tribenuron-metil (Ref: DPX L5300) |
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Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio
INFORMACIÓN GENERAL
for tribenuron-methyl
Descripción: A foliar acting, post-emergence herbicide used to control broad-leaved weeds in cereals and other crops
Ejemplos de plagas controladas: Charlock; Chickweed; Red deadnettle; Fat hen; Forget-me-not; Hemp nettle; Mayweed; Common poppy; Redshank; Shepherd's purse
Ejemplos de aplicaciones: Cereals including wheat, barley, triticale, oats; Olives; Sunflower; Grass seed crops; Cotton; Pre-harvest burndown
Eficacia y actividad: Efficacy established via field trials and long-term use in the EU.
Availability status: Current
Introduction & key dates: 1987, first approvals
CEE Regulación 1107/2009 ( 91/414):
Estado | Approved |
Dossier rapporteur/co-rapporteur | Sweden/Latvia |
Date inclusion expires | 30/01/2034 |
UE Candidatas a sustitución | No |
Incluido en la base de datos de la UE | Sí |
Approved for use () or known to be used (
) in the following European countries:
AT |
BE |
BG |
CY |
CZ |
DE |
DK |
EE |
EL |
ES |
FI |
FR |
HR |
HU |
IE |
IT |
LT |
LU |
LV |
MT |
NL |
PL |
PT |
RO |
SE |
SI |
SK |
UK |
Also used in: Australia
Isomerism | - |
Fórmula química | C15H17N5O6S |
Canonical SMILES | CC1=NC(=NC(=N1)OC)N(C)C(=O)NS(=O)(=O)C2=CC=CC=C2C(=O)OC |
Isomeric SMILES | No data |
International Chemical Identifier Key (InChIKey) | VLCQZHSMCYCDJL-UHFFFAOYSA-N |
International Chemical Identifier (InChI) | InChI=1S/C15H17N5O6S/c1-9-16-13(18-14(17-9)26-4)20(2)15(22)19-27(23,24)11-8-6-5-7-10(11)12(21)25-3/h5-8H,1-4H3,(H,19,22) |
¿Diagrama de estructura 2D / imagen disponible? | Sí |
Tipo de pesticida | Herbicida | |
Grupo químico | Sulfonylurea | |
Minimum active substance purity | 950 g/kg | |
Known relevant impurities | EU dossier - None declared | |
Sustancias de origen | Sintéticas | |
Modo de acción | Selective, absorbed through foliage. Inhibits plant amino acid synthesis - acetohydroxyacid synthase AHAS | |
CAS RN | 101200-48-0 | |
CEE número | 401-190-1 | |
Número CIPAC | 546 | |
EPA américaine chimiques de code | 128887 | |
PubChem CID | 153909 | |
Masa molecular (g mol-1) | 395.4 | |
PIN (Preferred Identification Name) | 2-{[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylcarbamoyl]sulfamoyl}benzoic acid | |
Nombre IUPAC | methyl 2-[4-methoxy-6-methyl-1,3,5-triazin-2-yl(methyl)carbamoylsulfamoyl]benzoate | |
Nombre CAS | methyl 2-[[[[(4-methoxy-6-methyl-1,3,5-triazin-2-yl)methylamino]carbonyl]amino]sulfonyl]benzoate | |
Otra información de estado | - | |
Relevant Environmental Water Quality Standards | - | |
Herbicide Resistance Classification (HRAC) | B | |
Herbicide Resistance Classification (WSSA) | 2 | |
Insecticide Resistance Classification (IRAC) | No aplicable | |
Fungicide Resistance Classification (FRAC) | No aplicable | |
Examples of recorded resistance | Many recorded cases Capsella bursa-pastoris Chrysanthemum coronarium Descurainia sophia Galium spurium |
|
Estado físico | White to off-white solid | |
Related substances & organisms |
Formulaciones:
DESTINO AMBIENTAL
for tribenuron-methyl
De absorción del suelo y la movilidad:
Key metabolites:
Metabolito | Medio de formación | Maximó Calculado de Fracción Ocurrencia | 1107/2009 Importancia ![]() |
|
N-methyl triazine amine (Ref: IN-L5296) ![]() |
Suelo | 0.857 | Major fraction, Relevant | |
2-amino-4-methoxy-6-methyl-1,3,5-triazine (Ref: IN-A4098) ![]() |
Suelo | 0.126 | Major fraction, Relevant | |
1,2-benzisothiazol-3(2H)-one,1,1-dioxide (Ref: IN-00581) ![]() |
Suelo | 0.339 | Major fraction, Relevant | |
tribenuron (Ref: IN-R9803) | Suelo | 0.076 | Minor fraction, Relevant | |
1-(4-methoxy-6-methyl-1,3,5-triazin-2-yl)-1-methylurea (Ref: ) ![]() |
Suelo | 0.162 | Major fraction, Relevant |
Other known metabolites:
Metabolite name and reference | Aliases | Medio de formación / Rate | Maximó Calculado de Fracción Ocurrencia | Metabolising enzymes |
