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zeta-cipermetrin (Ref: FMC 56701)
** zeta-cypermethrin ** zetacypermethrin ** z-cypermethrin ** F 56701 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for zeta-cypermethrin

Descripción: An insecticide used to control beetles, aphids and Lepidoptera in a range of crops

Ejemplos de plagas controladas: Aphids including peach aphid; Earworms; weevils; Cutworms; Pea moth; Flax flea beetle; Pollen beetle; Pod midge; Cabbage stem flea beetle

Ejemplos de aplicaciones: Cotton; Cabbage; Lettuce; Onions, garlic & shallots; Pecans; Rice, Sorghum; Alfalfa; Soybeans; Sugarcane; Sugarbeet; Linseed; Sunflowers; Fruit including aples, pears, berries; Tree nuts; Potatoes; Cereals including wheat, barley, ots

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1984

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Austria/Germany
Date inclusion expires 30/11/2021
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Cypermethrin is a chiral molecule and consists of eight isomers, four cis and four trans. Zeta-cypermethrin is a mixture of stereoisomer pairs
Fórmula química C22H19Cl2NO3
Canonical SMILES CC1(C(C1C(=O)OC(C#N)C2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Cl)Cl)C
Isomeric SMILES CC1(C(C1C(=O)O[C@H](C#N)C2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Cl)Cl)C
International Chemical Identifier Key (InChIKey) KAATUXNTWXVJKI-QPIRBTGLSA-N
International Chemical Identifier (InChI) InChI=1S/C22H19Cl2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-5-9-15/h3-12,17-18,20H,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Zeta-cypermethrin - Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Pyrethroid
Minimum active substance purity 850 g/kg
Known relevant impurities EU dossier - toluene <2g/kg, tars 12.5 g/kg
Sustancias de origen Sintéticas
Modo de acción Contact and stomach action. Acts mainly on the nervous system. Sodium channel modulator.
CAS RN 97955-44-7
CEE número 257-842-9
Número CIPAC 733
EPA américaine chimiques de code 109702/129064
PubChem CID 12617362
Masa molecular (g mol-1) 416.31
PIN (Preferred Identification Name) mixture of the stereoisomer pairs (S)-cyano(3-phenoxyphenyl)methyl (1R*,3R*)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate and (S)-cyano(3-phenoxyphenyl)methyl (1R*,3S*)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate in the ratio range 45–55 to 55–45 respectively
Nombre IUPAC mix of (S)-α-cyano-3-phenoxybenzyl (1RS,3RS;1RS,3SR)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Nombre CAS (S)-cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
Otra información de estado -
Relevant Environmental Water Quality Standards UK Environment Agency non-statutory standard for the protection of aquatic life in freshwater and saltwater annual average 0.0002 ug/L, max acceptable conc 0.002 ug/L
UK statutory standard for water quality: ‘Good’ for fresh, transitional & saltwater: 0.1 ng/L as annual mean conc, 0.4 ng/L 95th percentile
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 3
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Earias vittella
Helicoverpa armigera
Estado físico Pale yellow viscous liquid
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • AgriGuard
  • BASF
  • Belchim
Example products using this active
  • Fury 10EW
  • Minuet
  • Synphony
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Often supplied as oil in water emulsions that are mixed with water and used as a spray.


