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propaquizafop (Ref: CGA 233380)
** propaquizafop ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for propaquizafop

Descripción: A post-emergence herbicide used to control annual grass weeds and volunteer cereals in a range of crops

Ejemplos de plagas controladas: Wild oats; Sweet signal grass; Couch grass; Grabgrass; Goose grass; Common buffalo grass; Italian ryegrass

Ejemplos de aplicaciones: Sugarbeet; Oilsed rape; Soybean; Sunflower; Vegetables; Fruit; Potatoes

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: circa 1991

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK/Estonia
Date inclusion expires 30/11/2021
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Isomeric
Fórmula química C22H22ClN3O5
Canonical SMILES CC(C(=O)OCCON=C(C)C)OC1=CC=C(C=C1)OC2=CN=C3C=C(C=CC3=N2)Cl
Isomeric SMILES C[C@H](C(=O)OCCON=C(C)C)OC1=CC=C(C=C1)OC2=CN=C3C=C(C=CC3=N2)Cl
International Chemical Identifier Key (InChIKey) FROBCXTULYFHEJ-OAHLLOKOSA-N
International Chemical Identifier (InChI) InChI=1S/C22H22ClN3O5/c1-14(2)26-29-11-10-28-22(27)15(3)30-17-5-7-18(8-6-17)31-21-13-24-20-12-16(23)4-9-19(20)25-21/h4-9,12-13,15H,10-11H2,1-3H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Herbicida
Grupo químico Aryloxyphenoxypropionate
Minimum active substance purity -
Known relevant impurities EU dossier - toluene <5 g/kg
Sustancias de origen Sintéticas
Modo de acción Systemic, absorbed by foliage and roots and translocated. ACCase inhibitor.
CAS RN 111479-05-1
CEE número -
Número CIPAC 713
EPA américaine chimiques de code -
PubChem CID 16213016
Masa molecular (g mol-1) 443.88
PIN (Preferred Identification Name) -
Nombre IUPAC 2-isopropylideneaminooxyethyl (R)-2-[4-(6-chloroquinoxalin-2-yloxy)phenoxy]propionate
Nombre CAS 2-[[(1-methylethylidene)amino]oxy]ethyl (2R)-2-[4-[(6-chloro-2-quinoxalinyl)oxy]phenoxy]propanoate
Otra información de estado OSPAR soc
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) A
Herbicide Resistance Classification (WSSA) 1
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Alopecurus myosuroides
Brachiaria plantaginea
Eleusine indica
Estado físico Off-white coloured powder
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgriGuard
  • Greencrop
  • Makhteshim-Agan
  • Standon
  • Teliton
Example products using this active
  • Falcon
  • Shogun
  • Zealot
  • Agil 100EC
  • Longhorn
Estado de UK LERAP None
Formulation and application details Often supplied as emulsifiable concentrates that are mixed with water and used as a spray.


DESTINO AMBIENTAL

for propaquizafop

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.63 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 500000 A5 - Acetona -
100000 C4 - Cloroformo -
76000 A5 - Metanol -
500000 A5 - Tolueno -
Punto de fusión (oC) 66.3 A5 -
Punto de ebullición (oC) Decomposes before boiling A3 -
El punto de degradación (oC) 260 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 6.03 X 1004 Calculado -
Log P 4.78 A5 Alto
Masa densidad (g ml-1)/Peso específico 0.96 B5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: No dissociation between pH 4 and pH 9
Presión de vapor en 20oC (mPa) 4.39 X 10-07 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 9.20 X 10-08 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index - - -
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor - - -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - - -
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 235.0nm = 30500, 334.0nm = 5850; [Acidic solution: 235.0nm = 30000, 334.0nm = 5810; [Basic solution: 235.0nm = 29700, 334.0 nm = 5790; [No absorbance found between 400 and 750nm A5 -
Surface tension (mN m-1) 53.5-55.4 A5 at 20oC -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 2.1 A5 No persistente
DT50 (laboratorio en 20oC) 1.3 A5 No persistente
DT50 (campo) 85 A5 Persistente moderado
DT90 (laboratorio en 20oC) 20 A4 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab study DT50 <3days, field studies DT50 range 15-215 days, DT90 range 2-56 days; Other field studies DT50 range 15-26 days for spring applications
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 32 A5 Estable
Nota Data for seasonal average at 50 deg N. No difference between light and dark conditions.
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 32 A5 Persistente moderado
Nota pH sensitive: DT50 10.5 days at pH 5, 12.9 hours at pH 9
Aqua-Sedimento DT50 (días) <1 A5 -
Fase de agua sola DT50 (días) <1 A5 -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
quizalofop (Ref: CGA 287422) This metabolite may cause environmental pollution, click here for further information Suelo   0.879   Major fraction, Relevant
hydroxy quizalofop (Ref: CGA 294972) This metabolite may cause environmental pollution, click here for further information Suelo   0.326   Major fraction, Relevant
dihydroxy quinoxaline (Ref: CGA 294970) This metabolite may cause environmental pollution, click here for further information Suelo   0.137   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
2-[4-(6-chloroquinoxalin-2-yloxy)phenol] quizalofop-phenol Plant - -
(R)-2-[4-(6-chloro-3-hydroxyquinoxalin-2-yloxy)phenoxy]propionic acid hydroxy-quizalofop-phenol Plant - -
6-chloroquinoxalin-2-ol
Nota: Possible groundwater contaminant
hydroxyquinoxaline Plant; Soil (Aerobic) - -
6-chloroquinoxaline-2,3-diol dihydroxy-quinoxaline Plant; Soil (Aerobic); Water/sediment - -


ECOTOXICOLOGÍA

for propaquizafop

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 583 A5 Whole fish Umbral de importancia
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) 6.25 B5 Rata Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 827 mg kg-1 bw/día A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 0.19 A5 Cyprinus carpio Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.019 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 0.9 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.44 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 1.4 A5 Lemna gibba Moderado
Non-target plants > 400 A5 Lettuce, OSR, Carrot, Oat
Vegetative vigour, ER50
as g/ha
-
> 400 A5 Lettuce, OSR, Carrot, Oat
Seedling emergence, ER50
as g/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 2.1 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) > 2.1 Q2 Unknown species Bajo
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 200 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 20 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 1.95 E4 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 150 <
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 200 A5 Typhlodromus pyri -
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 2.0 mg kg-1 soil, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for propaquizafop

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 2.5 A5 Rat, 4 hr -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.015 A5 Mouse, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.04 A5 Mouse, SF=100 -
Estudios den la absorción cutánea (%) 10 A3 default -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Acceptable for bystanders considering the proposed uses
Low risk for consumers
Occupational Acceptable for proposed uses - PPE/PPC advised
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; A5 Calc MAC=45.0 μg l-1 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana No further information available

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 9
CLP classification 2013 Health: H304, H319
Environment: H411
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
Xn - Harmful: R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S24, S36, S37, S39, S60, S61
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU Usually 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for propaquizafop

Idioma Nombre
Inglés propaquizafop
Francés propaquizafop
Alemán Propaquizafop
Danés propaquizafop
Italiano propaquizafop
Español propaquizafop
Griego -
Esloveno propakvizafop
Polaco propakwizafop
Sueco propakizafop
Húngaro propaquizafop
Holandés -

Última actualización del registro: Friday 14 September 2018
Contacto: aeru@herts.ac.uk