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triflusulfuron-metil (Ref: DPX 66037)
** triflusulfuron-methyl ** triflusulfuron ** IN 66037 ** T 478 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for triflusulfuron-methyl

Descripción: A post-emergence herbicide for the control many annual and perennial broad-leaved weeds

Ejemplos de plagas controladas: Black bindweed; Charlock; Chickweed; Cleavers; Fathen; Field pansy; Fools parsley, Knotgrass; Redshank; Volunteer rape

Ejemplos de aplicaciones: Sugarbeet; Fodder beet; Mangolds

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1992

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur France/Denmark
Date inclusion expires 31/12/2019
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism None
Fórmula química C17H19F3N6O6S
Canonical SMILES CC1=CC=CC(=C1S(=O)(=O)NC(=O)NC2=NC(=NC(=N2)OCC(F)(F)F)N(C)C)C(=O)OC
Isomeric SMILES No data
International Chemical Identifier Key (InChIKey) IMEVJVISCHQJRM-UHFFFAOYSA-N
International Chemical Identifier (InChI) InChI=1S/C17H19F3N6O6S/c1-9-6-5-7-10(12(27)31-4)11(9)33(29,30)25-15(28)22-13-21-14(26(2)3)24-16(23-13)32-8-17(18,19)20/h5-7H,8H2,1-4H3,(H2,21,22,23,24,25,28)
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Herbicida
Grupo químico Sulfonylurea
Minimum active substance purity 96%
Known relevant impurities EU dossier - N,N-dimethyl-6-(2,2,2-trifluoroethoxy)-1,3,5-triazine-2,4-diamine 6/g/kg
Sustancias de origen Sintéticas
Modo de acción Selective, inhibits amino acid sysnthesis. Inhibits plant amino acid synthesis - acetohydroxyacid synthase AHAS
CAS RN 126535-15-7
CEE número -
Número CIPAC 731.201
EPA américaine chimiques de code 129002
PubChem CID 92434
Masa molecular (g mol-1) 492.43
PIN (Preferred Identification Name) methyl 2-({[4-(dimethylamino)-6-(2,2,2-trifluoroethoxy)-1,3,5-triazin-2-yl]carbamoyl}sulfamoyl)-3-methylbenzoate
Nombre IUPAC methyl 2-[4-dimethylamino-6-(2,2,2-trifluoroethoxy)-1,3,5-triazin-2-ylcarbamoylsulfamoyl]-m-toluate
Nombre CAS methyl 2-[[[[[4-(dimethylamino)-6-(2,2,2-trifluoroethoxy)-1,3,5-triazin-2-yl]amino]carbonyl]amino]sulfonyl]-3-methylbenzoate
Otra información de estado -
Relevant Environmental Water Quality Standards -
Herbicide Resistance Classification (HRAC) B
Herbicide Resistance Classification (WSSA) 2
Insecticide Resistance Classification (IRAC) No aplicable
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance -
Estado físico White crystalline solid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • DuPont
Example products using this active
  • Debut
  • Upbeet
  • Safari
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as water dispersible granules that are mixed with water and used as a spray.


DESTINO AMBIENTAL

for triflusulfuron-methyl

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 260 A5 - @ 25 DegC Moderado
Solubilidad - en solventes organicos en 20oC (mg l-1) 27000 A5 - Acetato de etilo -
120000 A5 - Acetona -
1.6 A5 - Hexano -
17000 A5 - Metanol -
Punto de fusión (oC) 160 A5 -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 159 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 9.12 X 1000 Calculado -
Log P 0.96 A5 - @ 25 DegC Bajo
Masa densidad (g ml-1)/Peso específico 1.46 B5 -
Disociación constante (pKa) at 25oC 4.4 A5 -
Nota: Ácido débil
Presión de vapor en 20oC (mPa) 6.0 X 10-07 A3 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 1.4 X 10-09 A3 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index 1.82 Calculado Estado de transición
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 8.83 X 10-03 Calculado -
Nota -
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Bajo
Maximum UV-vis absorption L mol-1 cm-1 - - -
Surface tension (mN m-1) 67.92 A5 at 20oC, 98.9% -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 3 B5 No persistente
DT50 (laboratorio en 20oC) 6.5 A5 No persistente
DT50 (campo) 5 A5 No persistente
DT90 (laboratorio en 20oC) 31.1 A5 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier lab studies DT50 range 5-12 days, DT90 range 18-69 days; Other studies: DT50 2-4 days (F3)
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 13.9 A5 Moderado rápido
Nota pH sensitive: 3.8 days @ pH 5, 24.6 days at pH 9
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 32 A5 Persistente moderado
Nota pH sensitive: 3.7 days at pH 5, 36 days at pH 9
Aqua-Sedimento DT50 (días) 24 A5 Rápido
Fase de agua sola DT50 (días) 30 A5 Estable

