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piraclostrobina (Ref: BAS 500F)
** pyraclostrobin ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for pyraclostrobin

Descripción: A fungicide used to control major plant pathogens in cereals and other crops

Ejemplos de plagas controladas: Septoria tritici; Puccinia spp.; Pyrenophora teres

Ejemplos de aplicaciones: Cereals including wheat, barley, oats; forage & grain maize, triticale; Sugarbeet; Potatoes; Vegetables including brassicas, carrot; beans, vining peas; Fruit including strawberry, blackcurrants

Eficacia y actividad: Wheat/Eyespot=Low; Wheat/Mildew=Low; Wheat/Septoria=Low; Wheat/Rust=High; Corn/Leaf blight=High; Corn/Rust=High; Corn/Eyespot=High; Soybean/Blight=High; Soybean/Anthracnose=High; Soybean/Brown spot=Moderate; Soybean/Leaf blight=Moderate; Soybean/Rust=High

Availability status: Current

Introduction & key dates: 2000, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Germany/Hungary
Date inclusion expires 31/01/2020
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism -
Fórmula química C19H18CIN3O4
Canonical SMILES COC(=O)N(C1=CC=CC=C1COC2=NN(C=C2)C3=CC=C(C=C3)Cl)OC
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) HZRSNVGNWUDEFX-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C19H18ClN3O4/c1-25-19(24)23(26-2)17-6-4-3-5-14(17)13-27-18-11-12-22(21-18)16-9-7-15(20)8-10-16/h3-12H,13H2,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Strobilurin
Minimum active substance purity 975 g/kg
Known relevant impurities EU dossier - <0.001 g/kg dimethyl sulphate
Sustancias de origen Sintéticas
Modo de acción Protective and curative action. Respiration inhibitor (QoL fungicide).
CAS RN 175013-18-0
CEE número Not assigned
Número CIPAC 657
EPA américaine chimiques de code 099100
PubChem CID 6422843
Masa molecular (g mol-1) 387.82
PIN (Preferred Identification Name) -
Nombre IUPAC methyl {2-[1-(4-chlorophenyl)pyrazol-3-yloxymethyl]phenyl}(methoxy)carbamate
Nombre CAS methyl (2-(((1-(4-chlorophenyl)-1H-pyrazol-3-yl)oxy)methyl)phenyl)methoxycarbamate
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 11
Examples of recorded resistance -
Estado físico White to light beige crystalline solid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • BASF
  • Vitax
  • Rigby Taylor
Example products using this active
  • Comet
  • Flyer
  • Gemstone
  • Platoon 250
  • Vivid
  • Tucana
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as an emulsifiable concentrate that is mixed with water and used as a spray.


