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trifloxiestrobina (Ref: CGA 279202)
** trifloxystrobin ** HSDB 7276 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Trifloxystrobin is a widely used fungicide that has EU approval for use. It has a low aqueous solubility, a low volatility and, based on its chemical properties, would not normally be expected to leach to groundwater. It would not be expected to be persistent in soil or water systems. It has a low mammalian oral toxicity but there is some evidence that it may cause negative reproduction or fertility effects. It is highly toxic to bird, fish and aquatic invertebrates, but less toxic to honeybees and earthworms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for trifloxystrobin

Descripción: A Strobilurin foliar applied fungicide for control of certain foliar, stem and root diseases

Ejemplos de plagas controladas: Alternaria; Black root; Black spot; Botrytis; Downy mildew; Powdery mildew; Leaf spot; Rust; Rhizoctonia stem & root rot; Scab; Blossom blight

Ejemplos de aplicaciones: Cereals; Ornamentals; Vegetables including carrots, asparagus, curcubits, fruiting vegetables, root vegetables (except radish); Fruit including apples, pears, grapes, strawberries; Tropical crops

Eficacia y actividad: Wheat/Mildew=Low; Wheat/Septoria=Low; Wheat/Rust=Low; Barley/Rhynchosporium=Low; Barley/Rust=Moderate

Availability status: Current

Introduction & key dates: 1999, South Africa and USA

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur UK/Greece
Date inclusion expires 31/07/2033
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Exists as four geometric isomers: EE, EZ, ZE, and ZZ
Fórmula química C20H19F3N2O4
Canonical SMILES CC(=NOCC1=CC=CC=C1C(=NOC)C(=O)OC)C2=CC(=CC=C2)C(F)(F)F
Isomeric SMILES C/C(=N\OCC1=CC=CC=C1/C(=N\OC)/C(=O)OC)/C2=CC(=CC=C2)C(F)(F)F
International Chemical Identifier Key (InChIKey) ONCZDRURRATYFI-TVJDWZFNSA-N
International Chemical Identifier (InChI) InChI=1S/C20H19F3N2O4/c1-13(14-8-10-16(11-9-14)20(21,22)23)24-29-12-15-6-4-5-7-17(15)18(25-28-3)19(26)27-2/h4-11H,12H2,1-3H3/b24-13+,25-18+
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Trifloxystrobin Unstated isomer Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Fungicide
Grupo químico Strobilurin
Minimum active substance purity 980 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Broad spectrum with preventative and curative action. Respiration inhibitor (QoL fungicide).
CAS RN 141517-21-7
CEE número -
Número CIPAC 617
EPA américaine chimiques de code 129112
PubChem CID 11664966
Masa molecular (g mol-1) 408.37
PIN (Preferred Identification Name) methyl (2E)-(methoxyimino)(2-{[({(1E)-1-[3-(trifluoromethyl)phenyl]ethylidene}amino)oxy]methyl}phenyl)acetate
Nombre IUPAC methyl (E)-methoxyimino-{(E)-α-[1-(α,α,α-trifluoro-m-tolyl)ethylideneaminooxy]-o-tolyl}acetate
Nombre CAS methyl (αE)-α-(methoxyimino)-2-(((((1E)-1-(3-(trifluoromethyl)phenyl)ethylidene)amino)oxy)methyl)benzeneacetate
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) 11
Examples of recorded resistance -
Estado físico White solid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgriGuard
  • Bayer CropScience
  • Pan Agriculture
Example products using this active
  • Coronet
  • Jaunt
  • Nativo
  • Scorpio
  • Compass
  • Twist
  • Flint
  • Zato 50 WG
Estado de UK LERAP None (may vary with mixtures)
Formulation and application details Often supplied as water dispersible granules that are mixed with water and used as a spray.


