Anilazine (Ref: ENT 26 058) |
![]() Last updated: 29/12/2020 |
![]() |
(Also known as: NCI-C08684; triasyn; anivaline; zinochlor ; dyrene; B-622) |
SUMMARY |
Anilazine is a fungicide that no longer has approval for use in the EU. It has a low aqueous solubility, volatile and presents a low risk of leaching to groundwater. Whilst it is not highly toxic to humans there are some concerns regarding its potential to bioaccumulate. It is highly toxic to fish and moderately toxic to most other aquatic organisms, birds, honeybees and earthworms. |
|
![]() |
|
An obsolete fungicide once used to control various fungal pathogens including blights and Botrytis on fruit and other crops | |
---|---|---|
|
Late blights; Leaf spots; Anthracnose; Downy mildew; Botrytis; Alternaria | |
|
Fruit including blackberry, cranberry, raspberry, blueberry and melon; Celery; Cucumber; Garlic and onions; Potato; Pumpkin | |
|
- | |
|
Obsolete | |
|
circa 1955 |
UK regulatory status |
|
Not approved | ||
---|---|---|---|
|
Expired | ||
|
No UK approval for use |
EC Regulation 1107/2009 (repealing 91/414) |
|
Not approved | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
- | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
Expired | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
- | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
Yes | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
|
|
Also used in |
|
USA |
---|
Chemical structure |
|
- | |
---|---|---|
|
C₉H₅Cl₃N₄ | |
|
C1=CC=C(C(=C1)NC2=NC(=NC(=N2)Cl)Cl)Cl | |
|
No data | |
|
IMHBYKMAHXWHRP-UHFFFAOYSA-N | |
|
InChI=1S/C9H5Cl3N4/c10-5-3-1-2-4-6(5)13-9-15-7(11)14-8(12)16-9/h1-4H,(H,13,14,15,16) | |
|
Yes |
|
![]() |
Common Name | Relationship | Link |
---|---|---|
anilazine | - | ![]() |
General status |
|
Fungicide | |
---|---|---|
|
Triazine | |
|
- | |
|
- | |
|
Synthetic | |
|
Non-systemic with protective action, enzyme inhibitor. Multi-site activity. | |
|
101-05-3 | |
|
202-910-5 | |
|
294 | |
|
080811 | |
|
7541 | |
|
275.53 | |
|
4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazin-2-amine | |
|
4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazin-2-amine | |
|
4,6-dichloro-N-(2-chlorophenyl)-1,3,5-triazin-2-amine | |
|
- | |
|
- | |
|
Not applicable | |
|
Not applicable | |
|
Not applicable | |
|
M8 | |
|
- | |
|
White to light brown crystals |
Formulations |
|
|
|||
---|---|---|---|---|
|
|
|||
|
|
|||
|
- |
|
![]() |
|
|
|
|
||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
|
8 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
Low | ||||||||
|
90000 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Dichloromethane4 = Verified data |
- | ||||||||
1700 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) n-Hexane4 = Verified data |
- | |||||||||
40000 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Toluene4 = Verified data |
- | |||||||||
8000 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Isopropanol4 = Verified data |
- | |||||||||
|
159 | Q3 Q = Miscellaneous internet resources 3 = Unverified data of known source |
- | ||||||||
|
Decomposes before boiling | V3 V = ChemID online databases / IPCS INCHEM (ChemID; IPCS INCHEM ) 3 = Unverified data of known source |
- | ||||||||
|
- | - | - | ||||||||
|
Not expected to self ignite; Not highly flammable | V3 V = ChemID online databases / IPCS INCHEM (ChemID; IPCS INCHEM ) 3 = Unverified data of known source |
- | ||||||||
|
|
1.05 X 1003 | Calculated | - | |||||||
|
3.02 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
High | ||||||||
|
1.7 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
- | ||||||||
|
Not applicable | H4 H = The US ARS pesticide properties database (click here ) 4 = Verified data |
- | ||||||||
No dissociation | |||||||||||
|
8.20 X 10-04 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
Low volatility | ||||||||
|
1.10 X 10-04 | H4 H = The US ARS pesticide properties database (click here ) 4 = Verified data |
Non-volatile | ||||||||
|
- | - | - | ||||||||
|
- | - | - |
Degradation |
|
|
|
|
||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
|
- | ||||||||||
|
|
1 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
Non-persistent | |||||||
|
1 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 4 = Verified data |
Non-persistent | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
Lab studies (1) DT₅₀: 15 hours (2) DT₅₀: 34 hours | ||||||||||
|
|
- | - | - | |||||||
|
- | ||||||||||
|
|
- | - | - | |||||||
|
- | ||||||||||
|
|
180 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 4 = Verified data |
Stable | |||||||
|
- | ||||||||||
|
|
15 | K3 K = Research datasets, e.g. Pandora, Demetra 3 = Unverified data of known source |
Non-persistent | |||||||
|
- | ||||||||||
|
1 | K4 K = Research datasets, e.g. Pandora, Demetra 4 = Verified data |
Fast | ||||||||
|
1 | K4 K = Research datasets, e.g. Pandora, Demetra 4 = Verified data |
Moderately fast |
Soil adsorption and mobility |
|
|
|
|
||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
|
|
- | H3 H = The US ARS pesticide properties database (click here ) 3 = Unverified data of known source |
Slightly mobile | |||||||
|
2000 | ||||||||||
|
Best available data | ||||||||||
|
|
