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beta-cipermetrina (Ref: OMS 3068)
** beta-cypermethrin ** beta-cipermetrin ** cypermethrinbeta ** Traducciones

Destino ambiental - Ecotoxicología - La salud humana - A a Z Indice - Inicio
Otros datos se pueden encontrar en el VSDB

RESUMEN

A pyrethroid insecticide currently within the EU regulatory review process. It has a low aqueous solubility, in relatively volatile and, based on its chemical properties, is not expected to leach to groundwater. It is non-persistent in soil systems. It is highly toxic to mammals and there is some concern regarding its ability to bioconcentrate. It is moderately toxic to birds, earthworms and highly toxic to honey bees and most aquatic species except for algae where there is a reduced risk.

INFORMACIÓN GENERAL Click here for an explantaion of the general chemical status information
for beta-cypermethrin

Descripción: A broad spectrum insecticide used to control common pests in crops, public health and veterinary situations.

Ejemplos de plagas controladas: Aphids; Cockroaches; Fleas; Ticks; Flies; Mosquitoes

Ejemplos de aplicaciones: Oilseed rape; Wheat; Barley; Maize; Livestock; Public health situations

Eficacia y actividad: -

Availability status: Current

Introduction & key dates: 1989

CEE Regulación 1107/2009 ( 91/414):
Estado Not approved
Dossier rapporteur/co-rapporteur United Kingdom
Date inclusion expires Expired
UE Candidatas a sustitución No aplicable
Incluido en la base de datos de la UE

Approved for use () or known to be used () in the following European countries: Click to access a note on the approvals information on this site

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia

Estructura química: Click here for further information on the general chemical status information used on this site
Isomerism Cypermethrin is a chiral molecule and consists of eight isomers, four cis and four trans. Beta -cypermethirn is a reaction mixture of two enantiomeric forms.
Fórmula química C22H19Cl2NO3
Canonical SMILES CC1(C(C1C(=O)OC(C#N)C2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Cl)Cl)C
Isomeric SMILES CC1([C@H]([C@H]1C(=O)O[C@H](C#N)C2=CC(=CC=C2)OC3=CC=CC=C3)C=C(Cl)Cl)C
International Chemical Identifier Key (InChIKey) GUQZCTLEJXHSIH-RZAVTOELSA-N
International Chemical Identifier (InChI) InChI=1S/C22H19Cl2NO3/c1-22(2)17(12-19(23)24)20(22)21(26)28-18(13-25)14-7-6-10-16(11-14)27-15-8-4-3-5-9-15/h3-12,17-18,20H,1-2H3/t17-,18+,20-/m0/s1
¿Diagrama de estructura 2D / imagen disponible?

Click to access the Cambridge Crystallographic Data Centre (CCDC) website
Cambridge Crystallographic Data Centre diagrams:
Nombre Común Relación Vínculo
Beta-cypermethrin - Click here for the CCDC structure diagram

Estado general: Click here for further information on the general chemical status information used on this site
Tipo de pesticida Insecticide, Veterinary substance
Grupo químico Pyrethroid
Minimum active substance purity >960mg/kg
Known relevant impurities EU dossier: none declared
Sustancias de origen Sintéticas
Modo de acción Non-systemic with contact and stomach action. Sodium channel modulator.
CAS RN 65731-84-2
CEE número 265-898-0
Número CIPAC 632
EPA américaine chimiques de code 109702
PubChem CID 6455379
Masa molecular (g mol-1) 416.3
PIN (Preferred Identification Name) reaction mixture comprising the enantiomeric pair rac-(R)-cyano(3-phenoxyphenyl)methyl (1S,3S)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate in ratio approximately 2:3 with the enantiomeric pair rac-(R)-cyano(3-phenoxyphenyl)methyl (1S,3R)-3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropane-1-carboxylate
Nombre IUPAC (R)-α-cyano-3-phenoxybenzyl (1S,3S)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate and (S)-α-cyano-3-phenoxybenzyl (1R,3R)-3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropanecarboxylate
Nombre CAS cyano(3-phenoxyphenyl)methyl 3-(2,2-dichloroethenyl)-2,2-dimethylcyclopropanecarboxylate
Otra información de estado -
Relevant Environmental Water Quality Standards UK Environment Agency non-statutory standard for the protection of aquatic life in freshwater and saltwater annual average 0.0002 ug/L, max acceptable conc 0.002 ug/L
UK statutory standard for water quality: ‘Good’ for fresh, transitional & saltwater: 0.1 ng/L as annual mean conc, 0.4 ng/L 95th percentile
Herbicide Resistance Classification (HRAC) No aplicable
Herbicide Resistance Classification (WSSA) No aplicable
Insecticide Resistance Classification (IRAC) 3
Fungicide Resistance Classification (FRAC) No aplicable
Examples of recorded resistance Musca domestica
Triatoma infestans
Estado físico White powder
Related substances & organisms

