benzoximate ** benzomate ** Translations

Environmental Fate - Ecotoxicology - Human Health

GENERAL INFORMATION

Description: An obsolete acaricide once used particularly to control spider mites on fruit and ornamentals

Introduction: 1971, Japan

EC Directive 1107/2009 (repealing 91/414):

Status	Excluded from Annex 1
Dossier rapporteur/co-rapporteur	-
Date inclusion expires	Expired

Approved for use () or known to be used () in the following European countries:

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

General status:

Pesticide type	Acaricide, Miticide
Substance group	Bridged diphenyl
Substance origin	Synthetic
Mode of action	Non-systemic with contact and stomach action
CAS RN	29104-30-1
EC number	249-439-1
CIPAC number	377
US EPA chemical code	-
Chemical formula	C18H18ClNO5
SMILES	Clc1ccc(OC)c(c1OC)C(=N\OCC)\OC(=O)c2ccccc2
International Chemical Identifier (InChI)	InChI=1/C18H18ClNO5/c1-4-20(25-18(22)12-8-6-5-7-9-12)17(21)15-14(23-2)11-10-13(19)16(15)24-3/h5-11H,4H2,1-3H3
Structure diagram/image available?	Yes
Molecular mass (g mol-1)	363.79
IUPAC Name	3-chloro-α-(EZ)-ethoxyimino-2,6-dimethoxybenzyl benzoate
CAS Name	benzoic acid anhydride with 3-chloro-N-ethoxy-2,6-dimethoxybenzenecarboximidic acid
Other status information	-
Herbicide Resistance Classification (HRAC)	Not applicable
Insecticide Resistance Classification (IRAC)	Not known
Fungicide Resistance Classification (FRAC)	Not applicable
Physical state	Colourless crystals
Related substances & organisms	-

Formulations:

Property	Value
Example manufacturers of products using this active	Nippon
Example products using this active	Azomate Acaramate Artaban
UK LERAP status	No UK approval for use or outside scope
Formulation and application details	-

ENVIRONMENTAL FATE

Property		Value	Source/Quality Score/Other Information	Interpretation
Solubility - In water at 20oC (mg l-1)		30	L3	Low
Solubility - In organic solvents at 20oC (mg l-1)		710000	L3 - Xylene	-
		650000	L3 - Benzene	-
		80000	L3 - Hexane	-
Melting Point (oC)		73	L3	-
Boiling Point (oC)		Decomposes before boiling	L3	-
Degradation point (oC)		-	-	-
Flashpoint (oC)		Not highly flammable	L3	-
Octanol-water partition coefficient at pH 7, 20oC	P	2.51 X 1002	Calculated	-
	Log P	2.4	L3	Low
Bulk density (g ml-1)/Specific gravity		1.3	L3	-
Dissociation constant (pKa) at 25oC		Not applicable	Q3	-
		Note: No dissociation
Vapour pressure at 25oC (mPa)		0.45	L3	Non-volatile
Henry's law constant at 25oC (Pa m3 mol-1)		5.46 X 10-03	L3	Non-volatile
Henry's law constant at 20oC (dimensionless)		2.24 X 10-06	Calculated	Moderately volatile
GUS leaching potential index		-	-	-
SCI-GROW groundwater index (µg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate	Value	-	-	-
	Note	-
Potential for particle bound transport index		-	-	-
Maximum UV-vis absorption L mol-1 cm-1		-	-	-
Surface tension (mN m-1)		-	-	-

Degradation:

Property		Value	Source/Quality Score/Other Information	Interpretation
Soil degradation (days) (aerobic)	DT50 (typical)	-	-	-
	DT50 (lab at 20oC)	-	-	-
	DT50 (field)	-	-	-
	DT90 (lab at 20oC)	-	-	-
	DT90 (field)	-	-	-
	Note:	-
Aqueous photolysis DT50 (days) at pH 7	Value	-	-	-
	Note	-
Aqueous hydrolysis DT50 (days) at 20oC and pH 7	Value	Stable	W4	Very persistent
	Note	-
Water-Sediment DT50 (days)		-	-	-
Water phase only DT50 (days)		-	-	-

Soil adsorption and mobility:

Property		Value	Source/Quality Score/Other Information	Interpretation
Linear	Kd	-	-	-
	Koc	-
	Notes and range	-
Freundlich	Kf	-	-	-
	Kfoc	-
	1/n	-
	Notes and range	-
pH sensitivity		-