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 0.68 A5 Móvil
Kfoc 58
1/n 0.92
Notas y rango EU dossier Kf range 0.36-1.28 mL/g, Kfoc range 25-132 mL/g, 1/n range 0.90-0.94, Soils=5
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
methyl saccharine (Ref: IN-W6725) This metabolite may cause environmental pollution, click here for further information Suelo   0.837   Major fraction, Relevant
N,N-dimethyl-6-(2,2,2-trifluoroethoxy)-1,3,5-triazine-2,4-diamine (Ref: IN-D8526) This metabolite may cause environmental pollution, click here for further information Suelo   0.923   Major fraction, Relevant
N-desmethyl triazine amine (Ref: IN-E7710) This metabolite may cause environmental pollution, click here for further information Suelo   0.359   Major fraction, Relevant
N,N-bis-desmethyl triazine amine (Ref: IN-M7222) This metabolite may cause environmental pollution, click here for further information Suelo   0.129   Major fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
triflusulfuron
(Ref: )
Nota: Major fraction, Relevant
- Water/sediment - -
N,N-dimethyl-6-(2,2,2-trifluoroethoxy)-1,3,5-triazine-2,4-diamine
(Ref: IN-D8526)
Nota: Soil DT50 = 74664 days
triazine amine Soil (Aerobic) - -
N-methyl-6-(2,2,2-trifluoroethoxy)-1,3,5-triazine-2,4-diamine
(Ref: IN-E7710)
Nota: Soil DT50 = 30393 days
N-desmethyl triazine amine Soil (Aerobic) - -
6-(2,2,2-trifluoroethoxy)-1,3,5-triazine-2,4-diamine
(Ref: IN-M7222)
N,N-bis-desmethyl triazine amine Rat; Plant; Soil (Aerobic) - -


ECOTOXICOLOGÍA

for triflusulfuron-methyl

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 1.3 Q2 Estimado Bajo potencial
CT50 (días) No disponible -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mamíferos - a corto plazo NOEL (mg kg-1) > 6.9 B5 Rata Alto
(ppm dieta) > 100 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2250 A5 Colinus virginianus Bajo
Birds - Short term dietary (LC50/LD50) > 1535 mg kg-1 bw/día A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 730 A5 Oncorhynchus mykiss Bajo
Pez - Crónico 21 días NOEC (mg l-1) 57.7 A5 Oncorhynchus mykiss Bajo
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) > 960 A5 Daphnia magna Bajo
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 11.0 A5 Daphnia magna Bajo
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) 0.0028 A5 Lemna gibba Alto
Non-target plants 17.8 A5 Grain sorghum
Vegetative vigour, ER50
as g/ha
-
23.5 A5 OSR
Seedling emergence, ER50
as g/ha
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) 0.046 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas Contacto aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Oral aguda 48 hora LD50 (μg abeja-1) > 100 A5 Bajo
Modo desconocido aguda 48 hora LD50 (μg abeja-1) - - -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 1000 A5 Eisenia foetida Bajo
Lombrices - Crónicos 14 día NOEC, reproducción (mg kg-1) 250 A4 Eisenia foetida, 56 día Bajo
Other soil macro-organisms - e.g. Collembola LR50 / EC50 / NOEC / % Causalidad - - -
Otro arthropoda (1) LR50 g ha-1 120 >, as product ha-1 (WG 50: Conc 50 g as/L)
A5 Aphidius rhopalosiphi
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 120 >, as product ha-1 (WG 50: Conc 50 g as/L)
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No adverse effect
Carbon mineralisation: No adverse effect
A5
Dose: 7.5x field rate, 56 días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for triflusulfuron-methyl

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 5000 A5 Rata Bajo
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) > 5.1 A5 Rat, 4 hr (nose only) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.04 A5 Rat, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 1.2 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.04 A5 Rat, SF=100 -
Estudios den la absorción cutánea (%) 50 A5 -
Directivo 76/464 Sustancias Peligrosas Lista II - -
Limites de exposiciones - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational No unacceptable risks to operators or other workers identified
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Mutágeno Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

-

-

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana May affect body weight and food intake
Possible liver toxicant
USEPA - possible human carcinogen

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
Treat fires with water spray, foam, dry chemical or CO2
CLP classification 2013 Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases Carcinogen category 3: R40
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases -
Clasificación de OSM U - Es poco probable que presente un riesgo agudo
US EPA Classification (formulation) III - Caution - Slightly toxic
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks -


TRADUCCIONES

for triflusulfuron-methyl

Idioma Nombre
Inglés triflusulfuron-methyl
Francés triflusulfuron-methyle
Alemán Triflusulfuron
Danés triflusulfuron-methyl
Italiano triflusulfuron-metile
Español triflusulfuron-metil
Griego -
Esloveno triflusulfuron-metil
Polaco triflusulfuron metylu
Sueco triflusulfuronmetyl
Húngaro triszulfuron-metil
Holandés -

Última actualización del registro: Friday 14 September 2018
Contacto: aeru@herts.ac.uk