Formulaciones:
Propiedad Click here for information on the general product and branding information used on this site Valor
Example manufacturers & suppliers of products using this active now or historically
  • Bonide Products
  • Syngenta
  • NuFarm
Example products using this active
  • Cymbush 3E Insecticide
  • Siperin
  • Barricade
Estado de UK LERAP No UK approval for use as a pesticide under EC Regulation 1107/2009
Formulation and application details Usually supplied as an emulsifiable concentrate.


DESTINO AMBIENTAL

for beta-cypermethrin

Propiedad Click here for information on the parameters used to describe environmental fate on this site Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with fate data Interpretación Click here for information on the way in which we interpret environmental fate data
Solubilidad - En aqua en 20oC (mg l-1) 0.9 A5 Bajo
Solubilidad - en solventes organicos en 20oC (mg l-1) 14000 A5 - n-Heptano -
45000 A5 - Metanol -
26000 A5 - Octanol -
1000000 A5 - Acetato de etilo -
Punto de fusión (oC) 63 A5 -
Punto de ebullición (oC) 253 A5 - Se descompone -
El punto de degradación (oC) 253 A5 -
Punto de inflamación (oC) Not expected to self ignite; Not highly flammable A5 -
Octanol-aqua coeficiente de particiónat en pH 7, 20oC P 6.31 X 1005 Calculado -
Log P 5.8 A5 Alto
Masa densidad (g ml-1)/Peso específico 1.34 L3 -
Disociación constante (pKa) at 25oC n/d A5 -
Nota: Ninguna disociación
Presión de vapor en 20oC (mPa) 0.02 A5 Baja volatilidad
Constante de Henry a 25oC (Pa m3 mol-1) 9.1 X 10-08 A5 No volátil
Indice de potencial de lixiviación GUS Click here for a note on the limitations of the GUS index -1.52 Calculado Bajo posibilidad de lixiviación
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate Click here for a note on the limitations of the SCI-GROW index Valor 5.35 X 10-03 Calculado -
Nota Estimated concentrations of chemicals with Koc values greater than 9995 ml g-1 are beyond the scope of the regression data used in SCI-GROW development. If there are concerns for such chemicals, a higher tier groundwater exposure assessment should be considered, regardless of the concentration returned by SCI-GROW
Potencial para transportar de 'particle bound' Click here for a note on the limitations of the potential for particle bound transport index - Calculado Mediano
Maximum UV-vis absorption L mol-1 cm-1 Acidic: 204nm=44881, 277nm=714
Neutral: 203nm-61241
Basic: 208nm=39764, 310nm=2756
A5 -
Surface tension (mN m-1) - - -

Degradación:
Propiedad Click here for information on the parameters used to describe substance degradation Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with degradation data Interpretación Click here for information on the way in which we interpret substance degradation data
Biodegradabilidad general -
Degradación de suelo (días) (aerobic) DT50 (típico) 27.1 A5 No persistente
DT50 (laboratorio en 20oC) 27.1 A5 No persistente
DT50 (campo) - - -
DT90 (laboratorio en 20oC) - - -
DT90 (campo) - - -
Endpoint de modelado DT50 - - -
Nota EU dossier DT50 lab studies range 15.2-43.4 days days ; DT90 range 257-734 days
Dissipation rate RL50 on plant matrix Valor - - -
Nota -
Dissipation rate RL50 on and in plant matrix Valor 4.9 R4 -
Nota Published literature RL50 range 3.7-6.0 days, 2 field crops, various matrices, n=2
Acuoso fotólisis DT50 (días) en pH 7 Valor - - -
Nota -
Acuoso hidrólisis DT50 (días) en 20oC y pH 7 Valor - - -
Nota -
Aqua-Sedimento DT50 (días) 22.2 A5 Rápido
Fase de agua sola DT50 (días) - - -

De absorción del suelo y la movilidad:
Propiedad Click here for information on the parameters used to describe substance adsorption and mobility Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with adsorption and mobility data Interpretación Click here for information on the way in which we interpret substance adsorption and mobility
Lineal Kd - - -
Koc -
Notas y rango -
Freundlich Kf 1369 A5 No Móvil
Kfoc 114676
1/n 1.001
Notas y rango EU dossier Kf range 889-1622 mL/g, Kfoc range 41167-249607 mL/g, 1/n range 0.946-1.072, Soils=4
pH senbsibilidad No

