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propiconazol (Ref: CGA 64250)
** propiconazole ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for propiconazole

Descripción: A systemic fungicide with a broad range of activity and a wide range of agricultural cropping applications

Ejemplos de plagas controladas: Diseases caused by Erysiphe graminis; Leptosphaeria nodorum; Pseudocerosporella herpotrichoides; Puccinia spp.; Pyrenophora teres; Rhynchosporium secalis; Septoria spp.

Ejemplos de aplicaciones: Mushrooms; Corn; Wild rice; Peanuts; Amonds; Sorghum; Oats; Pecan; Fruit including apricots, plums, prunes, peaches & nectarines

Eficacia y actividad: Wheat/Eyespot=Low; Wheat/Mildew=Low; Wheat/Septoria=Low; Wheat/Rust=Low; Barley/Rust=Low; Corn/Northern Leaf blight=Moderate; Corn/Rust=Moderate; Corn/Eyespot=High; Soybean/Blight=Low; Soybean/Anthracnose=High; Soybean/Brown spot=Moderate; Soybean/Rust=High

Availability status: Current

Introduction & key dates: 1980

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur Finland/UK
Date inclusion expires Expired
UE Candidatas a sustitución No aplicable
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A molecule with 2 chiral features leading to four stereoisomers.
Fórmula química C15H17Cl2N3O2
Canonical SMILES CCCC1COC(O1)(CN2C=NC=N2)C3=C(C=C(C=C3)Cl)Cl
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) STJLVHWMYQXCPB-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C15H17Cl2N3O2/c1-2-3-12-7-21-15(22-12,8-20-10-18-9-19-20)13-5-4-11(16)6-14(13)17/h4-6,9-10,12H,2-3,7-8H2,1H3
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Propiconazole Unstated isomer Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Triazole
Minimum active substance purity 930 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Systemic with curative and protective action, works via the demethylation of C-14 during ergosterol biosynthesis
CAS RN 60207-90-1
CEE número 262-104-4
Número CIPAC 408
EPA américaine chimiques de code 122101
PubChem CID 43234
Masa molecular (g mol-1) 342.22
PIN (Preferred Identification Name) -
Nombre IUPAC (2RS,4RS;2RS,4SR)-1-[2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-ylmethyl]-1H-1,2,4-triazole
Nombre CAS 1-((2-(2,4-dichlorophenyl)-4-propyl-1,3-dioxolan-2-yl)methyl)-1H-1,2,4-triazole
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 3
Examples of recorded resistance -
Estado físico Clear to pale yellow viscous liquid depending on the ratio of isomers
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Greencrop
  • Makhteshim-Agan
  • Syngenta
  • Ciba Geigy
Example products using this active
  • Bumper 250EC
  • Cherokee
  • Menara
  • Tilt
  • Mantis
  • Banner Maxx
Estado de UK LERAP None
Formulation and application details Often supplied as emulsifiable concentrates or wettable powder.