metsulfuron-methyl (Ref: DPX T6376) Nota: Major fraction, Relevant |
- | Crops; Livestock; Poultry | - | - |
(((aminocarbonyl)amino)sulfonyl)benzoate (Ref: IN-B5685) |
sulfonamide urea | Crops; Livestock; Poultry | - | - |
methyl 2-(((((4-methoxy-6-methyl-1,2,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)4-(beta-D-glucopyranpsyl)benzoate (Ref: IN-B9700) |
- | Crops | - | - |
2-(aminosulfonyl)benzoic acid (Ref: IN-D5119) |
- | Crops; Livestock; Poultry | - | - |
methyl-2-(amonosulfonyl)benzoate (Ref: IN-D5803) |
- | Crops; Livestock; Poultry | - | - |
methyl 2-(((((4-methoxy-6-methyl-1,2,5-triazin-2-yl)amino)carbonyl)amino)sulfonyl)4-hydroxybenzoate (Ref: IN-G7460) |
- | Crops, Livestock | - | - |
methyl-2(((((4-hydroxy-6-methyl-1,3,5-triazin-2-yl)methylamino)carbonyl)amino)solfonyl)benzoate (Ref: IN-GK521) |
- | Crops; Livestock; Poultry | - | - |
methyl 2-(((((4-methoxy-6-methyl-1,2,5-triazin-2-yl)methylamino)carbonyl)amino)sulfonyl)benzoate (Ref: IN-GN815) |
- | Crops; Poultry | - | - |
methyl 2-(((((4-(hyroxymethyl)-6-methoxy-13,5-triazin-2-yl)methylamino)carbonyl)amino)sulfonyl)benzoate (Ref: IN-QKK48) |
- | Crops; Livestock; Poultry | - | - |
ECOTOXICOLOGÍA
for tribenuron-methyl
LA SALUD HUMANA Y PROTECCIÓN
for tribenuron-methyl
General:
Propiedad ![]() |
Valor | Fuente/Cuenta de Cualidad/Otra Información ![]() |
Interpretación ![]() |
|
Threshold of Toxicological Concern (Cramer Class) ![]() |
High (class III) | - | - | |
Mamíferos - Agudos oral LD50 (mg kg-1) | > 5000 | A5 Rata | Bajo | |
Mammals - Dermal LD50 (mg kg-1 body weight) | > 5000 | A5 Rat | - | |
Mammals - Inhalation LC50 (mg l-1) | > 6.0 | A5 Rat, 4 hr (nose only) | - | |
Other Mammal toxicity endpoints | - | - | ||
Consumo cada día aceptable (mg kg-1p.c. días-1) | 0.01 | A5 Rat, 2 year, SF=100 | - | |
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) | 0.2 | A5 Rat, SF=100 | - | |
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) | 0.13 | A5 Rat, SF=167 | - | |
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) | 0.05 | A5 Rat, SF=167 | - | |
Estudios den la absorción cutánea (%) | 25-75 | A5 concentration dependent | - | |
Directivo 76/464 Sustancias Peligrosas | - | - | - | |
Exposure Routes | Public | No unacceptable risks to bystanders identified | ||
Occupational | No unacceptable risks to operators or other workers identified | |||
European MRLs | Click here for the EU MRL pesticide database | |||
Drinking Water Standards | - | - | - | |
Drinking Water MAC (μg l-1) | - | - | - |
Health issues:
Carcinogen | Genotóxico | Endocrine disrupter | Reproduction / development effects | Cholinesterase inhibitor | Neurotoxicant | |||
A3; B3; C3; D0; E3 | ||||||||
Respiratory tract irritant | Skin irritant | Skin sensitiser | Eye irritant | Phototoxicant | ||||
|
||||||||
Cuestiones generales de la salud humana | USEPA - possible human carcinogen Possible liver & spleen toxicant Endocrine issues - Weak estrogenic effect |
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Clave: Genotoxicidad A: Aberración cromosómica (base de datos EFSA) B: Daño/reparación del ADN (base de datos EFSA) C: Mutación genética (base de datos EFSA) D: Mutación del genoma (base de datos EFSA) E: Tipo de genotoxicidad no especificada (fuente de datos diversos) 0: Sin datos 1: Positivo 2: Resultados mixtos/ambiguos 3: Negativo |
Clave: Otro![]() ![]() ![]() - : Datos no encontrados |
Handling issues:
TRADUCCIONES
for tribenuron-methyl
Idioma | Nombre |
Inglés | tribenuron-methyl |
Francés | tribenuron-methyle |
Alemán | Tribenuron |
Danés | tribenuron-methyl |
Italiano | tribenuron-metile |
Español | tribenuron-metil |
Griego | - |
Esloveno | tribenuron-metil |
Polaco | tribenuron metylu |
Sueco | tribenuronmetyl |
Húngaro | tribenuron-metil |
Holandés | - |
Última actualización del registro: Friday 08 November 2019
Contacto: aeru@herts.ac.uk