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tiacloprid (Ref: YRC 2894)
** thiacloprid ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for thiacloprid

Descripción: A chloronicotinyl insecticide for use on apples and other crops to control sucking and chewing insects

Ejemplos de plagas controladas: Aphids; Pollen beetles; Blossom midge; codling moth

Ejemplos de aplicaciones: Apples; Pears; Some citrus crops; Brussel sprouts; Cabbage; Cauliflower; Carrot; Parsnip; Peas; Potato; Oilseed rape

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1999, first registered Brazil; 2003 USA

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK/Germany
Date inclusion expires 30/04/2020
UE Candidatas a sustitución Yes - endocrine disrupting properties
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Isomeric - exists in the E- and Z- forms. Technical products are predominately comprised of the Z- form.
Fórmula química C10H9CIN4S
Canonical SMILES C1CSC(=NC#N)N1CC2=CN=C(C=C2)Cl
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) HOKKPVIRMVDYPB-UVTDQMKNSA-N
International Chemical Identifier (InChI) InChI=1S/C10H9ClN4S/c11-9-2-1-8(5-13-9)6-15-3-4-16-10(15)14-7-12/h1-2,5H,3-4,6H2/b14-10-
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Thiacloprid Unstated isomer Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Molluscicide
Grupo químico Neonicotinoid
Minimum active substance purity 975 g/kg
Known relevant impurities EU and FAO dossiers - None declared
Sustancias de origen Sintéticas
Modo de acción Contact and stomach action with some systemic properties. Acetylcholine receptor (nAChR) agonist.
CAS RN 111988-49-9
CEE número -
Número CIPAC 631
EPA américaine chimiques de code 014019
PubChem CID 115224
Masa molecular (g mol-1) 252.72
PIN (Preferred Identification Name) ((2Z)-3-((6-chloropyridin-3-yl)methyl)-1,3-thiazolidin-2-ylidene}cyanamide
Nombre IUPAC (Z)-3-(6-chloro-3-pyridylmethyl)-1,3-thiazolidin-2-ylidenecyanamide
Nombre CAS (Z)-(3-((6-chloro-3-pyridinyl)methyl)-2-thiazolidinylidene)cyanamide
Otra información de estado NOTE ban or usage restriction may be in place for use on flowering crops in some Member States
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 4A
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Leptinotarsa decemlineata
Estado físico White to beige crystalline powder
Related substances & organisms -

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bayer CropScience
  • Scotts
  • Standon
Example products using this active
  • Biscaya
  • Calypso
  • Exemptor
  • Topstar
Estado de UK LERAP None (may vary with mixtures)
Formulation and application details Formulations include oil dispersions, soluble concentrates and granules.


DESTINO AMBIENTAL

for thiacloprid

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 184 A5 Moderado
Solubilidad - en solventes organicos en 20oC (mg l-1) 100 A5 - n-Hexano -
300 A5 - Xileno -
64000 A5 - Acetona -
9400 A5 - Acetato de etilo -
Punto de fusión (oC) 136 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 270 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 1.82 X 1001 Calculado -
Log P 1.26 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.46 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 3.00 X 10-07 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 5.00 X 10-10 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 0.14 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 3.79 X 10-04 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 No absorption above 290nm A3 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 15.5 A5 No persistente
DT50 (laboratorio en 20oC) 1.3 A5 No persistente
DT50 (campo) 18 A5 No persistente
DT90 (laboratorio en 20oC) 8.9 A5 -
DT90 (campo) 45 A5 -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 0.7-5 days, DT90 range 2.3-15.5 days, field studies DT50 range 9-27 days, DT90 range 31-91 days; Other sources: 15 days
Dissipation rate RL50 on plant matrix Valor 8.8 R4 -
Nota Published literature RL50 range 1.1-11.3 days, 3 field grown crops, various matrices, n=4
Dissipation rate RL50 on and in plant matrix Valor 3.8 R4 -
Nota Published literature RL50 range 0.7-9.0 days, 9 field & undercover grown crops, various matrices, n=13
Acuoso fotólisis DT50 (días) en pH 7 Valor Estable A5 -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor Estable A5 -
Nota Stable pH 5 to pH 9
Aqua-Sedimento DT50 (días) 28 A5 Rápido
Fase de agua sola DT50 (días) 8.5 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 4.41 A5 Móvil un poco
Kfoc 615
1/n 0.875
Notas y rango EU dossier Kf range 1.14-5.76 mL/g, Kfoc range 393-870 mL/g, 1/n range 0.833-0.914, Soils=6
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
thiacloprid-amide This metabolite may cause environmental pollution, click here for further information Suelo   0.740   Major fraction, Relevant
thiacloprid sulfonic acid This metabolite may cause environmental pollution, click here for further information Suelo   0.200   Major fraction, Relevant


ECOTOXICOLOGÍA

for thiacloprid

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) Low risk A5 Based on LogP < 3 Bajo potencial
CT50 (días) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 444 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) > 7.3 A5 Rata Alto
(ppm dieta) > 100 -
Pájaros/aves - Agudos LD50 (mg kg-1) 49 A5 Coturnix japonica Alto
Birds - Short term dietary (LC50/LD50) > 2250 mg kg feed-1 A5 Coturnix japonica -
Pez - agudo 96 hora LC50 (mg l-1) 24.5 F4 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 85.1 C4 Daphnia magna Moderado
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.58 P3 Daphnia magna Moderado
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 95.4 C4 Lemna gibba Bajo
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 60.6 C4 Raphidocelis subcapitata Bajo
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) 38.82 A5 Moderado
Oral aguda 48 hora LD50 (μg abeja-1) 17.32 A5 Moderado
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) 105 A5 Eisenia foetida Moderado
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 62.5 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 6.8 as LC50
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 30
30
Mortalidad
Beneficial capacity
Dose: 0.4 kg ha-1
A5 Typhlodromus pyri
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 2.57 mg kg-1 soil, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for thiacloprid

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 444 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 0.481 F4 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.03 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.02 A3 Rabbit, SF=100 -
Estudios den la absorción cutánea (%) 1.0-10.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Limites de exposiciones - - -
Exposure Routes Public Minimal risk from dietary exposure
Risk assessment indicates ARfD would not normally be execeeded
Occupational -
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Possible liver and thyroid toxicant
USEPA - probable human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H301, H332, H351, H361f
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R20/22
N - Dangerous for the environment: R52/53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S60
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) No consensus across products or no products available - -
Número de las NU Variable with product, usually 2902 or 3077
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for thiacloprid

Idioma Nombre
Inglés thiacloprid
Francés thiacloprid
Alemán Thiacloprid
Danés thiacloprid
Italiano tiacloprid
Español tiacloprid
Griego -
Esloveno tiakloprid
Polaco tiachlopryd
Sueco tiakloprid
Húngaro tiakloprid
Holandés thiacloprid

Última actualización del registro: Wednesday 03 April 2019
Contacto: aeru@herts.ac.uk