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beta-ciflutrina (Ref: OMS 3051)
** beta-cyfluthrin ** FCR 4545 ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio

RESUMEN

Beta-cyfluthrin is a pyrethroid insecticide approved for use in the EU. It has a low aqueous solubility, semi-volatile and is not expected to leach to groundwater. It is highly toxic to mammals and may be a neurotoxin. It is also highly toxic to fish, aquatic invertebrates, aquatic plants and honeybees but slightly less toxic to birds, algae and earthworms.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for beta-cyfluthrin

Descripción: A pyrethroid insecticide effective against a range of common pests including locusts in a many different crops

Ejemplos de plagas controladas: Migratory locusts; Grasshoppers; Mosquitoes; Bedbugs; Loopers; Cutworms; Spittlebugs; Leaf hoppers; Caterpillars; Armyworms; Weevils; Stinkbugs

Ejemplos de aplicaciones: Alfalfa; Corn; Cotton; Peanuts; Sorghum; Sugarcane; Sugarbeet; Tobacco; Wheat; Brassicas; Sweetcorn; Potatoes; Tomatoes; Stone fruit; Root vegetables

Eficacia y actividad: Field trials have adequately demonstrated efficiacy.

Availability status: Current

Introduction & key dates: 1993, first reported

CEE Regulación 1107/2009 ( 91/414):
Estado Approved
Dossier rapporteur/co-rapporteur Germany/Hungary
Date inclusion expires 31/10/2020
UE Candidatas a sustitución No
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, Estados Unidos

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism An isomeric mixture of the two biologically active diastereoisomeric pairs of cyfluthrin. Diastereomer II 300-400 g/kg; Diastereomer IV 570-670 g/kg.
Fórmula química C22H18Cl2FNO3
Canonical SMILES CC1(C(C1C(=O)OC(C#N)C2=CC(=C(C=C2)F)OC3=CC=CC=C3)C=C(Cl)Cl)C
Isomeric SMILES CC1([C@H](C1C=C(Cl)Cl)C(=O)O[C@@H](C#N)C2=CC(=C(C=C2)F)OC3=CC=CC=C3)C
International Chemical Identifier Key (InChIKey) OFHFONYRMVKULH-WNYJFNBPSA-N
International Chemical Identifier (InChI) InChI=1S/C22H18Cl2FNO3/c1-22(2)15(11-19(23)24)20(22)21(27)29-18(12-26)13-8-9-16(25)17(10-13)28-14-6-4-3-5-7-14/h3-11,15,18,20H,1-2H3
¿Diagrama de estructura 2D / imagen disponible?

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide
Grupo químico Pyrethroid
Minimum active substance purity >=965 g/kg
Known relevant impurities EU dossier - None declared
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action. Sodium channel modulator.
CAS RN 1820573-27-0
CEE número 269-855-7
Número CIPAC 482
EPA américaine chimiques de code 118831
PubChem CID 56608859
Masa molecular (g mol-1) 434.29
PIN (Preferred Identification Name) reaction mixture comprising the enantiomeric pair rac-(R)-cyano(4-fluoro-3-phenoxyphenyl)methyl (1S,3S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate in ratio 1:2 with the enantiomeric pair rac-(R)-cyano(4-fluoro-3-phenoxyphenyl)methyl (1S,3R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate
Nombre IUPAC (R)-α-cyano-4-fluoro-3-phenoxybenzyl (1S,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-4-fluoro-3-phenoxybenzyl (1R,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarbox
Nombre CAS cyano(4-fluoro-3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
Otra información de estado -
Relevant Environmental Water Quality Standards UK Environment Agency non-statutory standard for the protection of freshwater and saltwater aquatic life 0.001 ug/L]
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 3
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Helicoverpa armigera
Musca domestica
Triatoma infestans
Estado físico White crystalline powder
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bayer CropScience
  • Bayer Environmental Science
  • AgroCare
Example products using this active
  • Chinook Blue
  • Modesto
  • Hawk
  • Acilothrin B
  • Bulldog 25EC
Estado de UK LERAP Buffer probably required in UK - see product label
Formulation and application details Available in a wide variety of formulations including emulsifiable concentrates, granules, oil in water emulsions, suspension concentrates, ULVs and wettable powders.


