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piriproxifen (Ref: S 9318)
** pyriproxyfen ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio
Otros datos se pueden encontrar en el VSDB

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for pyriproxyfen

Descripción: An insecticide used to control public health insect pests. Also used for flea control on domestic pets.

Ejemplos de plagas controladas: Flies; Mosquitoes; Midges; Ants; Cockroaches; Whiteflies

Ejemplos de aplicaciones: Waste dumps; Residences and public places; Some ornamentals

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1995, first registered for agricultural use Japan

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Netherlands/Spain
Date inclusion expires 31/12/2019
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A molecules with one chiral centre. The technical material is an isomeric mixture.
Fórmula química C20H19NO3
Canonical SMILES CC(COC1=CC=C(C=C1)OC2=CC=CC=C2)OC3=CC=CC=N3
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) NHDHVHZZCFYRSB-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C20H19NO3/c1-16(23-20-9-5-6-14-21-20)15-22-17-10-12-19(13-11-17)24-18-7-3-2-4-8-18/h2-14,16H,15H2,1H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Veterinary substance
Grupo químico Unclassified
Minimum active substance purity 970 g/kg racemic mixture
Known relevant impurities EU dossier - toluene 5g/kg
Sustancias de origen Sintéticas
Modo de acción A juvenile hormone mimic. Inhibits insect maturation process
CAS RN 95737-68-1
CEE número 429-800-1
Número CIPAC 715
EPA américaine chimiques de code 129032
PubChem CID 91753
Masa molecular (g mol-1) 321.37
PIN (Preferred Identification Name) -
Nombre IUPAC 4-phenoxyphenyl (RS)-2-(2-pyridyloxy)propyl ether
Nombre CAS 2-(1-methyl-2-(4-phenoxyphenoxy)ethoxy)pyridine
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 7C
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Bemisia tabaci
Estado físico White granule solid
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Sumitomo
  • Syngenta
  • BePharm Ltd.
Example products using this active
  • Admiral
  • Juvinal
  • Atominal
  • Pyriproxyfen 10EC
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually supplied as an emulsifiable concentrate that is mixed with water and applied as a spray for crops. Also available as bait and wettable powders.


DESTINO AMBIENTAL

for pyriproxyfen

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.37 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 27000 A5 - n-Heptano -
27000 A5 - Metanol -
1000000 A5 - Acetona -
1000000 A5 - Acetato de etilo -
Punto de fusión (oC) 49 A5 -
Punto de ebullición (oC) 318 A5 -
El punto de degradación (oC) 318 A3 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.34 X 1005 Calculado -
Log P 5.37 B4 Alto
Masa densidad (g ml-1)/Peso específico 1.26 A5 -
Disociación constante (pKa) at 25oC 6.87 A4 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 1.33 X 10-02 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 1.16 X 10-02 A2 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -0.27 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution 271nm = 6649; [Acidic solution 278nm = 10354; [Basic solution 271nm = 6749 A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 10 A5 No persistente
DT50 (laboratorio en 20oC) 6.7 A5 No persistente
DT50 (campo) 4.2 A5 No persistente
DT90 (laboratorio en 20oC) 24.5 A5 -
DT90 (campo) 14.7 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 2.8-20.4 days, DT90 range 9.2-54 days; Field studies DT50 range 3.5-5.9 days, DT90 range 12-20 days
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor 65.5 R4 -
Nota Published literature RL50 range 13-212 days, fruit from 4 field & undercover grown crops, n=4; RL50 peppers in cold storage=718 days
Acuoso fotólisis DT50 (días) en pH 7 Valor 11.5 A5 Moderado rápido
Nota Natural light, 43N
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable pH 4 to pH 9, 50 degC
Aqua-Sedimento DT50 (días) 6.5 A5 Rápido
Fase de agua sola DT50 (días) 1.6 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 227 A5 No Móvil
Kfoc 21175
1/n 1.15
Notas y rango EU dossier Kf range 126-324 mL/g, Kfoc range 11000-34200 mL/g, 1/n range 1.1-1.2, Soils=4
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
4-(4-hydroxyphenoxy)phenyl (RS)-2-(2-pyridyloxy)propyl ether Suelo   0.063   Minor fraction, Relevant
(RS)-2-(2-pyridyloxy)propionic acid Suelo   0.086   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
4-hydroxyphenyl (RS)-2-(2-pyridyloxy)propyl ether
Nota: Koc = 10mL/g; DT50 ~ 1000 days (industry data)
DPH-pyr a=Soil; b=Water a=0.02 -
(RS)-2-hydroxypropyl 4-phenoxyphenyl ether POPA Plant - -
2-hydroxypyridin 2-OH-PY Plant - -
(RS)-2-(2-pyridyloxy)propyl alcohol PYPA Plant - -


ECOTOXICOLOGÍA

for pyriproxyfen

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 1379 A5 Umbral de importancia
CT50 (días) 0.9 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 B5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) > 24 B3 Rata, 6 mes Alto
(ppm dieta) > 400 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 1906 A5 Colinus virginianus Moderado
Birds - Short term dietary (LC50/LD50) > 863 mg kg-1 bw/día A5 Colinus virginianus -
Pez - agudo 96 hora LC50 (mg l-1) > 0.27 A5 Lepomis macrochirus Moderado
Pez - Crónico 21 días NOEC (mg l-1) 0.0043 A5 Oncorhynchis mykiss Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.4 B5 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.000015 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.047 F3 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.01 A5 Chironomus riparius, emergence Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 0.18 A5 Lemna gibba Moderado
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.15 A5 Selenastrum capricornutum Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 74 A4 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) > 100 A4 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 500 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 213 48 hora (Other data: ER50 = 81 g ha-1)
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 20 7 día (Other data: ER50 = 8.1 g ha-1)
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms - - -
Mesocosm study data NOEAEC mg l-1 0.005 A5 Aquatic community -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for pyriproxyfen

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 B5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 1.3 A5 Rat, 4 hr (whole body) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.1 A4 Dog, SF=100, Proposed -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.04 A5 Dog, SF=100 -
Estudios den la absorción cutánea (%) 2.5-13 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified with proposed uses
Occupational No unacceptable risks to operators or other workers identified for poposed uses
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards Non-statutory WHO drinking water guideline 0.3 mg/L UK EA QS database, 2018 -
Drinking Water MAC (μg l-1) 0.1 EU Dir 89/778/EC limit; A5 Calc MAC=300 μg l-1 -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Possible liver toxicant
Possible blood toxicant
Endocrine issues - Estrogenic effect

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 9
CLP classification 2013 None allocated at this time
CEE clasificación de riesgos Click here to view information omn the EU risk phrases N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S60, S61
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU Usually 3077
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for pyriproxyfen

Idioma Nombre
Inglés pyriproxyfen
Francés pyriproxyfen
Alemán Pyriproxyfen
Danés pyriproxyfen
Italiano piriproxifen
Español piriproxifen
Griego -
Esloveno piriproksifen
Polaco pyriproksyfen
Sueco pyriproxyfen
Húngaro piriproxifen
Holandés pyriproxyfen

Última actualización del registro: Wednesday 03 April 2019
Contacto: aeru@herts.ac.uk