1-decanol

1-decanol	Last updated: 12/01/2021
(Also known as: decyl alcohol; capric alcohol; n-decyl alcohol; 1-hydroxydecane; n-decanol)

GENERAL INFORMATION

Description

Used as a plant growth regulator mainly on tobacco plants but is also has other uses as a solvent and surfactant

Example pests controlled

Shoot development

Example applications

Tobacco

Efficacy & activity

Availability status

Current

Introduction & key dates

UK regulatory status

UK COPR regulatory status

Not approved

Date COPR inclusion expires

Not applicable

UK LERAP status

Not applicable

EC Regulation 1107/2009 (repealing 91/414)

EC Directive 1107/2009 status

Approved

Dossier rapporteur/co-rapporteur

Poland/Italy

Date EC 1107/2009 inclusion expires

31/05/2021

EU Candidate for substitution (CfS)

Listed in EU database

Yes

Approved for use (✓) under EC 1107/2009 in the following EU Member States

ATAustria	BEBelgium	BGBulgaria	CYCyprus	CZCzech Republic	DEGermany	DKDenmark	EEEstonia	ELGreece
	✓				✓			✓
ESSpain	FIFinland	FRFrance	HRCroatia	HUHungary	IEIreland	ITItaly	LTLithuania	LULuxembourg
✓		✓	✓	✓		✓
LVLatvia	MTMalta	NLNetherlands	PLPoland	PTPortugal	RORomania	SESweden	SISlovenia	SKSlovakia
			✓	✓

Also used in

USA; Japan; Australia

Chemical structure

Isomerism

None

Chemical formula

C₁₀H₂₂O

Canonical SMILES

CCCCCCCCCCO

Isomeric SMILES

No data

International Chemical Identifier key (InChIKey)

MWKFXSUHUHTGQN-UHFFFAOYSA-N

International Chemical Identifier (InChI)

InChI=1S/C10H22O/c1-2-3-4-5-6-7-8-9-10-11/h11H,2-10H2,1H3

2D structure diagram/image available?

Yes

Cambridge Crystallographic Data Centre diagrams

Common Name	Relationship	Link
1-decanol	-

General status

Pesticide type

Plant growth regulator, Wood preservative

Other constituent type

Solvent, Surfactant

Substance group

Unclassified

Minimum active substance purity

960 g kg⁻¹

Known relevant impurities

EU dossier - none declared

Substance origin

Natural

Mode of action

As a biocontral agent it functions as an insect attractant

CAS RN

112-30-1

EC number

203-956-9

CIPAC number

831

US EPA chemical code

079038

PubChem CID

8174

Molecular mass

158.28

PIN (Preferred Identification Name)

IUPAC name

decan-1-ol

CAS name

1-decanol

Other status information

Potential marine pollutant

Relevant Environmental Water Quality Standards

Herbicide Resistance Classification (HRAC)

None allocated

Herbicide Resistance Classification (WSSA)

None allocated

Insecticide Resistance Classification (IRAC)

None allocated

Fungicide Resistance Classification (FRAC)

None allocated

Examples of recorded resistance

None identified

Physical state

Colourless, viscous liquid

Formulations

Property

Value

Example manufacturers & suppliers of products using this active now or historically

Antac 79
Royaltac
Sucker-Plucker: Off-Shoot

Example products using this active

Chemtura
Drexel Chemical Company

Formulation and application details

Usually supplied as an aqueous spray

ENVIRONMENTAL FATE

Property

Value

Source; quality score; and other information

Interpretation

Solubility - In water at 20 °C (mg l⁻¹)

9.75

Low

Solubility - In organic solvents at 20 °C (mg l⁻¹)

250000

n-Heptane

250000

Xylene

250000

Methanol

250000

Acetone

Melting point (°C)

6.66

Boiling point (°C)

231.4

Degradation point (°C)

Above 400

Flashpoint (°C)