Key metabolites:
Metabolito Medio de formación Maximó Calculado de Fracción Ocurrencia 1107/2009 Importancia Click here for further information on 1107/2009 relevancy
3-phenoxybenzoic acid This metabolite may cause environmental pollution, click here for further information Suelo   0.171   Major fraction; Relevant
3-(2,2-dichlorovinyl)-2,2-dimethylcyclopropane-carboxylate This metabolite may cause environmental pollution, click here for further information Suelo   0.271   Major fraction; Relevant

Other known metabolites:
Metabolite name and reference Aliases Medio de formación / Rate Maximó Calculado de Fracción Ocurrencia Metabolising enzymes
3-phenoxybenzaldehyde - Aqueous and soil photolysis - -
3-phenoxybenzylactetic acid - Aqueous photolysis - -
Phenol - Aqueous photolysis - -
Cyperamide - Aqueous and soil photolysis; Hydrolysis - -
alpha-carbamoyl-3-phenoxybenzyl-alcohol - Soil photolysis - -
2-OH-PBAcid - - - -
PBAlcohol - - - -
N-(3-phenoxybenzoyl)glycerine - - - -
N-(3-phenoxybenzoyl)glutamic acid - - - -
3-(4-hydroxyphenoxy)benzoic acid O-sulfate - - - -
taurine-PBA - Mouse - -


ECOTOXICOLOGÍA

for beta-cypermethrin

Propiedad Click here for information on the parameters used to describe substance ecotoxicology Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with ecotoxicology data Interpretación Click here for information on the way in which we interpret substance ecotoxicology
Factor de la bio-concentración BCF (l kg-1) 846 A5 Umbral de importancia
CT50 (días) 2.0 -
Mamíferos - Agudos oral LD50 (mg kg-1) 93.0 A5 Rata Alto
Mamíferos - a corto plazo NOEL (mg kg-1) - L3 Rata -
(ppm dieta) > 250 -
Pájaros/aves - Agudos LD50 (mg kg-1) > 2000 A5 Collinus virginians Bajo
Birds - Short term dietary (LC50/LD50) - - -
Pez - agudo 96 hora LC50 (mg l-1) 0.00039 A5 Oncorhynchus mykiss Alto
Pez - Crónico 21 días NOEC (mg l-1) 0.00037 A5 Pimephales promelas, 34 día Alto
Invertebrados acuáticos - Agudos 48 hora EC50 (mg l-1) 0.00042 A5 Daphnia magna Alto
Invertebrados acuáticos - Crónicos 21 días NOEC (mg l-1) - - -
Crustáceos acuáticos - Agudos 96 hora LC50 (mg l-1) 0.0000059 A5 Mysidopsis bahia Alto
Sediment dwelling organisms - Agudos 96 hora LC50 (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, estático, agua (mg l-1) - - -
Sediment dwelling organisms - Crónicos 28 día NOEC, sedimento (mg kg-1) 0.00006 A5 Chironomus riparius Alto
Plantas acuáticas - Agudos 7 día EC50, biomasa (mg l-1) - - -
Non-target plants - - -
- - -
Algas - Agudos 72 hora EC50, crecimiento (mg l-1) > 0.053 A5 Pseudokirchneriella subcapitata Moderado
Algas - Crónicos 96 hora NOEC, crecimiento (mg l-1) - - -
Abejas mielíferas (Apis spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.014 A5 Alto
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) 0.05 A5 Alto
Modo desconocido aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Abejorros (Bombus spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
-
Abejas albañiles (Osmia spp.) Contacto aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Oral aguda LD50 (peor caso de 24 , 48 y 72 hora valores - μg abeja-1) - - -
Otros polinizadores (1) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Otros polinizadores (2) Agudos LD50 (peor caso de 24 , 48 y 72 hora valores - μg insect-1) - - -
Modo de exposición -
Lombrices - Agudos 14 día LC50 (mg kg-1) > 150 A5 Eisenia foetida, corr Moderado
Lombrices - Crónicos NOEC, reproducción (mg kg-1) 0.243 A5 Eisenia foetida, corr Moderado
Other soil macro-organisms Agudos LC50 (mg kg-1) - - -
Crónicos NOEC (mg kg-1) - - -
Otro arthropoda (1) LR50 g ha-1 - - -
% Causalidad 100 Mortality,
Dose 12.5g ha-1
A5 Aphidius rhopalosiphi
-
Otro arthropoda (2) LR50 g ha-1 - - -
% Causalidad 100 Mortality,
Dose 12.5g ha-1
A5 Typhlodromus pyri
-
Soil micro-organisms Nitrogen mineralisation: No significant adverse effect
Carbon mineralisation: No significant adverse effect
A5
Dose: 0.67mg kg-1, 28días
-
Mesocosm study data NOEAEC mg l-1 - - -
NOEAEC mg l-1 - - -