DESTINO AMBIENTAL

for pyraclostrobin

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 1.9 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 3700 A5 - n-Heptano -
24200 A5 - Octanol -
500000 A5 - Acetona -
100800 A5 - Metanol -
Punto de fusión (oC) 63.7 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 200 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 9.77 X 1003 Calculado -
Log P 3.99 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.37 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 2.60 X 10-05 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 5.31 X 10-06 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.05 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.48 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 205nm = 2500, 275nm = 2400 A5 -
Surface tension (mN m-1) 71.5 A5 20 degC, 2.0% w/ww -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 41.9 A5 Persistente moderado
DT50 (laboratorio en 20oC) 41.9 A5 Persistente moderado
DT50 (campo) 33.3 A5 Persistente moderado
DT90 (laboratorio en 20oC) 914 A5 -
DT90 (campo) 234 A5 -
Endpoint de modelado DT50 - - -
Nota EU 2018 dossier lab studies DT50 (normalised) range 4.2-95.4 days, DT90 (actual) range 115- >1000 days, Soils=7; Field studies Dt50 (normalised) range 5.2-181 days, DT90 range 80.3- >1000 days, Soils=10
Dissipation rate RL50 on plant matrix Valor 3.7 R4 -
Nota Published literature RL50 range 3.1-4.3 days, 3 field & undercover grown crops, various matrices, n=3
Dissipation rate RL50 on and in plant matrix Valor 4.7 R4 -
Nota Published literature RL50 range 2.7-10.1 days, 5 field & undercover grown crops, various matrices, n=6
Acuoso fotólisis DT50 (días) en pH 7 Valor 0.06 A5 Rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable pH 5 to pH 9 at 25 degC
Aqua-Sedimento DT50 (días) 28 A5 Rápido
Fase de agua sola DT50 (días) 2 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 160 A4 No Móvil
Koc 9304
Notas y rango EU 2018 dossier Kd range 30-368 mL/g, Koc range 6000-16000 mL/g, Soils=6
Freundlich Kf 145 A5 No Móvil
Kfoc 9315
1/n 0.830
Notas y rango EU 2018 dossier Kf range 47-354 mL/g; Kfoc range 4240-12000 mL/g, 1/n range 0.773-0.942, Soils=6
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
Ref: BAS 500-6 This metabolite may cause environmental pollution, click here for further information Suelo   0.309   Major fraction, Relevant
methyl N-(2((1-(4-chlorophenyl)-1H-pyrazol-3-yl)oxymethyl) phenyl)carbamate (Ref: BAS 500-7) This metabolite may cause environmental pollution, click here for further information Suelo   0.190   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
(Ref: BF500-11) - Water; Sediment - -
(Ref: BF500-13) - Water; Sediment - -
(Ref: BF500-14) - Water; Sediment - -
(Ref: BF500-16) - Animal - -
methyl-N-[[[1-(4-chlorophenyl)-pyrazol-3-yl]oxy]-o-tolyl]carbamate
(Ref: BF500-3)
500M07 a = Soil (Anerobic); b = Water (Photolysis); c= rat; d = Animal; e = Plant a=0.958; b=0.180 -
1 -(4-chloropheny1)-1H-pyrazol-3-ol
(Ref: BF500-5)
500M04 Rat; Plant; Animal - -
(Ref: BF500-6) - a = Water (Photolysis); b = Animal a=0.178 -
1-(4-chloro-2-hydroxyphenyl)-1H-pyrazol-3-ol
(Ref: BF500-8)
- Animal - -


ECOTOXICOLOGÍA

for pyraclostrobin

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 706 A5 Whole fish Umbral de importancia
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 5000 mg kg feed-1 A4 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 0.006 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.005 A5 Oncorhynchus mykiss Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.016 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.004 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.04 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 1.72 F4 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.843 A4 Pseudokirchneriella subcapitata, 72 hora Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Apis mellifera Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 110 A5 Apis mellifera Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 567 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 0.443 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 30
80
Mortalidad
Reproducción
Dose: 0.32 kg ha-1
A5 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 47.3
99
Mortalidad
Reproducción
Dose: 0.32 kg ha-1
A5 Typhlodromus pyri, protonymph
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 2.5 kg ha-1
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for pyraclostrobin

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 0.58 A5 Rat, 4hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.03 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.03 A5 Rabbit, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) 0.09 A5 Rat, SF=100 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.015 A3 Rabbit, SF=100 -
Estudios den la absorción cutánea (%) 1.0-7.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational No unacceptable risks to operators or other workers identified
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

Cuestiones generales de la salud humana No further information available

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is variable depending upon product, often either 6.1 or 9
CLP classification 2013 Health: H335, H361d, H315, H331, H302
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xi - Irritant: R38
N - Dangerous for the environment: R51, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM NL - No inscripto en la lista
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for pyraclostrobin

Idioma Nombre
Inglés pyraclostrobin
Francés pyraclostrobine
Alemán Pyraclostrobin
Danés pyraclostrobin
Italiano pyraclostrobin
Español piraclostrobina
Griego -
Esloveno piraklostrobin
Polaco pyraklostrobina
Sueco pyraklostrobin
Húngaro -
Holandés pyraclostrobin

Última actualización del registro: Tuesday 07 May 2019
Contacto: aeru@herts.ac.uk