110

Octanol-water partition coefficient at pH 7, 20 °C

1.30 X 10⁰⁴

Calculated

Log P

4.115

at 22 °C

High

Bulk density (g ml⁻¹)

0.830

Dissociation constant pKa) at 25 °C

15.21

Vapour pressure at 20 °C (mPa)

1387

Highly volatile

Henry's law constant at 25 °C (Pa m³ mol⁻¹)

22.52

Moderately volatile

Maximum UV-vis absorption L mol⁻¹ cm⁻¹

Neutral solution: 192nm = 26.3
Acidic solution: 197nm = 6.66
Basic solution: 192nm = 21.3

Surface tension (mN m⁻¹)

30.2

at 20 °C undiluted

Degradation

Property

Value

Source; quality score; and other information

Interpretation

General biodegradability

Soil degradation (days) (aerobic)

DT₅₀ (typical)

DT₅₀ (lab at 20 °C)

DT₅₀ (field)

DT₉₀ (lab at 20 °C)

DT₉₀ (field)

DT₅₀ modelling endpoint

Note

Literature reports rapid degradation in the soil

Dissipation rate RL₅₀ on plant matrix

Value

Note

Dissipation rate RL₅₀ on and in plant matrix

Value

Note

Aqueous photolysis DT₅₀ (days) at pH 7

Value

Note

Aqueous hydrolysis DT₅₀ (days) at 20 °C and pH 7

Value

Stable

Note

Considered stable under environmental conditions

Water-sediment DT₅₀ (days)

Water phase only DT₅₀ (days)

Soil adsorption and mobility

Property

Value

Source; quality score; and other information

Interpretation

Linear

K_d

K_oc

Notes and range

Freundlich

K_f

K_foc

¹/_n

Notes and range

pH sensitivity

Fate indices

Property

Value

Source; quality score; and other information

Interpretation

GUS leaching potential index

SCI-GROW groundwater index (μg l⁻¹) for a 1 kg ha⁻¹ or 1 l ha⁻¹ application rate

Value

Cannot be calculated

Note

Potential for particle bound transport index

Potential for loss via drain flow

ECOTOXICOLOGY

Property

Value

Source; quality score; and other information

Interpretation

Bio-concentration factor

BCF (l kg⁻¹)

CT₅₀ (days)

Mammals - Acute oral LD₅₀ (mg kg⁻¹)

> 5000

Rat

Low

Mammals - Short term dietary NOEL

(mg kg⁻¹)

(ppm diet)

Mammals - Chronic 21d NOAEL (mg kg⁻¹ bw d⁻¹)

Birds - Acute LD₅₀ (mg kg⁻¹)

> 4640

Anas platyrhynchos

Low

Birds - Short term dietary (LC₅₀/LD₅₀)

> 10000 mg kg feed⁻¹

Anas platyrhynchos

Birds - Chronic 21d NOEL (mg kg⁻¹ bw d⁻¹)

Fish - Acute 96 hour LC₅₀ (mg l⁻¹)

2.4

Pimephales promelas

Moderate

Fish - Chronic 21 day NOEC (mg l⁻¹)

0.0064

Oncorhynchus mykiss

High

Aquatic invertebrates - Acute 48 hour EC₅₀ (mg l⁻¹)

1.8

Daphnia magna

Moderate

Aquatic invertebrates - Chronic 21 day NOEC (mg l⁻¹)

0.51

Daphnia magna

Moderate

Aquatic crustaceans - Acute 96 hour LC₅₀ (mg l⁻¹)

Sediment dwelling organisms - Acute 96 hour LC₅₀ (mg l⁻¹)

Sediment dwelling organisms - Chronic 28 day NOEC, static, water (mg l⁻¹)

Sediment dwelling organisms - Chronic 28 day NOEC, sediment (mg kg⁻¹)

Aquatic plants - Acute 7 day EC₅₀, biomass (mg l⁻¹)

6.96

Lemna gibba

Moderate

Non-target plants

Algae - Acute 72 hour EC₅₀, growth (mg l⁻¹)

1.57

Pseudokirchneriella subcapitata

Moderate

Algae - Chronic 96 hour NOEC, growth (mg l⁻¹)

Honeybees (Apis spp.)

