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triclorfon (Ref: OMS 800)
** trichlorfon ** chlorophos ** metriphonate ** trichlorphon ** dipterex ** chloroxyphos ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio
Otros datos se pueden encontrar en el VSDB

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for trichlorfon

Descripción: A insecticide and acaricide used to control a variety of insects on an extensive range of crops

Ejemplos de plagas controladas: Cockroaches; Silverfish; Fleas; Flies; Ticks; Grapevine moth; Banana spotting bug; Passion vine bug; Fruit flies; Cabbage white butterfly; Army worms; Leaf miners

Ejemplos de aplicaciones: Fruit including apples, pears, plums, cherries, avodado, grapes, passionfruit, blueberries; Peppers; Chillies; Tomatoes; Brassicas; Tomatoes; Linseed; Lucerne; Cereals; Soybean; Rice

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1957

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur Spain
Date inclusion expires Expired
UE Candidatas a sustitución No aplicable
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism A chiral molecule. The technical material is an isomeric mixture of two isomers.
Fórmula química C4H8Cl3O4P
Canonical SMILES COP(=O)(C(C(Cl)(Cl)Cl)O)OC
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) NFACJZMKEDPNKN-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C4H8Cl3O4P/c1-10-12(9,11-2)3(8)4(5,6)7/h3,8H,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Trichlorfon Unstated isomer Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Veterinary substance
Grupo químico Organophosphate
Minimum active substance purity 980 g/kg
Known relevant impurities EU dossier - diclorvos 0.02g/kg
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action. Acetylcholinesterase (AChE) inhibitor.
CAS RN 52-68-6
CEE número 200-149-3
Número CIPAC 68
EPA américaine chimiques de code 057901
PubChem CID 5853
Masa molecular (g mol-1) 257.4
PIN (Preferred Identification Name) rac-dimethyl [(1R)-2,2,2-trichloro-1-hydroxyethyl]phosphonate
Nombre IUPAC dimethyl (RS)-2,2,2-trichloro-1-hydroxyethylphosphonate
Nombre CAS dimethyl (2,2,2-trichloro-1-hydroxyethyl)phosphonate
Otra información de estado Evidence of use in third world countries; Chemical subject to PIC regulations
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 1B
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Agrotis ipsilon
Blattella germanica
Boophilus microplus
Culex pipiens pallens
Dendrolimus punctatus
many others
Estado físico Colourless to yellow or pink waxy solid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bayer CropScience
  • Mobay
  • Makhteshim Agan
Example products using this active
  • Cekufon 80SP
  • Dylox
  • Nevugon
  • Cekufon
  • Danex
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Available in a range of formulations including soluble powders, soluble concentrates, granules and spot-on sticks.


DESTINO AMBIENTAL

for trichlorfon

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 120000 A5 Alto
Solubilidad - en solventes organicos en 20oC (mg l-1) 21500 A5 - Xileno -
363000 A5 - Acetato de etilo -
1346000 A5 - Metanol -
707000 A5 - Acetona -
Punto de fusión (oC) 80 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 100 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 2.69 X 1000 Calculado -
Log P 0.43 A5 Bajo
Masa densidad (g ml-1)/Peso específico 1.68 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: No determinable
Presión de vapor en 20oC (mPa) 0.21 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 4.50 X 10-07 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 3.77 Calculado Alta posibilidad de la lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 4.25 X 10-01 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) 71.8 A5 at 20oC, 99.3%, 1 g l-1 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 18 K4 No persistente
DT50 (laboratorio en 20oC) 18 K4 No persistente
DT50 (campo) - - -
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota Other sources: DT50 10 days (DW4); General literature DT50 range 7-30 days (R2)
Dissipation rate RL50 on plant matrix Valor 2.45 R4 -
Nota Published literature RL50 range 0.34-5.16 days, 3 field grown crops, various matrices, n=3
Dissipation rate RL50 on and in plant matrix Valor 3.9 R4 -
Nota Published literature RL50 range 1.6-6.7 days, 9 field & undercover grown crops, various matrices, n=10
Acuoso fotólisis DT50 (días) en pH 7 Valor Estable A5 -
Nota No UV degradation
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 1.6 A5 No persistente
Nota pH sensitive: DT50 117 days at pH 5, 31 minutes at pH 9, all at 25 degC
Aqua-Sedimento DT50 (días) - - -
Fase de agua sola DT50 (días) 1.2 A4 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - G4 Móvil muy alta
Koc 10
Notas y rango -
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad -

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
dichlorvos (Ref: OMS 14) This metabolite may cause environmental pollution, click here for further information Suelo   0.245   Major fraction, Relevant
desmethyl dichlorvos This metabolite may cause environmental pollution, click here for further information Suelo   0.376   Major fraction, Relevancy unknown
dichlorivinylphosphate This metabolite may cause environmental pollution, click here for further information Suelo   0.407   Major fraction, Relevancy unknown
dichloroethanol Suelo   0.044   Minor, Relevancy unknown


ECOTOXICOLOGÍA

for trichlorfon

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 0.41 R4 Piaractus mesopotamicus, Other data: Low risk LogP<3 (A5) Bajo potencial
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) 212 A5 Rata Moderado
Mamíferos - a corto plazo NOEL (mg kg-1) > 4.5 A5 Rata, 2 año Alto
(ppm dieta) > 500 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 36.8 G4 Anas platyrhynchos Alto
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.7 A3 Oncorhynchus mykiss Moderado
Pez - Crónico 21 días NOEC (mg l-1) - - -
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.00096 L3 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) - - -
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 10 A3 Scenedemus subspicatus Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 3.2 Q2 Unknown species Bajo
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) - - -
Oral aguda 48 hora LD50 (μg abeja-1) > 0.4 K4 Alto
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) - - -
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 0.519 48 hora
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 90 Mortalidad
Dose: 1.2 kg ha-1
A5 Typhlodromus pyri, adult
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 7.2 kg ha-1, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for trichlorfon

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 212 A5 Rata Moderado
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 0.53 A5 Rat -
Other Mammal toxicity endpoints Intraperitoneal LD50 = 160 mg kg-1 V3 Rat -
Intramuscular LD50 = 395 mg kg-1 V3 Rata -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.045 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.1 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.09 A5 Rat, SF=500 -
Estudios den la absorción cutánea (%) - - -
Directivo 76/464 Sustancias Peligrosas List I; List II - -
Limites de exposiciones - - -
Exposure Routes Public Possible bystander risk from spray drift
Occupational Risk of exposure acceptable under label recommendations for use for personal protection clothing and equipment
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana May cause pyrexia, cyanosis, pulmonary edema, loss of sphincter control, paralysis, coma and respiratory failure
IARC Group 3 carcinogen; USEPA - possible human carcinogen at high doses
Endocrine issues - Alteration of thyroid function

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive
IMDG Transport Code is usually 9 or 6.1
CLP classification 2013 Health: H302, H317
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R22, R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S24, S37, S60, S61
Clasificación de OSM II - Peligroso mediano
US EPA Classification (formulation) II - Warning - Moderately toxic
Número de las NU Active 2783, liquid products usually 3077
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for trichlorfon

Idioma Nombre
Inglés trichlorfon
Francés trichlorfon
Alemán Trichlorfon
Danés trichlorphon
Italiano triclorfon
Español triclorfon
Griego -
Esloveno triklorfon
Polaco trichlorfon
Sueco triklorfon
Húngaro -
Holandés -

Última actualización del registro: Wednesday 31 October 2018
Contacto: aeru@herts.ac.uk