dithianon

ditianon (Ref: BAS 216F)
** dithianon ** IT 931 ** CME 107 ** Prevodi

Usoda v okolju - Ekotoksikologija - Cloveško zdravje - Abecedno kazalo - Domov

SPLOŠNE INFORMACIJE

Opis: A dicarbonitrile fungicide for control of scab and other foliar diseases excluding powdery mildew

Uvod: circa 1965

Direktive 1107/2009 (razveljavitvi 91/414): 0 cellpadding= 5 cellspacing= 1 width= 99% > valign= top bgcolor= #E2E2E2 > Status valign= top bgcolor= #E2E2E2 > Annex 1 valign= top bgcolor= #E2E2E2 > Dossier rapporteur/co-rapporteur valign= top bgcolor= #E2E2E2 > Greece valign= top bgcolor= #E2E2E2 > Date inclusion expires valign= top bgcolor= #E2E2E2 > 31/05/2021 > Odobreno za uporabo () or known to be used () v sledecih evropskih državah: 0 cellpadding= 5 cellspacing= 1 width= 99% > bgcolor= #E2E2E2 >

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> Also registered in: Avstralija

Osnovni status:

Vrsta fitofarmacevtskega sredstva Fungicid

Snov skupina Quinone

Snov izvora Sinteticni
Nacin delovanja Protectant with some curative activity

CAS RN 3347-22-6

EC številka 222-098-6

CIPAC številka 153

US EPA kemicni kodo 099201

Kemijska formula C₁₄H₄N₂O₂S₂

SMILES N#CC=1S\C2=C(/SC=1C#N)C(=O)c3c(C2=O)cccc3

International Chemical Identifier (InChI) InChI=1/C14H4N2O2S2/c15-5-9-10(6-16)20-14-12(18)8-4-2-1-3-7(8)11(17)13(14)19-9/h1-4H

Ali je strukturni diagram na voljo/slika? Da

Molekulska masa (g mol^-1) 296.32

IUPAC Ime 5,10-dihydro-5,10-dioxonaphtho[2,3-b]-1,4-dithiine-2,3-dicarbonitrile

CAS Ime 5,10-dihydro-5,10-dioxonaphtho[2,3-b]-1,4-dithiin-2,3-dicarbonitrile

Druge informacije -

Herbicide Resistance Classification (HRAC) Neprimeren

Insecticide Resistance Classification (IRAC) Neprimeren

Fungicide Resistance Classification (FRAC) M9

Fizikalno stanje Dark brown fibrous crystals

Related substances & organisms
piraklostrobin

Formulations:

Lastnost Vrednost
Example manufacturers of products using this active
BASF

Example products using this active
Dithianon Flowable
Dithianon WG
Delan 70WG

Status UK LERAP None

Formulation and application details Often supplied as a soluble concentrate or wettable granules that are mixed with water and applied as a spray.

USODA V OKOLJU

Lastnost		Vrednost	Vir / Stopnja kakovosti / Ostale informacije	Razlaga
Topnost - v vodi pri 20^oC (mg l^-1)		0.22	A5	Nizko
Topnost - V organskih topilih pri 20^oC (mg l^-1)		14700	A5 - Toluen	-
		22200	A5 - Aceton	-
		10600	A5 - Etilacetat	-
		8.77	A5 - Heksan	-
Tališce (^oC)		215	A5	-
Vrelišce (^oC)		-	-	-
Razgradnja point (^oC)		222	A5	-
Plamenišce (^oC)		Not highly flammable	A5	-
Koeficient porazdelitve oktanol-voda (log P) pri pH7, 20oC	P	1.58 X 10⁰³	Izracunano	-
Koeficient porazdelitve oktanol-voda (log P) pri pH7, 20oC	Log P	3.2	A4 - @ pH 2.0	Visoko
Volumska gostota (g ml^-1) / Specificna teža		1.58	L3	-
Konstanta disociacije (pKa) pri 25^oC		Neprimeren	A5	-
Konstanta disociacije (pKa) pri 25^oC		Opomba: Brez disociacije
Pritisk pare pri 25^oC (mPa)		1.0 X 10^-07	A3	Nehlapen
Henrijeva konstanta pri 25^oC (Pa m³ mol^-1)		1.347 X 10^-07	A4	Nehlapen
Henrijeva konstanta pri 20^oC (dimensionless)		1.00 X 10^-09	K3	Nehlapen
GUS potencialni indeks izpiranja		0.45	Izracunano	Nizko izpiranje
Model za podtalnico SCI-GROW (µg l^-1) za 1 kg ha^-1 or 1 l ha^-1 odmerek	Vrednost	8.09 X 10^-03	Izracunano	-
	Opomba	-
Potencial za prenos vezanih delcev		-	Izracunano	Srednje
Maximum UV-vis absorption L mol^-1 cm^-1		In CH3CN: 199nm = 35932, 233nm = 20542, 330nm = 5083, 290.5nm = 6535; [pH 1.3: 199nm = 18102, 237nm = 15110, 342nm = 4489, 290.5nm = 5100; [pH 6.9: 199nm = 22380, 250nm = 15110, 350nm = 7204, 290.5nm = 8724	A5	-
Surface tension (mN m^-1)		72.7	A5 at 20^oC	-

