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pimetrozina (Ref: CGA 215944)
** pymetrozine ** pimetrozin ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for pymetrozine

Descripción: A novel azomethine insecticide suitable for use in integrated crop management to control aphids and other plant sucking pests

Ejemplos de plagas controladas: Pollen beetles; Aphids; Whiteflies

Ejemplos de aplicaciones: OSR; Potatoes; Brassicas; Spinach; Cucumbers; Ornamentals

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1992, first reported; 1993, first introduced

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur Germany/Belgium
Date inclusion expires Expired
UE Candidatas a sustitución No aplicable
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Isomeric
Fórmula química C10H11N5O
Canonical SMILES CC1=NNC(=O)N(C1)N=CC2=CN=CC=C2
Isomeric SMILES CC1=NNC(=O)N(C1)/N=C/C2=CN=CC=C2
International Chemical Identifier Key (InChIKey) QHMTXANCGGJZRX-WUXMJOGZSA-N
International Chemical Identifier (InChI) InChI=1S/C10H11N5O/c1-8-7-15(10(16)14-13-8)12-6-9-3-2-4-11-5-9/h2-6H,7H2,1H3,(H,14,16)/b12-6+
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Pymetrozine hydrate hydrate Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Pyridine
Minimum active substance purity 970 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Selective, neural inhibition of feeding behavior that eventually starves insect.
CAS RN 123312-89-0
CEE número -
Número CIPAC 593
EPA américaine chimiques de code 101103
PubChem CID 9576037
Masa molecular (g mol-1) 217.23
PIN (Preferred Identification Name) -
Nombre IUPAC (E)-4,5-dihydro-6-methyl-4-(3-pyridylmethyleneamino)-1,2,4-triazin-3(2H)-one
Nombre CAS 4,5-dihydro-6-methyl-4-((E)-(3-pyridinylmethylene)amino)-1,2,4-triazin-3(2H)-one
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 9B
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Bemisia tabaci
Estado físico White to light brown coloured crystals
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Syngenta
Example products using this active
  • Chess
  • Plenum
  • Endeavour
  • Fulfill
Estado de UK LERAP None
Formulation and application details Often supplied as wettable granules that are mixed with water and used as a spray.