LA SALUD HUMANA Y PROTECCIÓN

for beta-cypermethrin

General:
Propiedad Click here for information on the parameters used to describe human health and protection issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with human health and protection data Interpretación Click here for information on the way in which we interpret human health and protection data
Threshold of Toxicological Concern (Cramer Class) Click here for a note on the limitations of the Cramer class High (class III) - -
Mamíferos - Agudos oral LD50 (mg kg-1) 93.0 A5 Rata Alto
Mammals - Dermal LD50 (mg kg-1 body weight) > 5000 A5 Rat -
Mammals - Inhalation LC50 (mg l-1) 1.06 A5 Rat -
Other Mammal toxicity endpoints - -
Consumo cada día aceptable (mg kg-1p.c. días-1) 0.0016 A5 Dog, SF=300 -
ARfD - Acute Reference Dose (mg kg-1p.c. días-1) 0.0016 A5 Dog, SF=300 -
AAOEL - Acute Acceptable Operator Exposure Level (mg kg-1 bw day-1) - - -
El nivel de exposición del operador (AOEL) sistemíco (mg kg-1p.c. días-1) 0.0008 A5 Dog, SF=600 -
Estudios den la absorción cutánea (%) 5-7 A5 Concentration dependent -
Directivo 76/464 Sustancias Peligrosas - - -
Exposure Routes Public Risk from vapour exposure risk identified for bystanders in the vicinity
Occupational PPE/PPC required to reduce exposure risk
European MRLs Click here for the EU MRL pesticide database
Drinking Water Standards - - -
Drinking Water MAC (μg l-1) - - -

Health issues:
Carcinogen Genotóxico Endocrine disrupter Reproduction / development effects Cholinesterase inhibitor Neurotoxicant

A3; B3; C3; D0; E3

-

Respiratory tract irritant Skin irritant Skin sensitiser Eye irritant Phototoxicant

-

-

Cuestiones generales de la salud humana Risk of serious damage to the eye
Clave: Genotoxicidad
A: Aberración cromosómica (base de datos EFSA)
B: Daño/reparación del ADN (base de datos EFSA)
C: Mutación genética (base de datos EFSA)
D: Mutación del genoma (base de datos EFSA)
E: Tipo de genotoxicidad no especificada (fuente de datos diversos)
0: Sin datos
1: Positivo
2: Resultados mixtos/ambiguos
3: Negativo
Clave: Otro
: Sí, se sabe que causa un problema
: No, sabe no causar un problema
: Posiblemente, estado no identificado
- : Datos no encontrados

Handling issues:
Propiedad Click here for information on the parameters used to describe substance handling issues Valor Fuente/Cuenta de Cualidad/Otra Información Click here for information on the primary data sources used to populate this database with data on handling issues Interpretación Click here for information on the way in which we interpret data on handling issues
General Click here for a description of the International Maritime Dangerous Goods (IMDG) codes IMDG Transport class 6.1
Not explosive or oxidising
CLP classification 2013 Health: H301, H318, H332, H335
Environment: H410
CEE clasificación de riesgos Click here to view information omn the EU risk phrases T - Toxic: R25
Xn - Harmful: R20, R41
Xi - Irritant: R37
N - Dangerous for the environment: R50, R53
CEE clasificación sin riesgos Click here to view information omn the EU safety phrases S22, S26, S39, S60, S61
Clasificación de OSM NL - No inscripto en la lista
Número de las NU -
Waste disposal & packaging Click here for a description of UN packaging marks Packaging Group III (minor danger)


TRADUCCIONES

for beta-cypermethrin

Idioma Nombre
Inglés beta-cypermethrin
Francés betacypermethrine
Alemán beta-Cypermethrin
Danés betacypermethrin
Italiano beta-cipermetrina
Español beta-cipermetrina
Griego -
Esloveno beta-cipermetrin
Polaco beta-cypermetryna
Sueco -
Húngaro beta-cypermethrin
Holandés -

Última actualización del registro: Tuesday 03 March 2020
Contacto: aeru@herts.ac.uk