Razgradnja:

Lastnost Vrednost Vir / Stopnja kakovosti / Ostale informacije Razlaga

Razgradnja v tleh (dnevi) (aerobic) DT50 (znacilno) 10.5 A5 Neobstojen

DT50 (v laboratoriju pri 20^oC) 10.5 A5 Neobstojen

DT50 (polje) 35 Y4 Zmerno obstojen

DT90 (v laboratoriju pri 20^oC) 69.2 A5 -

DT90 (polje) - - -

Opomba EU dossier lab studies DT50 range 2.6-33.3 days, DT90 range 8.5-135 days

Fotoliza v vodi DT50 (dni) pri pH 7 Vrednost 0.01 A5 Hiter

Opomba -

Hidroliza v vodi DT50 (dni) pri 20^oC in pH 7 Vrednost 0.6 A5 Neobstojen

Opomba pH sensitive: DT50 10.7 days at pH 5, 9.8 minutes at pH 9 all at 20 degC

Vodni sediment DT50 (dni) 0.05 A4 Hiter

Vodna faza samo DT50 (dni) 0.05 A4 Hiter

Tla adsorpcija in mobilnosti:

Lastnost Vrednost Vir / Stopnja kakovosti / Ostale informacije Razlaga

Linear K_d 86.4 - Nekoliko mobilen

K_oc 3627

Opombe in obseg EU dossier Kd range 9-157 mL/g, Koc range 1167-6004 mL/g, Soils=5

Freundlich K_f - - -

K_foc -

¹/_n -

Opombe in obseg -

pH obcutljivost Not stable under wet conditions pH > 4

Other known metabolites:

Metabolite name and reference Aliases Srednja Formacija / Rate Ocenjen Delež Maksimalne Pojav Metabolising Enzymes

2-amino-1,4-naphthoquinone dithianon metabolite D33 Rat (Faeces) - -

phthalic acid - Soil (Photolysis, Anaerobic); Plant - -

phthadialdehdye - Water (Hydrolysis, Photolysis) - -

1,2-benzenedimethanol - Water (Hydrolysis, Photolysis) - -

- - - - -

- - - - -

(Ref: CL 1017911) - Water (Hydrolysis) - -

(Ref: CL 1025) dithianon metabolite D2 Soil (Anaerobic) - -

(Ref: CL 153880) dithianon metabolite D5 Soil (Anaerobic) 0.046 -

(Ref: CL 231509) - Plant - -

4,9-dioxo-4,9-dihydronaphtho(2,3-b)thiophene-2,3-dicarbonitrile
(Ref: CL 902198) dithianon metabolite D8 a = Rat (Faeces); b = Soil (Aerobic) b=0.039 -