DESTINO AMBIENTAL

for beta-cyfluthrin

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.0019 A5 - (isomer mean) Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 150000 A4 - Tolueno -
10000 A4 - n-Hexano -
200000 A4 - Cloruro de metileno -
Punto de fusión (oC) 82 A5 - (82-96 degC) -
Punto de ebullición (oC) Decomposes before boiling A5 -
El punto de degradación (oC) 210 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable L3 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 7.08 X 1005 Calculado -
Log P 5.85 A5 - (isomer mean) Alto
Masa densidad (g ml-1)/Peso específico 1.35 A5 -
Disociación constante (pKa) at 25oC No aplicable A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 2.8 X 10-05 A4 - (isomer mean) Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 0.347 A5 - (isomer mean) Volátil moderado
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -2.01 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 SOMER II [Neutral pH; 204nm=41366, 269nm=2129, 276nm=2008, 291nm=80; [Acidic pH: 203nm=44498, 269nm=2129, 276nm=2008, 291nm=80
Basic pH: 220nm=29639, 295nm=1486 ISOMER IV [Neutral pH 204nm=42545, 269nm=2127, 276nm=2000, 291nm=85
Acidic pH: 204nm=42503, 269nm=2042, 276nm=1957, 291nm=43
Basic pH: 219nm=28888, 294nm=1617
A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general Not readily biodegradable
Degradación de suelo (días) (aerobic) DT50 (típico) 28.0 A5 No persistente
DT50 (laboratorio en 20oC) 28.0 A5 No persistente
DT50 (campo) 93.3 A5 Persistente moderado
DT90 (laboratorio en 20oC) 677 A5 -
DT90 (campo) 192 A5 -
Endpoint de modelado DT50 - - -
Nota EU 2018 Dossier lab studies DT50 (normalised) range 16.7-89.5 days, DT90 (measured) range 66-194 days, Soils =4, Field studies DT50 (measured) range 3.3-297 days, DT90 (measured) range 52-359 days, Soils=4; EU 2002 Dossier Lab studies DT50 range 4-54 days, DT90 range 53-1664 days, field study DT50 range 5-21 days (Germany), DT90 range 70-133 days
Dissipation rate RL50 on plant matrix Valor 1.4 R4 -
Nota Published literature RL50 range 0.8-1.7 days,2 field crops, various matrices, n=3
Dissipation rate RL50 on and in plant matrix Valor 3.9 R4 -
Nota Published literature RL50 range 3.0-4.7 days, 2 field crops, various matrices, n=2
Acuoso fotólisis DT50 (días) en pH 7 Valor 5.5 A5 Moderado rápido
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor 160 A5 Persistente
Nota pH sensitive: DT50: >1 year at pH 4, 33 hours at pH 9
Aqua-Sedimento DT50 (días) 27.6 A5 Rápido
Fase de agua sola DT50 (días) 0.5 A5 Rápido

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd 1216 A5 No Móvil
Koc 104491
Notas y rango EU 2018 dossier Kd range 810-1793 mL/g, Koc range 64286-180290 mL/g, Soils=5
Freundlich Kf - - -
Kfoc -
1/n -
Notas y rango -
pH senbsibilidad -

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
4-fluoro-3-phenoxybenzoic acid This metabolite may cause environmental pollution, click here for further information Suelo   0.127   Major fraction, Relevant
3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylic acid This metabolite may cause environmental pollution, click here for further information Suelo   0.405   Major fraction, Relevant


