhlodromus pyri
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad Nocivo Dose: 300 g ha-1
AA3 Chrysoperla carnea
-
Soil micro-organisms - - -
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for azinphos-methyl

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 9 L3 Rata Alto
Mammals - Dermal LD50 (mg kg-1 body weight) 175 L3 Rat -
Mammals - Inhalation LC50 (mg l-1) 0.15 L3 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.005 A5 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.1 JMPR 2007 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) - - -
Estudios den la absorción cutánea (%) - - -
Directivo 76/464 Sustancias Peligrosas List I; List II - -
Limites de exposiciones [UK LT TWA 8 hr: 0.2 mg/m3], [UK ST 15 mins: 0.6 mg/m3] Occupation Exposure -
Exposure Routes Public -
Occupational -
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana No further information available

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes IMDG Transport Code is 6.1
CLP classification 2013 Health: H300, H311, H317, H330
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T+ - Very toxic: R26/28
T - Toxic: R24
Xn - Harmful: R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S28, S45, S61, S36/37, S60
Clasificación de OSM Ib - Peligroso alto
US EPA Classification (formulation) I - Danger - Highly toxic
Número de las NU Active 2783, liquid products usually 3018
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for azinphos-methyl

Idioma Nombre
Inglés azinphos-methyl
Francés azinphos-methyle
Alemán Azinphos-methyl
Danés azinphos-methyl
Italiano azinfos-metile
Español azinfos-metil
Griego azinphos-methyl
Esloveno azinfosmetil
Polaco azinofos metylowy
Sueco azinfosmetyl
Húngaro azinphos-metil
Holandés azinfos-methyl

Última actualización del registro: Tuesday 30 October 2018
Contacto: aeru@herts.ac.uk