(Ref: CL 902200) dithianon metabolite D15 Soil (Anaerobic); Plant - -

EKOTOKSIKOLOGIJA

Lastnost		Vrednost	Vir / Stopnja kakovosti / Ostale informacije	Razlaga
Faktor biokoncentracije	BCF	27	A5 Cela riba	Nizek potencial
Faktor biokoncentracije	CT₅₀ (dnevi)	1	A5 Cela riba	-
Potencial bioakumulacije		-	Izracunano	Nizko
Sesalci - oralno akutno LD₅₀ (mg kg^-1)		300	A5 Podgana	Srednji
Sesalci - kratek izraz NOEL	(mg kg^-1)	-	L2 Podgana, 2 leto	-
Sesalci - kratek izraz NOEL	(ppm dieta)	20	L2 Podgana, 2 leto	-
Ptici - Akutno LD₅₀ (mg kg^-1)		309	A5 Colinus virginianus	Srednji
Birds - Short term dietary (LC₅₀/LD₅₀)		> 1198.5 mg kg^-1 bw/dan	A5 Colinus virginianus	-
Ribe - Akutno 96 ura LC₅₀ (mg l^-1)		0.07	A5 Oncorhynchus mykiss	Visoko
Ribe - Kronicno 21 dni NOEC (mg l^-1)		0.02	A5 Oncorhynchus mykiss	-
Vodni nevretencarji - Akutno 48 ura EC₅₀ (mg l^-1)		0.26	A5 Daphnia magna	Srednji
Vodni nevretencarji - Kronicno 21 dni NOEC (mg l^-1)		0.05	A5 Daphnia magna	-
Vodnih rakov - Acute 96 ura LC₅₀ (mg l^-1)		-	-	-
Sediment dwelling organisms - Acute 96 ura LC₅₀ (mg l^-1)		> 0.5	A5 Chironomus riparius	Srednji
Sediment dwelling organisms - Kronicni 28 dan NOEC, static, voda (mg l^-1)		> 0.125	A5 Chironomus riparius	Srednji
Sediment dwelling organisms - Kronicni 28 dan NOEC, sediment (mg kg^-1)		-	-	-
Vodne rastline - Akutno 7 dni EC₅₀, biomasa (mg l^-1)		-	-	-
Alge - Akutno 72 ura EC₅₀, rast (mg l^-1)		0.09	A5 Pseudokirchneriella subcapitata	Srednji
Alge - Kronicno 96 ura NOEC, rast (mg l^-1)		0.025	A5 Pseudokirchneriella subcapitata	Srednji
Cebele - Acute 48 ura - LD₅₀ (µg za cebele^-1)		> 25.4	A5 Usten	Srednji
Deževniki - Akutno 14 dan LC₅₀ (mg kg^-1)		578	A5 Eisenia foetida	Srednji
Deževniki - Kronicno 14 dan NOEC, razmnoževanje (mg kg^-1)		22.3	A5 Eisenia foetida	Srednji
Other soil macro-organisms - e.g. Collembola	LR₅₀product ha EC₅₀product ha NOECproduct ha % Ucinek	-	-	-
Ostali clenonožci (1)	LR₅₀ g ha^-1	4200	48 ura A5 Aphidius rhopalosiphi	Neškodljivo pri 1 kg ha^-1
Ostali clenonožci (1)	% Ucinek	-	-	-
Ostali clenonožci (2)	LR₅₀ g ha^-1	4200	7 dan A5 Typhlodromus pyri	Neškodljivo pri 1 kg ha^-1
Ostali clenonožci (2)	% Ucinek	-	-	-
Talni mikroorganizmi		Mineralizacija dušika: Brez pomembnejšega ucinka Mineralizacija ogljika: Brez pomembnejšega ucinka	A5 Dose: 14 kg/ha, 28 days	-
Mesocosm study data	NOEAEC mg l^-1	0.004	A5 Fish	-
Mesocosm study data	NOEAEC mg l^-1	-	-	-

CLOVEŠKO ZDRAVJE IN ZAŠCITA

Splošno:

Lastnost Vrednost Vir / Stopnja kakovosti / Ostale informacije Razlaga

Sesalci - oralno akutno LD₅₀ (mg kg^-1) 300 A5 Podgana Srednji

Mammals - Dermal LD50 (mg kg^-1 body weight) > 2000 A5 Rat -

Mammals - Inhalation LC50 (mg l^-1) 0.31 A5 Rat -

Other Mammal toxicity endpoints - -

ADI - Sprejemljiv dnevni vnos (mg kg^-1bw dan^-1) 0.01 A5 Rat, SF=100 -

ARfD - Referenca akutnega odmerka (mg kg^-1bw dan^-1) 0.12 A5 Rat, SF=100 -

AOEL - Sprejemljiva stopnja izpostavljenosti - Sistemski (mg kg^-1) 0.0135 A5 Dog, SF=100 -

Dermalne študije (%) 0.26-3.1 A5 concentration dependant -

Direktiva o nevarnih snoveh 76/464 - - -

Meje izpostavljenosti - - -

Exposure Routes Public [No unacceptable risks to bystanders identified]

Occupational [Possible risk to operators identified even with PPE], [Minimal risk to other workers with PPE]

Primeri evropskih MRL (mejnih vrednosti ostankov FFS) (mg kg^-1) Vrednost Pome fruits and grapes: 3.0
Opomba [A5 EU dossier proposals]
For the EU pesticides database click here

MAC - najvišja, še sprejemljiva koncentracija v pitni vodi (µg l^-1) 0.1 EU Dir 89/778/EC limit; A5 -

Vprašanja zdravje:

Rakotvorna Mutagena Endokrini disruptor Reproduction / development effects Acetyl cholinesterase inhibitor Neurotoxicant Respiratory tract irritant Skin irritant Eye irritant

-

-

-

Vprašanja vezana na zdravje cloveka [Skin sensitiser], [Toxic], [Possible liver and kidney toxicant], [May cause nausea, vomiting and diarrhea if ingested]