ECOTOXICOLOGÍA

for beta-cyfluthrin

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 506 A5 Umbral de importancia
CT50 (días) 9 -
Mamíferos - Agudos oral LD50 (mg kg-1) > 14.3 A5 Rat (as cyfluthrin) Alto
Mamíferos - a corto plazo NOEL (mg kg-1) 1.5 L3 Rata Alto
(ppm dieta) 100 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 170 A5 Serinus canaria Moderado
Birds - Short term dietary (LC50/LD50) > 5000 ppm A5 Colinus virginianus, as cyfluthrin -
Pez - agudo 96 hora LC50 (mg l-1) 0.000068 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.000032 A4 Oncorhynchus mykiss, 72 día Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.00029 A4 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) 0.00014 A5 Daphnia magna Alto
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.0000022 A5 Americamysis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) 0.00045 A5 Chironomus riparius Alto
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) 0.00004 A5 Chironomus riparius Alto
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) > 0.00084 A5 Lemna gibba Alto
Non-target plants > 60 A5 Cabbage, cucumber, sunflower, barley, rye
Vegatitive vigour, ER50
as g/ha
-
> 60 - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.002 A5 Scenedemus subspicatus Alto
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) 0.01 A3 Unknown species Moderado
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.012 A5 Apis mellifera Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.05 A5 Apis mellifera Alto
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.46 R3 Bombus terrestris Alto
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.12 R3 Bombus terrestris Alto
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.035 R4 Osmia bicornis Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Lombrices - Agudos 14 día LC50 (mg kg-1) 0.565 A3 Eisenia foetida, as EC10 corr Alto
Lombrices - Crónicos NOEC, reproducción (mg kg-1) > 0.825 A5 Eisenia foetida, corr Moderado
Other soil macro-organisms Agudos LC50 (mg kg-1) - - -
Crónicos NOEC (mg kg-1) 28 A5 Folsomia candida, corr -
Otro arthropoda (1) LR50 g ha-1 0.163 Mortalidad
A5 Aphidius rhopalosiphi
-
% Causalidad 100 Mortalidad
Dose: 1.675 kg ha-1
A5 Aphidius rhopalosiphi
-
Otro arthropoda (2) LR50 g ha-1 0.0025 Mortalidad
A5 Typhlodromus pyri
-
% Causalidad - - -
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.18 g as/ha
-
Mesocosm study data NOEAEC mg l-1 0.00005 A5 Aquatic community -
NOEAEC mg l-1 0.00001 A4 NOEC Aquatic community -


LA SALUD HUMANA Y PROTECCIÓN

for beta-cyfluthrin

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) > 14.3 A5 Rat (as cyfluthrin) Alto
Mammals - Dermal LD50 (mg kg-1 body weight) > 2000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 0.081 A5 Rat (aerosol) -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.01 A5 Rat 4wk, SF=100 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.01 A5 Rat, SF=100 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) 0.01 A5 Rat 4wk, SF=100 -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.00024 A5 Rat 13wk, SF=100 -
Estudios den la absorción cutánea (%) 0.1-13.0 A5 concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Exposure Routes Public -
Occupational -
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A0; B0; C0; D0; E0

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

Cuestiones generales de la salud humana May cause metabolic or neurological disturbances
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes Not explosive or oxidising
IMDG Transport Code is usually 6.1
CLP classification 2013 Health: H300, H330, H362, H361d, H362, H335
Environment: H400, H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T+ - Very toxic: R26/28
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S1/2, S36/37/39, S45, S60, S61
Clasificación de OSM Ib - Peligroso alto
Número de las NU Usually 2588
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for beta-cyfluthrin

Idioma Nombre
Inglés beta-cyfluthrin
Francés betacyflutrine
Alemán beta-Cyfluthrin
Danés betacyfluthrin
Italiano beta-ciflutrina
Español beta-ciflutrina
Griego beta-cyfluthrin
Esloveno beta-ciflutrin
Polaco beta-cyflutryna
Sueco betacyflutrin
Húngaro beta-ciflutrin
Holandés -

Última actualización del registro: Wednesday 11 March 2020
Contacto: aeru@herts.ac.uk