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fosalon (Ref: ENT 27163)
** phosalone ** benzofos ** benzphos ** NPH 1090 ** O,O-diethyl phosphorodithioate ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for phosalone

Descripción: An insecticide and acaricide used to control Coleoptera, Homoptera, Lepidoptera and other pests mainly on fruit

Ejemplos de plagas controladas: Red spider mite; Caterpillars; Beetles; Codling moth; Seed weevil; Fruit maggots

Ejemplos de aplicaciones: Potatoes; Artichokes; Nuts; Fruit including citrus, apples, pears, plums, apricots, grapes; Nuts; Roses

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: circa 1965

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur Austria
Date inclusion expires Expired
UE Candidatas a sustitución No aplicable
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C12H15ClNO4PS2
Canonical SMILES CCOP(=S)(OCC)SCN1C2=C(C=C(C=C2)Cl)OC1=O
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) IOUNQDKNJZEDEP-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C12H15ClNO4PS2/c1-3-16-19(20,17-4-2)21-8-14-10-6-5-9(13)7-11(10)18-12(14)15/h5-7H,3-4,8H2,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Acaricide
Grupo químico Organophosphate
Minimum active substance purity 940 g/kg
Known relevant impurities EU dossier - S-chloromethyl O,O-diethyl phosphorodithioate
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action. Acetylcholinesterase (AChE) inhibitor.
CAS RN 2310-17-0
CEE número 218-996-2
Número CIPAC 109
EPA américaine chimiques de code 097701
PubChem CID 4793
Masa molecular (g mol-1) 367.8
PIN (Preferred Identification Name) -
Nombre IUPAC S-6-chloro-2,3-dihydro-2-oxo-1,3-benzoxazol-3-ylmethyl O,O-diethyl phosphorodithioate
Nombre CAS (S-)(6-chloro-2-oxo-3(2H)-benzoxazolyl)methyl) O,O-diethyl phosphorodithioate
Otra información de estado Severe Marine Pollutant; Chemical subject to PIC regulations
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 1B
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Boophilus microplus
Choristoneura rosaceana
Myzocallis coryli
Myzus persicae
Phorodon humuli
many others
Estado físico Colourless crystals
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Rhone-Poulenc
Example products using this active
  • Zolone
  • Azonfene
  • Benzofos
  • Rubitox
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Supplied as an emulsifiable concentrate formulation for foliar, ground and aerial applications.


DESTINO AMBIENTAL

for phosalone

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 1.4 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 1000000 A5 - Acetona -
26300 A5 - n-Heptano -
1000000 A5 - Tolueno -
1000000 A5 - Acetato de etilo -
Punto de fusión (oC) 46.9 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 174.6 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.02 X 1004 Calculado -
Log P 4.01 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.49 A5 -
Disociación constante (pKa) at 25oC - - -
Nota:
Presión de vapor en 20oC (mPa) 1.56 X 10-02 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 2.04 X 10-03 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.21 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.55 X 10-04 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 203nm = 46918, 236nm = 14820, 284nm = 4602, 291nm = 3575 A5 -
Surface tension (mN m-1) 71.78 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 2 A5 No persistente
DT50 (laboratorio en 20oC) 2 A5 No persistente
DT50 (campo) - - -
DT90 (laboratorio en 20oC) 7.2 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 0.8-4.9 days, DT90 range 2.8-16.3 days; Other sources: DT50 21 days (DW3)
Dissipation rate RL50 on plant matrix Valor 4.7 R4 -
Nota Published literature RL50 range 1.4-9.9 days, 5 field & undercover grown crops, various matrices, n=7
Dissipation rate RL50 on and in plant matrix Valor 6.5 R4 -
Nota Published literature RL50 range 2.5-16.0 days, 3 field crops, various matrices, n=4
Acuoso fotólisis DT50 (días) en pH 7 Valor 3.8 A5 Moderado rápido
Nota DT50 1.8 days in summer, 5.8 days in winter, artificial light, 40 deg N
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 321 A5 Persistente
Nota pH sensitive: DT50 365 days at pH 4, 17.8 days at pH 9, all at 20 degC
Aqua-Sedimento DT50 (días) 4 A5 Rápido
Fase de agua sola DT50 (días) 2.8 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 21.2 A5 Móvil un poco
Koc 2063
Notas y rango EU dossier Koc range 870-2680 mL/g, degradation reported with clay
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad No

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
desethyl phosalone Phosalone metabolite M01 Rat - -
2-amino-7-chloro-3H-phenoxazin-3-one
(Ref: AE 0651017)
- unknown - -
phenoxazone
(Ref: AE 0651017)
Nota: Possible groundwater contaminant
RP18726 Water - -
6-chloro-2(3H)-benzoxazolone
(Ref: AE F054014)
- Water (Hydrolysis @ pH9) - -
2-amino-5-chlorophenol
(Ref: AE F114970)
- Water (Anaerobic) - -
S-6-chloro-2,3-dihydro-2-oxo-benzoxazol-3-ylmethyl
(Ref: AE0941954)
- Water (Hydrolysis @ pH9) - -
deschlorophosalone
(Ref: RP 11690)
- Plant - -
6-chlorobenzoxazolone
(Ref: RP 11881)
- Plant - -
oxophosalone
(Ref: RP 12244)
- Plant - -
2-hydroxy-p-chloroaniline
(Ref: RP 18709)
- Rat - -
6-chloro-2,3-dihydro-3-methylsulfinylmethyl-1,3-benzoxazol-2-one
(Ref: RP 19889)
- Animal (Liver) - -
6-chloro-2,3-dihydro-3-methylthiomethyl-1,3-benzoxazol-2-one
(Ref: RP 19914)
- Animal (Liver) - -


ECOTOXICOLOGÍA

for phosalone

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 180 A5 Whole fish Umbral de importancia
CT50 (días) 0.71 -
Mamíferos - Agudos oral LD50 (mg kg-1) 120 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 0.9 45 Rata, NOAEL Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) 503 A4 Gallus gallus Moderado
Birds - Short term dietary (LC50/LD50) 1659 mg kg feed-1 A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 0.63 A5 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.056 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.00074 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.00014 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.019 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 1.1 A5 Scenedemus subspicatus Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.1 Q2 Unknown species Moderado
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 4.4 A5 Apis mellifera Moderado
Oral aguda 48 hora LD50 (μg abeja-1) 102 A5 Apis mellifera Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 22.5 A5 Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 0.72 kg ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 45.8 7 día
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 12.7 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for phosalone

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 120 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) 1530 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 1.26 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 Dog, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.1 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.01 A2 Dog, SF=100 -
Estudios den la absorción cutánea (%) 0.7-3.6 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas List I; List II - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Dietary risk is considered low
Occupational Risk of exposure acceptable under label recommendations for use for personal protection clothing and equipment
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana No further information available

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Prevent generation of dust
Not explosive
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H301, H312, H317, H332
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T - Toxic: R25
Xn - Harmful: R20/21, R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S36/37, S45, S60, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) II - Warning - Moderately toxic
Número de las NU 2783
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for phosalone

Idioma Nombre
Inglés phosalone
Francés phosalone
Alemán Phosalon
Danés phosalon
Italiano fosalone
Español fosalon
Griego -
Esloveno fosalon
Polaco fosalon
Sueco -
Húngaro phosalon
Holandés -

Última actualización del registro: Tuesday 14 May 2019
Contacto: aeru@herts.ac.uk