Contact acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

> 13.8

Moderate

Oral acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

Unknown mode acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

Bumblebees (Bombus spp.)

Contact acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

Oral acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

Mason bees (Osmia spp.)

Contact acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

Oral acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg bee⁻¹)

Other pollinators (1)

Acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg insect⁻¹)

Mode of exposure

Other pollinators (2)

Acute LD₅₀ (worst case from 24, 48 and 72 hour values - μg insect⁻¹)

Mode of exposure

Earthworms - Acute 14 day LC₅₀ (mg kg⁻¹)

> 627.6

Eisenia foetida

Moderate

Earthworms - Chronic NOEC, reproduction (mg kg⁻¹)

Other soil macro-organisms

Acute LC₅₀ (mg kg⁻¹)

Chronic NOEC (mg kg⁻¹)

Other arthropod (1)

LR₅₀ g ha⁻¹

0.621

Aphidius rhopalosiphi

% Effect

Other arthropod (2)

LR₅₀ g ha⁻¹

2.62

Typhlodromus pyri

% Effect

Soil micro-organisms

Mesocosm study data

NOEAEC mg l⁻¹

HUMAN HEALTH AND PROTECTION

General

Property

Value

Source; quality score; and other information

Interpretation

Threshold of Toxicological Concern (Cramer Class)

Low (class I)

Mammals - Acute oral LD₅₀ (mg kg⁻¹)

> 5000

Rat

Low

Mammals - Dermal LD₅₀ (mg kg⁻¹ body weight)

5000

Rat

Mammals - Inhalation LC₅₀ (mg l⁻¹)

> 2.05

Rat 4 hr (nose only)

Other Mammal toxicity endpoints

ADI - Acceptable Daily Intake (mg kg⁻¹ bw day⁻¹)

None allocated

ARfD - Acute Reference Dose (mg kg⁻¹ bw day⁻¹)

None allocated

AAOEL - Acute Acceptable Operator Exposure Level (mg kg⁻¹ bw day⁻¹)

AOEL - Acceptable Operator Exposure Level - Systemic (mg kg⁻¹ bw day⁻¹)

Rat SF=100

Dermal penetration studies (%)

100

default

Dangerous Substances Directive 76/464

Exposure Routes

Public

Acceptable risk levels for prescribed uses

Occupational

Some risk identified - PPE/PPC advised

European MRLs

EU MRL pesticide database

Drinking Water Standards

Drinking Water MAC (μg l⁻¹)

Health issues

Specific human health issues

Carcinogen

Genotoxic

Endocrine disruptor

; ; ; ;

Reproduction / development effects

Acetyl cholinesterase inhibitor

Neurotoxicant

No data found

Respiratory tract irritant

Skin irritant

Skin sensitiser

Eye irritant

Phototoxicant

No data found

General human health issues

Inhalation & ingestion may be harmful
Nausea, vomiting & diarrhea may follow ingestion.

Handling issues

Property

Value and interpretation

General

Not explosive or oxidising
Combustible liquid & vapour - use water spray, carbon dioxide, alcohol-resistant foam or dry powder for fire fighting.
IMDG Transport Code is usually 9

CLP classification 2013

Health: H319
Environment: H411, H412

EC Risk Classification

Xi - Irritant: R36/38
N - Dangerous for the environment: R51/53

EC Safety Classification

S26, S61

WHO Classification

NL (Not listed)

UN Number

Waste disposal & packaging

Packaging Group III (minor danger)

TRANSLATIONS

Language

Name

English

1-decanol

French

German

Danish

Italian

Spanish

Greek

Polish

Swedish

Hungarian

Dutch

Record last updated:	12/01/2021
Contact:	aeru@herts.ac.uk
Please cite as:	Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242