DESTINO AMBIENTAL

for propiconazole

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 150 A5 Moderado
Solubilidad - en solventes organicos en 20oC (mg l-1) 1585 A5 - n-Heptano -
Miscible A5 - Acetona -
Miscible A5 - Metanol -
Miscible A5 - Xileno -
Punto de fusión (oC) -23 A4 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 355 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 5.25 X 1003 Calculado -
Log P 3.72 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.09 A5 -
Disociación constante (pKa) at 25oC 1.09 A5 -
Nota: Base muy débil
Presión de vapor en 20oC (mPa) 0.056 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 9.20 X 10-05 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 1.89 Calculado Estado de transición
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 6.96 X 10-02 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 220 nm = 11666 A5 -
Surface tension (mN m-1) 55.0 A5 at 20 degC, 90% -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 71.8 A5 Persistente moderado
DT50 (laboratorio en 20oC) 71.8 A5 Persistente moderado
DT50 (campo) 35.2 A5 Persistente moderado
DT90 (laboratorio en 20oC) 344.8 A5 -
DT90 (campo) 478 A3 -
Endpoint de modelado DT50 - - -
Nota EU 2016 dossier lab studies DT50 range 26.6-115 days, DT90 range 107-1000 days, Soils=12; field studies DT50 range 15.3-96.3 days, DT90 range 108-525 days, Soils=6
Dissipation rate RL50 on plant matrix Valor 6.4 R4 -
Nota Published literature RL50 range 4.6-8.5 days, 2 field crops, various matrices, n=2
Dissipation rate RL50 on and in plant matrix Valor 7.4 R4 -
Nota Published literature RL50 range 1.0-16.9 days, 7 field crops, various matrices, n=8
Acuoso fotólisis DT50 (días) en pH 7 Valor Estable A5 -
Nota Not a significant degradation route
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 53.5 A5 Persistente moderado
Nota -
Aqua-Sedimento DT50 (días) 561 A5 Estable
Fase de agua sola DT50 (días) 6 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 33.7 A5 Móvil un poco
Koc 1086
Notas y rango EU 2003 dossier Koc range 382-1789, Soils=9
Freundlich Kf 15.0 A5 Móvil un poco
Kfoc 955
1/n 0.86
Notas y rango EU 2016 dossier: Kf range 1.20-59.0 mL/g, Kfoc range 387-1817 mL/g, 1/n range 0.81-0.89, Soils=9; Literature data: Kf range 27-1277 mL/g, Kfoc range 1440-3387 mL/g, 1/n range 0.75-0.88, Soils=3 (R4)
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
1,2,4-triazole (Ref: CGA 71019) This metabolite may cause environmental pollution, click here for further information Suelo   0.430   Major fraction, Relevant
(2S,4S-2R,4R)-2-(2,4-dichlorophenyl)-2-(1H-1,2,4-triazol-1-ylmethyl)-1,3-dioxolane-4-carboxylic acid (Ref: SYN 547889) This metabolite may cause environmental pollution, click here for further information Suelo   0.154   Major fraction, Relevant
1H-1,2,4-triazole-1-ethanol, alpha-(2,4-dichlorophenyl)- 2-(1,2,4) triazol-1-yl-ethanol (Ref: CGA 91305) Suelo   0.08   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
- NOA 436613 Soil 0.123 -
2-(2,4-dichlorophenyl)--ethyl-2-(1H-1,2,4-riazol-1-yl-methyl)-1,3-dioxolane-4-methanol
Nota: CAS Number:119725-85-8
CGA136735 Plant - -
3-chloro-4-(4-propyl-2-[1,2,4]triazol-1-ylmethyl-[1,3]dioxolan-2-yl)-phenol GB-XLIII-42-1 Plant - -
1,3-dioxolane-4-ethanol, 2-(2,4-dichlorophenyl)--methyl-2-(1H-1,2,4-triazol-1-ylmethyl)-
Nota: CAS Number 104390-57-0
CGA118244; CSAA107724 Plant; Rat; Livestock - -
3-[2-(2,4-dichlorophenyl)-2-[1,2,4]triazol-1-ylmethyl-[1,3]dioxolan-4-yl]-2-hydroxy-propionic acid SYN542636 Lactating goat - -
3-[2-(2,4-dichlorophenyl)-2-[1,2,4]triazol-1-yl-methyl-[1,3]dioxolan-4-yl]-propan-1-ol CGA118245 Wheat; Lactating goat - -


ECOTOXICOLOGÍA

for propiconazole

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 116 A5 Whole fish Umbral de importancia
CT50 (días) 8 -
Mamíferos - Agudos oral LD50 (mg kg-1) 550 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) 2.7 A4 Ratones Alto
(ppm dieta) 20 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2510 A5 Anas platyrhynchos Bajo
Birds - Short term dietary (LC50/LD50) > 5620 mg kg feed-1 A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 2.6 A5 Leiostomus xanthurus Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.068 A5 Oncorhynchus mykiss Moderado
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 10.2 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.31 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.37 F3 Americamysis bahia Moderado
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 8.0 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) 25.0 A5 Chironomus riparius Moderado
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 4.9 F3 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.093 A4 Navicula seminulum, 11 día Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.32 Q2 Unknown species Moderado
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 686 A5 Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 0.833 P4 Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 100 Mortalidad
Dose: 0.25 kg ha-1
A5 Aphidius rhopalosiphi
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 100 Beneficial capacity
Dose: 0.125 kg ha-1
A5 Typhlodromus pyri
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 6.7 mg kg-1 soil, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for propiconazole

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 550 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 4000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.8 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.04 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.3 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 9-14 A5 Rat, SF=100 -
Estudios den la absorción cutánea (%) 0.9-2.4 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational No unacceptable risks to operators or other workers identified
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana USEPA - possible human carcinogen, EU - unlikely to pose a hazard to humans
Possible liver toxicant
Endocrine issues - Weak estrogen and aromatase activity inhibition

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 9
CLP classification 2013 Health: H302, H317
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22, R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S36/37, S46, S60, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) II - Warning - Moderately toxic
Número de las NU Usually 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for propiconazole

Idioma Nombre
Inglés propiconazole
Francés propiconazol
Alemán Propiconazol
Danés propiconazol
Italiano propiconazolo
Español propiconazol
Griego -
Esloveno propiokonazol
Polaco propikonazol
Sueco propikonazol
Húngaro propikonazol
Holandés propiconazool

Última actualización del registro: Wednesday 03 April 2019
Contacto: aeru@herts.ac.uk