20.6 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
Slightly mobile | |||||||
|
1980 | ||||||||||
|
0.86 | ||||||||||
|
UK dossier Kf range 9.2-37.9 mL g⁻¹, Kfoc range 1438-2724 mL g⁻¹, 1/n - no data, Soils=4 | ||||||||||
|
No |
Fate indices |
|
|
|
|
||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
0.00 | Calculated | Low leachability | ||||||||||||||||||||||||||
|
|
1.39 X 10-04 | Calculated | - | |||||||||||||||||||||||||
|
- | ||||||||||||||||||||||||||||
|
Low | Calculated | - | ||||||||||||||||||||||||||
|
Slightly mobile | Calculated | - |
|
![]() |
|
|
|
|
||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
|
|
210 | P4 P = Other governments and regulators 4 = Verified data |
Threshold for concern | |||||||
|
Not available | - | |||||||||
|
4570 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Rat5 = Verified data used for regulatory purposes |
Low | ||||||||
|
|
42 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Rat5 = Verified data used for regulatory purposes |
High | |||||||
|
500 | - | |||||||||
|
- | - | - | ||||||||
|
> 2000 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Colinus virginianus5 = Verified data used for regulatory purposes |
Low | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
0.095 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Oncorhynchus mykiss5 = Verified data used for regulatory purposes |
High | ||||||||
|
- | - | - | ||||||||
|
0.56 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Daphnia magna5 = Verified data used for regulatory purposes |
Moderate | ||||||||
|
0.058 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Daphnia magna3 = Unverified data of known source |
Moderate | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
- | - | - | |||||||||
|
1.02 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Scenedemus subspicatus5 = Verified data used for regulatory purposes |
Moderate | ||||||||
|
1 | Q2 Q = Miscellaneous internet resources Unknown species2 = Unverified data of unknown source |
Moderate | ||||||||
|
|
- | - | - | |||||||
|
100 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
Moderate | ||||||||
|
- | - | - | ||||||||
|
|
- | - | - | |||||||
- | |||||||||||
|
- | - | - | ||||||||
- | |||||||||||
|
|
- | - | - | |||||||
|
- | - | - | ||||||||
|
|
- | - | - | |||||||
|
- | ||||||||||
|
|
- | - | - | |||||||
|
- | ||||||||||
|
1000 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 5 = Verified data used for regulatory purposes |
Moderate | ||||||||
|
- | - | - | ||||||||
|
|
2938 | B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Folsomia candida as LC₅₀4 = Verified data |
- | |||||||
|
- | - | - | ||||||||
|
|
1000 | LC₅₀ as mg kg⁻¹ soil B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Calathus fuscipes4 = Verified data |
- |
|
- | - | - | |||
|
|
- | - | - |
|
- | - | - | |||
|
Nitrogen mineralisation: Chronic effect Carbon mineralisation: No significant adverse effect |
B4 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) 4 = Verified data Dose: 100 mg kg⁻¹ soil |
- | ||||||||
|
|
- | - | - |
|
- | - | - |
|
![]() |
General |
|
|
|
|
||||||||
---|---|---|---|---|---|---|---|---|---|---|---|
|
High (class III) | - | - | ||||||||
|
4570 | B5 B = UK CRD and ACP evaluation documents / and other Defra (UK) documents (click here ) Rat5 = Verified data used for regulatory purposes |
Low | ||||||||
|
5000 | AC4 AC = EC Joint Research Centre ESIS European Chemical Substance Information Systems including EINECS, now integrated with the database provided by the European Chemicals Agency (ECHA) (click here ) Rat4 = Verified data |
- | ||||||||
|
0.25 | AC4 AC = EC Joint Research Centre ESIS European Chemical Substance Information Systems including EINECS, now integrated with the database provided by the European Chemicals Agency (ECHA) (click here ) Rat 4 hr4 = Verified data |
- | ||||||||
|
- | - | - | ||||||||
|
0.1 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) UK ACP 19995 = Verified data used for regulatory purposes |
- | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
- | - | - | ||||||||
|
[Since substance is no longer used as a fungicide in the most of the developed world consumer exposure is expected to be low] | - | - | ||||||||
|
|
Since substance is no longer used as a fungicide in the most of the developed world occupational exposure is expected to be low | |||||||||
|
- | ||||||||||
|
|
||||||||||
|
- | - | - | ||||||||
|
- | - | - |
Health issues |
|
|
||||||||||||||||||||||||||||
---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
|
Toxic by inhalation, skin absorption, and/or ingestion |
Handling issues |
|
|
|||
---|---|---|---|---|
|
Incompatible with oils and alkaline materials | |||
|
Health: H315, H319 Environment: H400, H410 |
|||
|
Xi - Irritant: R36/38 N - Dangerous for the environment: R50, R53 |
|||
|
S2, S22, S60, S61 | |||
|
O (Obsolete substance) | |||
|
- | |||
|
- |
|
![]() |
|
|
||
---|---|---|---|
|
anilazine | ||
|
anilazine | ||
|
Anilazin | ||
|
anilazin | ||
|
anilazina | ||
|
anilazina | ||
|
anilazine | ||
|
anilazyna | ||
|
- | ||
|
- | ||
|
anilazine |
Record last updated: | 29/12/2020 |
Contact: | aeru@herts.ac.uk |
Please cite as: | Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242 |