DESTINO AMBIENTAL

for zeta-cypermethrin

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.039 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 40120 A5 - n-Heptano -
1000000 A5 - p-Xileno -
1000000 A5 - Acetona -
1000000 A5 - Acetato de etilo -
Punto de fusión (oC) -3 A5 -
Punto de ebullición (oC) 360 A3 -
El punto de degradación (oC) - - -
Punto de inflamación (oC) 181 A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 3.98 X 1006 Calculado -
Log P 6.6 V3 - (EU dossier: LogP 5-6 at pH 2, 24oC; A4) Alto
Masa densidad (g ml-1)/Peso específico 1.24 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 2.53 X 10-04 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 2.31 X 10-03 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -1.09 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Alto
Maximum UV-vis absorption L mol-1 cm-1 Neutral solution: 278nm = 2468, 290nm = 765; [Acidic solution 278nm = 2472, 290nm = 765; [Basic solution: hydrolysis product formed with maxima = 308 nm A5 -
Surface tension (mN m-1) 59.5 A5 at 25oC, 90% solution -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 49 A5 Persistente moderado
DT50 (laboratorio en 20oC) 60 A5 Persistente moderado
DT50 (campo) 10 A5 No persistente
DT90 (laboratorio en 20oC) 56.7 A3 -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota Earlier EU dossier lab studies DT50 range 6-105 days (A3), DT90 range 34-80.5 days, Current dossier field studies DT50 6-24 days S. France, Italy and Germany;Other data source: 14 days (DW4)
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor - - -
Nota -
Acuoso fotólisis DT50 (días) en pH 7 Valor 3.05 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 25 A5 No persistente
Nota pH sensitive: Stable at pH 4, variable at pH 9
Aqua-Sedimento DT50 (días) 2 A5 Rápido
Fase de agua sola DT50 (días) 0.1 A5 Rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 1033 A5 No Móvil
Kfoc 121786
1/n 1.30
Notas y rango EU dossier Kf range 416-1897 mL/g, Kfoc range 18326-285562 mL/g, 1/n range 1.15-1.47, Soils=4
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid This metabolite may cause environmental pollution, click here for further information Suelo   0.242   Major fraction, Relevant
3-phenoxybenzoic acid Suelo   0.084   Minor fraction, Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
(3-phenoxyphenyl)methanol mPBAcohol Plant; Animal - -
3-phenoxybenzaldehyde mPBAldehyde Plant - -


ECOTOXICOLOGÍA

for zeta-cypermethrin

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 356 A5 Whole fish Umbral de importancia
CT50 (días) 1.2 -
Mamíferos - Agudos oral LD50 (mg kg-1) 86 A5 Rata Alto
Mamíferos - a corto plazo NOEL (mg kg-1) - - -
(ppm dieta) - -
Pájaros/aves - Agudos LD50 (mg kg-1) > 5124 A5 Anas platyrhynchos Bajo
Birds - Short term dietary (LC50/LD50) > 601 mg kg-1 bw/día A5 Anas platyrhynchos -
Pez - agudo 96 hora LC50 (mg l-1) 0.00069 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.000585 A5 Oncorhynchus mykiss Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.00014 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.00001 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.0128 F3 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) > 0.001 A5 Chironomus riparius Alto
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) - - -
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants > 100 A5 Ryegrass
Vegetative vigour, EC50
as mg/kg soil dw
-
> 100 A5 Ryegrass
Seedling emergence, ER50
as mg/kg soil dw
-
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 1 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.002 A5 Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.044 A5 Alto
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Lombrices - Agudos 14 día LC50 (mg kg-1) 37.5 A5 Eisenia foetida Moderado
Lombrices - Crónicos NOEC, reproducción (mg kg-1) - - -
Other soil macro-organisms Agudos LC50 (mg kg-1) - - -
Crónicos NOEC (mg kg-1) - - -
Otro arthropoda (1) LR50 g ha-1 5.48 as mL/ha
A5 Aphidius rhopalosiphi, adult
-
% Causalidad - - -
Otro arthropoda (2) LR50 g ha-1 23.18 7 día
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect @ 59 días
Carbon mineralisation: No significant adverse effect @ 64 días
A5
Dose: 2 mg kg-1 soil
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for zeta-cypermethrin

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 86 A5 Rata Alto
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 1.26 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.04 A5 Dog, 1 year, SF=200 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.125 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.02 A5 Dog, 90 day, SF=400 -
Estudios den la absorción cutánea (%) - - -
Directivo 76/464 Sustancias Peligrosas - - -
Exposure Routes Public No unacceptable risks to bystanders identified
Occupational Possible risk of exposure to operators or other workers identified - PPE/PPC advised
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A3; B3; C3; D0; E0

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

Cuestiones generales de la salud humana USEPA - possible human carcinogen
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H302, H317, H332
Environment: H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T - Toxic: R25
Xn - Harmful: R48/22
Xi - Irritant: R37
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S36/37/39, S45, S60, S61
Clasificación de OSM Ib - Peligroso alto
Número de las NU Usually 3352
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for zeta-cypermethrin

Idioma Nombre
Inglés zeta-cypermethrin
Francés zetacypermethrine
Alemán zeta-Cypermethrin
Danés zeta-cypermethrin
Italiano zeta-cipermetrina
Español zeta-cipermetrin
Griego -
Esloveno zeta-cipermetrin
Polaco zeta-cypermetryna
Sueco -
Húngaro zeta-cypermethrin
Holandés -

Última actualización del registro: Wednesday 04 March 2020
Contacto: aeru@herts.ac.uk