ECOTOXICOLOGY

Property		Value	Source/Quality Score/Other Information	Interpretation
Bio-concentration factor	BCF	-	-	-
	CT50 (days)	-		-
Bioaccumulation potential		-	Calculated	Low
Mammals - Acute oral LD50 (mg kg-1)		> 5000	L3 Rat	Low
Mammals - Short term dietary NOEL	(mg kg-1)	-	L2 Rat, 2 year	-
	(ppm diet)	400		-
Birds - Acute LD50 (mg kg-1)		-	-	-
Birds - Short term dietary (LC50/LD50)		-	-	-
Fish - Acute 96 hour LC50 (mg l-1)		1.75	L3 Salmonidae	Moderate
Fish - Chronic 21 day NOEC (mg l-1)		-	-	-
Aquatic invertebrates - Acute 48 hour EC50 (mg l-1)		-	-	-
Aquatic invertebrates - Chronic 21 day NOEC (mg l-1)		-	-	-
Aquatic crustaceans - Acute 96 hour LC50 (mg l-1)		-	-	-
Sediment dwelling organisms - Acute 96 hour LC50 (mg l-1)		-	-	-
Sediment dwelling organisms - Chronic 28 day NOEC, static, water (mg l-1)		-	-	-
Sediment dwelling organisms - Chronic 28 day NOEC, sediment (mg kg-1)		-	-	-
Aquatic plants - Acute 7 day EC50, biomass (mg l-1)		-	-	-
Algae - Acute 72 hour EC50, growth (mg l-1)		-	-	-
Algae - Chronic 96 hour NOEC, growth (mg l-1)		-	-	-
Honeybees - Acute 48 hour LD50 (µg bee-1)		-	-	-
Earthworms - Acute 14 day LC50 (mg kg-1)		-	-	-
Earthworms - Chronic 14 day NOEC, reproduction (mg kg-1)		-	-	-
Other soil macro-organisms - e.g. Collembola	LR50product ha EC50product ha NOECproduct ha % Effect	-	-	-
Other arthropod (1)	LR50 g ha-1	Moderately harmful	Moderately harmfulAB1 Typhlodromus pyri	Moderately harmful
	% Effect	-	-	-
Other arthropod (2)	LR50 g ha-1	-	-	-
	% Effect	-	-	-
Soil micro-organisms		-	-	-
Mesocosm study data	NOEAEC mg l-1	-	-	-
	NOEAEC mg l-1	-	-	-

HUMAN HEALTH AND PROTECTION

General:

Property		Value	Source/Quality Score/Other Information	Interpretation
Mammals - Acute oral LD50 (mg kg-1)		> 5000	L3 Rat	Low
Mammals - Dermal LD50 (mg kg-1 body weight)		> 15000	L3 Rat	-
Mammals - Inhalation LC50 (mg l-1)		-	-	-
Other Mammal toxicity endpoints		-		-
ADI - Acceptable Daily Intake (mg kg-1bw day-1)		-	-	-
ARfD - Acute Reference Dose (mg kg-1bw day-1)		-	-	-
AOEL - Acceptable Operator Exposure Level - Systemic (mg kg-1bw day-1)		-	-	-
Dermal penetration studies (%)		-	-	-
Dangerous Substances Directive 76/464		-	-	-
Exposure Limits		-	-	-
Exposure Routes	Public	-
	Occupational	-
Examples of European MRLs (mg kg-1)	Value	-
	Note	For the EU pesticides database click here
Drinking Water MAC (µg l-1)		-	-	-

Health issues:

Carcinogen	Mutagen	Endocrine disrupter	Reproduction / development effects	Acetyl cholinesterase inhibitor	Neurotoxicant	Respiratory tract irritant	Skin irritant	Eye irritant
-	-	-	-		-	-
General human health issues		[No further information available]

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data

Handling issues:

Property		Value	Source/Quality Score/Other Information	Interpretation
General		[No information available]
EC Risk Classification		-
EC Safety Classification		-
WHO Classification		O	-	Obsolete substance
US EPA Classification (formulation)		IV	-	Caution - Not acutely toxic
UN Number		-
Waste disposal & packaging		-

TRANSLATIONS