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data

:

Lastnost Vrednost Vir / Stopnja kakovosti / Ostale informacije Razlaga

General [Not explosive or oxidising], [IMDG Transport Code is usually 6.1 or 9]

EC Klasifikacija Tveganja [Carcinogen category 3: R40], [T - Toxic: R23], [Xn - Harmful: R22, R41], [Xi - Irritant: R43, R66], [N - Dangerous for the environment: R50, R53]

EC Klasifikacija Varnosti S2, S13, S36/37/39, S45

WHO klasifikacija II - Zmerno nevaren

US EPA Classification (formulation) III - Pozor - Rahlo toksicno

UN Številka Variable with product, usually 3077 or 3082

Waste disposal & packaging [Usually Packaging Group III (minor danger)]

PREVODI

Jezik	Ime
Anglešcina	dithianon
Francošcina	dithianon
Nemšcina	Dithianon
Danšcina	dithianon
Italijanšcina	ditianon
Španšcina	ditianona
Gršcina	dithianon
Slovenšcina	ditianon
Poljšcina	ditianon
Švedšcina	ditianon
Madžaršcina	ditianon
Nizozemšcina	dithianon

Zadnja posodobitev: petek 4. november 2011
Kontakt: aeru@herts.ac.uk

Vrsta fitofarmacevtskega sredstva	Fungicid
Snov skupina	Quinone
Snov izvora	Sinteticni
Nacin delovanja	Protectant with some curative activity
CAS RN	3347-22-6
EC številka	222-098-6
CIPAC številka	153
US EPA kemicni kodo	099201
Kemijska formula	C₁₄H₄N₂O₂S₂
SMILES	N#CC=1S\C2=C(/SC=1C#N)C(=O)c3c(C2=O)cccc3
International Chemical Identifier (InChI)	InChI=1/C14H4N2O2S2/c15-5-9-10(6-16)20-14-12(18)8-4-2-1-3-7(8)11(17)13(14)19-9/h1-4H
Ali je strukturni diagram na voljo/slika?	Da
Molekulska masa (g mol^-1)	296.32
IUPAC Ime	5,10-dihydro-5,10-dioxonaphtho[2,3-b]-1,4-dithiine-2,3-dicarbonitrile
CAS Ime	5,10-dihydro-5,10-dioxonaphtho[2,3-b]-1,4-dithiin-2,3-dicarbonitrile
Druge informacije	-
Herbicide Resistance Classification (HRAC)	Neprimeren
Insecticide Resistance Classification (IRAC)	Neprimeren
Fungicide Resistance Classification (FRAC)	M9
Fizikalno stanje	Dark brown fibrous crystals
Related substances & organisms	piraklostrobin

Lastnost	Vrednost
Example manufacturers of products using this active	BASF
Example products using this active	Dithianon Flowable Dithianon WG Delan 70WG
Status UK LERAP	None
Formulation and application details	Often supplied as a soluble concentrate or wettable granules that are mixed with water and applied as a spray.

Metabolite name and reference	Aliases	Srednja Formacija / Rate	Ocenjen Delež Maksimalne Pojav	Metabolising Enzymes
2-amino-1,4-naphthoquinone	dithianon metabolite D33	Rat (Faeces)	-	-
phthalic acid	-	Soil (Photolysis, Anaerobic); Plant	-	-
phthadialdehdye	-	Water (Hydrolysis, Photolysis)	-	-
1,2-benzenedimethanol	-	Water (Hydrolysis, Photolysis)	-	-
-	-	-	-	-
-	-	-	-	-
(Ref: CL 1017911)	-	Water (Hydrolysis)	-	-
(Ref: CL 1025)	dithianon metabolite D2	Soil (Anaerobic)	-	-
(Ref: CL 153880)	dithianon metabolite D5	Soil (Anaerobic)	0.046	-
(Ref: CL 231509)	-	Plant	-	-
4,9-dioxo-4,9-dihydronaphtho(2,3-b)thiophene-2,3-dicarbonitrile (Ref: CL 902198)	dithianon metabolite D8	a = Rat (Faeces); b = Soil (Aerobic)	b=0.039	-
(Ref: CL 902200)	dithianon metabolite D15	Soil (Anaerobic); Plant	-	-

Rakotvorna	Mutagena	Endokrini disruptor	Reproduction / development effects	Acetyl cholinesterase inhibitor	Neurotoxicant	Respiratory tract irritant	Skin irritant	Eye irritant
	-	-				-
Vprašanja vezana na zdravje cloveka		[Skin sensitiser], [Toxic], [Possible liver and kidney toxicant], [May cause nausea, vomiting and diarrhea if ingested]