DESTINO AMBIENTAL

for pymetrozine

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 270 A5 - @ 25 degC Moderado
Solubilidad - en solventes organicos en 20oC (mg l-1) 1000 A5 - n-Hexano -
34000 A5 - Tolueno -
940000 A5 - Acetona -
260000 A5 - Acetato de etilo -
Punto de fusión (oC) Decomposes before melting A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 217 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 6.46 X 10-01 Calculado -
Log P -0.19 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.37 A5 -
Disociación constante (pKa) at 25oC 4.06 A5 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 4.20 X 10-03 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 3.00 X 10-06 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.65 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 3.14 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 246nm=9500, 299.2nm = 20500 A5 -
Surface tension (mN m-1) 68.4 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 5 A5 No persistente
DT50 (laboratorio en 20oC) 4.6 A5 No persistente
DT50 (campo) 22.6 A5 No persistente
DT90 (laboratorio en 20oC) 32 A5 -
DT90 (campo) 320.7 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 2.05-29.2 days, DT90 range 8.3-96.9 days, field studies DT50 range 3.81-183 days, n=8, DT90 range 65.2 - >1000 days
Dissipation rate RL50 on plant matrix Valor 2.5 R3 -
Nota Lettuce head, n=1
Dissipation rate RL50 on and in plant matrix Valor 2.5 R4 -
Nota Published literature RL50 range 0.9-4.2 days,4 field crops, various matrices, n=4
Acuoso fotólisis DT50 (días) en pH 7 Valor 6.8 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota DT50: 8.6 days at pH 5, stable pH 7 and pH 9, all at 25 deg C
Aqua-Sedimento DT50 (días) 83 A5 Moderado rápido
Fase de agua sola DT50 (días) 6 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 19.3 A5 Móvil un poco
Kfoc 1049
1/n 0.880
Notas y rango EU dossier 2014 Kf range 3.10-47.7 mL/g, kfoc range 246-3080, 1/n range 0.790-0.952, Soils=7
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
5-hydroxy-6-methyl-4-(((E)-pyridin-3-ylmethylene)amino)-4,5-dihydro-1,2,4-triazin-3(2H)-one (Ref: CGA 359009) This metabolite may cause environmental pollution, click here for further information Suelo   0.537   Major fraction, Relevant
6-methyl-4-((6-oxo-1,6-dihydropyridine-3-ylmethylene)-amino)4,5-dihydro-2H-(1,2,4)triazin-3,5-dione (Ref: CGA 363430) This metabolite may cause environmental pollution, click here for further information Suelo   0.100   Major fraction, Relevant
5-hydroxy-6-methyl-4-(((E)-(6-oxo-1,6-dihydropyridin-3-yl)methylene)amino)-4,5-dihydro-1,2,4-triazin-3(2H)-one (Ref: CGA 363431) This metabolite may cause environmental pollution, click here for further information Suelo   0.238   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
pyridin-3-ylmethanol
(Ref: CGA 128632)
- Plant - -
nicotinic acid
(Ref: CGA 180777)
- Soil (a = Aerobic, b = Anaerobic) a=0.170; b=0.850 -
4-amino-6-methyl-4,5-dihydro-1,2,4-triazin-3(2H)-one
(Ref: CGA 215525)
- Water (Hydrolysis) 0.480 -
6-methyl-4,5-dihydro-1,2,4-triazin-3(2H)-one
(Ref: CGA 249257)
- a = Soil (Anaerobic); b = Water (Photolysis) a=0.130; b=0.210 -
6-oxo-1,6-dihydropyridine-3-carbaldehyde
(Ref: CGA 255548)
- a=Soil; b=Groundwater a=0.137 -
3,5-dioxo-2,3,4,5-tetrahydro-1,2,4-triazine-6-carboxylic acid
(Ref: CGA 266591)
- Plant - -
4-amino-6-methyl-1,2,4-triazine-3,5(2H,4H)-dione
(Ref: CGA 294849)
- Soil (Aerobic) 0.130 -
nicotinaldehyde
(Ref: CGA 300407)
- Water (Hydrolysis) 0.630 -
4,6-dimethyl-1,2,4-triazine-3,5(2H,4H)-dione
(Ref: CGA 371075)
- a=Soil; b=Groundwater a=0.008 -
6-methyl-1,2,4-triazine-3,5(2H,4H)-dione
(Ref: GS 23199)
- Soil (Anaerobic) 0.150 -
6-methylene-3-oxo-5,6-dihydro-1,2,4-triazin-4(3H)-aminium
(Ref: SYN 505866)
- a=Soil; Groundwater a=0.007 -
6-methyl-4-{[(E)-(6-oxo-1,6-dihydropyridin-3-yl)methylene]amino}-1,2,4-triazine-3,5(2H,4H)-dione
(Ref: SYN 510306)
- a=Soil; b=Groundwater a=0.006 -


ECOTOXICOLOGÍA

for pymetrozine

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) Low risk A5 Based on LogP < 3 Bajo potencial
CT50 (días) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 5820 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) 3.7 L2 Rata, 2 año Alto
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Anas platyrhynchos Bajo
Birds - Short term dietary (LC50/LD50) > 5200 mg kg feed-1 A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) > 100 A5 Oncorhynchus mykiss Bajo
Pez - Crónico 21 días NOEC (mg l-1) > 11.7 A5 Oncorhynchus mykiss Bajo
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 87 A5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.025 A5 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 61.7 E4 Americamysis bahia EC50 Moderado
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.313 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 106 E4 Lemna gibba Bajo
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 21.6 A4 Raphidocelis subcapitata, 72 hora Bajo
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 200 A5 Apis mellifera Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 117 A5 Apis mellifera Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 250 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 1.39 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 95.2 Beneficial capacity
Dose: 0.6 kg ha-1
A5 Aphidius coleman, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 17.4 Beneficial capacity
Dose: 0.6 kg ha-1
A5 Typhlodromus pyri, lifecycle
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 6.66 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for pymetrozine

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 5820 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 1.8 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.03 A5 Dog, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.1 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.03 A5 Rat, 90 day, SF=100 -
Estudios den la absorción cutánea (%) 0.05-5% A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational No unacceptable risks to operators or other workers identified
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana May affect most major organs at high doses
Highly toxic - harmful if swallowed
USEPA - probable human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
Non-flammable but is combustible
CLP classification 2013 Health: H351, H361f, H361d
Environment: H412
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
Reproduction risk category 3: R62, R63
N - Dangerous for the environment: R52, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S36/37, S61
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for pymetrozine

Idioma Nombre
Inglés pymetrozine
Francés pymetrozine
Alemán Pymetrozin
Danés pymetrozin
Italiano pymetrozine
Español pimetrozina
Griego pymetrozine
Esloveno pimetrozin
Polaco pymetrozyna
Sueco pymetrozin
Húngaro pimetrozin
Holandés pymetrozine

Última actualización del registro: Tuesday 14 May 2019
Contacto: aeru@herts.ac.uk