DESTINO AMBIENTAL

for trifloxystrobin

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.61 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 500000 A5 - Acetona -
500000 A5 - Acetato de etilo -
76000 A5 - Metanol -
500000 A5 - Tolueno -
Punto de fusión (oC) 72.9 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 285 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 3.16 X 1004 Calculado -
Log P 4.5 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.36 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 3.40 X 10-03 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 2.30 X 10-03 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -0.30 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 1.43 X 10-05 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 250.7nm = 17500, no absorption between 340-750nm A5 -
Surface tension (mN m-1) 65.3 A5 -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general Not readily biodegradable
Degradación de suelo (días) (aerobic) DT50 (típico) 0.34 Click here to see a warning relating to modelling and this active substance A5 No persistente
DT50 (laboratorio en 20oC) 0.34 A5 No persistente
DT50 (campo) 1.69 A5 No persistente
DT90 (laboratorio en 20oC) 39 A4 -
DT90 (campo) 20.9 A5 -
Endpoint de modelado DT50 0.60 A5 -
Nota EU RAR 2016 lab studies DT50 range 0.13-2.83 days, Soils = 20; field study DT50 range 1.1-2.73 days, DT90 range 10.4-35.6 days, Soils=6
Dissipation rate RL50 on plant matrix Valor 5.0 R4 -
Nota Published literature RL50 range 1.7-7.0 days, field grown ginseng & peppers, various matrices, n=4
Dissipation rate RL50 on and in plant matrix Valor 9.1 R4 -
Nota Published literature RL50 range 6.4-12.0 days, fruit of field grown grapes & mango, n=3
Acuoso fotólisis DT50 (días) en pH 7 Valor 2.7 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 40 A5 Persistente moderado
Nota pH sensitive: DT50 480 days at pH 5, 40 days at pH 7, 1.2 days at pH 9, all at 25 degC
Aqua-Sedimento DT50 (días) 2.4 A5 Rápido
Fase de agua sola DT50 (días) 1.1 A5 Moderado rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 43.5 A5 Móvil un poco
Kfoc 2287
1/n 0.96
Notas y rango EU dossier Kf range 11.2-325 mL/g, Koc range 1642-3745 mL/g, Soils=6
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
(E,E)-trifloxystrobin acid (Ref: CGA 321113) This metabolite may cause environmental pollution, click here for further information Suelo   0.970   Major fraction, Relevant
(E)-2-((((1-(3-(trifluoromethyl)phenyl)ethylidene)amino)oxy)methy)benzonitrile (Ref: CGA 357276) Suelo   0.056   Minor fraction; Relevant
(Z,E)-methoxyimino-(2-(1-(3-trifluoro methylphenyl-ethylideneaminooxymethyl)-phenyl)-acetic acid (Ref: CGA 373466) This metabolite may cause environmental pollution, click here for further information Suelo   0.425   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
(Ref: CGA 166988) - Poultry - -
(Ref: CGA 279202)
Nota: Koc = 951–3064
- Soil - -
(Ref: CGA 327262) - Soil (Photolysis) - -
(Ref: CGA 331409) - Plant; Water (Aerobic); Soil (Photolysis) - -
(Ref: CGA 357261)
Nota: LD50(oral, rat) >2000 mg kg-1; Koc = 389–567
- Plant; Water (Photolysis) - -
(Ref: CGA 357362) - Water (Photolysis) - -
(Ref: NOA 413161)
Nota: LD50(oral, rat) >2000 mg kg-1; Risk to Groundwater
- Soil; Plant - -
(Ref: NOA 413163)
Nota: LD50(oral, rat) >2000 mg kg-1
- Soil; Plant - -
(Ref: NOA 414412)
Nota: LD50(oral, rat) >2000 mg kg-1
- - - -
(Ref: NOA 417076) - Poultry; Plant - -


ECOTOXICOLOGÍA

for trifloxystrobin

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 431 A5 Umbral de importancia
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) > 6.4 A5 Rata Alto
(ppm dieta) > 100 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 5200 mg kg feed-1 A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 0.022 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.008 A5 Oncorhynchus mykiss Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.011 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.003 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) 0.45 A4 Chironomus riparius, EC50 Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) 0.2 A5 Chironomus riparius Moderado
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 1.93 F3 Lemna gibba Moderado
Non-target plants > 270 A5 Brassica oleracea, Daucus carota, Lactuca sativa, Zea mays, Lolium perenne
Vegetative vigour, ER50
as g/ha
-
> 270 A5 Brassica oleracea, Daucus carota, Lactuca sativa, Zea mays, Lolium perenne
Seedling emergence, ER50
as g/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.0053 A4 Scenedemus subspicatus, 72 hora Alto
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.01 Q2 Unknown species Moderado
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) > 100 A5 Bajo
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) > 110 A5 Apis mellifera Bajo
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 1000 A5 Bajo
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 3.5 A5 Eisenia foetida Moderado
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 383 >
A5 Typhlodromus pyri
-
% Causalidad 29 Mortality/ Beneficial capacity
Dose: 0.01 kg ha-1
A4 Aphidius rhopalosiphi, adult
-
Otro arthropoda (2) LR50 g ha-1 500 >
A5 Aphidius colemani
-
% Causalidad 93 Mortalidad
Dose: 0.5 kg ha-1
A5 Typhlodromus pyri, protonymph
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.27 mg kg-1 soil, 28 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for trifloxystrobin

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 2000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.5 A5 Rat, 4hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.1 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) Ningunos asignaron A5 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.06 A4 Rat, 2 year, SF=100 -
Estudios den la absorción cutánea (%) 1.6-3.8 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational No unacceptable risks to operators or other workers identified
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A3; B0; C0; D0; E0

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

Cuestiones generales de la salud humana Probable liver & teste toxicant
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 9
CLP classification 2013 Health: H317
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Xn - Harmful: R43
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S2, S24, S37, S46, S60, S61
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
Número de las NU Variable with product, usually 3077 or 3082
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for trifloxystrobin

Idioma Nombre
Inglés trifloxystrobin
Francés trifloxystrobine
Alemán Trifloxystrobin
Danés trifloxystrobin
Italiano trifloxistrobina
Español trifloxiestrobina
Griego -
Esloveno trifloksistrobin
Polaco trifloksystrobina
Sueco trifloxystrobin
Húngaro trifloxistrobin
Holandés trifloxystrobine

Última actualización del registro: Wednesday 31 October 2018
Contacto: aeru@herts.ac.uk