Oxycarboxin (Ref: F 461) |
![]() Last updated: 25/02/2021 |
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(Also known as: oxycarboxine; carboxin sulfone; plantvax; carboxin M06) |
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A fungicide for the control of fungal diseases on ornamentals, cereals, nursery trees and turf. Also a pesticide transformation product. | |
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Rusts; Fairy rings | |
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Ornamentals; Cereals; Nursery trees; Turf; Vegetables | |
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- | |
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Current | |
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1966, first reported |
UK regulatory status |
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Not approved | ||
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Expired | ||
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No UK approval for use |
EC Regulation 1107/2009 (repealing 91/414) |
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Not approved | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Not applicable | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Expired | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Yes | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Also used in |
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Australia |
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Chemical structure |
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None | |
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C₁₂H₁₃NO₄S | |
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CC1=C(S(=O)(=O)CCO1)C(=O)NC2=CC=CC=C2 | |
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No data | |
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AMEKQAFGQBKLKX-UHFFFAOYSA-N | |
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InChI=1S/C12H13NO4S/c1-9-11(18(15,16)8-7-17-9)12(14)13-10-5-3-2-4-6-10/h2-6H,7-8H2,1H3,(H,13,14) | |
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Yes |
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Common Name | Relationship | Link |
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oxycarboxin | - | ![]() |
General status |
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Fungicide, Metabolite | |
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Soil, Water, Groundwater | |
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Oxathiin | |
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- | |
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- | |
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Synthetic | |
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Systemic with curative action. Inhibition of nucleic acid synthesis. Succinate DeHydrogenase Inhibitor. | |
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5259-88-1 | |
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226-066-2 | |
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274 | |
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090202 | |
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21330 | |
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267.31 | |
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- | |
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2,3-dihydro-6-methyl-5-phenylcarbamoyl-1,4-oxathiine 4,4-dioxide | |
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5,6-dihydro-2-methyl-N-phenyl-1,4-oxathiin-3-carboxamide 4,4-dioxide | |
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PAN listed Highly Hazardous Chemical | |
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- | |
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Not applicable | |
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Not applicable | |
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Not applicable | |
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7 | |
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- | |
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White solid | |
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Can be a metabolite of: |
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carboxin | Soil | 0.170 | Major, Relevant |
Formulations |
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Usually supplied as an emulsifiable concentrate or wettable powder. |
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1400 | H4 H = The US ARS pesticide properties database (click here ) 4 = Verified data |
High | ||||||||
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83700 | L3 L = Pesticide manuals and hard copy reference books / other sources Acetone3 = Unverified data of known source |
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8.8 | L3 L = Pesticide manuals and hard copy reference books / other sources Hexane3 = Unverified data of known source |
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120.5 | L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source |
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5.92 X 1000 | Calculated | - | |||||||
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0.772 | H4 H = The US ARS pesticide properties database (click here ) 4 = Verified data |
Low | ||||||||
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1.41 | L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source |
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5.60 X 10-03 | L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source |
Low volatility | ||||||||
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1.07 X 10-06 | L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source |
Non-volatile | ||||||||
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Degradation |
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18 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 4 = Verified data |
Non-persistent | |||||||
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21.2 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Non-persistent | ||||||||
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42.3 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Moderately persistent | ||||||||
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70.4 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Moderately persistent | ||||||||
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140 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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EU dossier lab studies DT₅₀ range 101-27.4 days, DT₉₀ range 33.6-91.0 days; field studies DT₅₀ range 34.6-49.2 days, DT₉₀ range 115-163c days | ||||||||||
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9.8 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Non-persistent | |||||||
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Stable at pH 5, DT₅₀ 3.4 hours at pH 9 | ||||||||||
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1000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Stable | ||||||||
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1000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Stable |
Soil adsorption and mobility |
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0.66 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Mobile | |||||||
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65 | ||||||||||
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0.847 | ||||||||||
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EU dossier Kf range 0.26-1.64 mL g⁻¹, Kfoc range 33.139 mL g⁻¹, 1/n range 0.683-0.932, Soils=8 | ||||||||||
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Fate indices |
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3.56 | Calculated | High leachability | ||||||||||||||||||||||||||
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5.96 X 10-01 | Calculated | - | |||||||||||||||||||||||||
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Low | Calculated | - | ||||||||||||||||||||||||||
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Mobile | Calculated | - |
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0.9 | Q2 Q = Miscellaneous internet resources Estimated2 = Unverified data of unknown source |
Low potential | |||||||
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Not available | - | |||||||||
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1632 | L3 L = Pesticide manuals and hard copy reference books / other sources Rat3 = Unverified data of known source |
Moderate | ||||||||
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15 | L2 L = Pesticide manuals and hard copy reference books / other sources Rat 2 year2 = Unverified data of unknown source |
High | |||||||
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1250 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Anas platyrhynchos5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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19.9 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Oncorhynchus mykiss5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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69.1 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Daphnia magna5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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0.46 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Pseudokirchneriella subcapitata5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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181 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Low | |||||||
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General |
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High (class III) | - | - | ||||||||
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1632 | L3 L = Pesticide manuals and hard copy reference books / other sources Rat3 = Unverified data of known source |
Moderate | ||||||||
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5000 | L3 L = Pesticide manuals and hard copy reference books / other sources Rabbit3 = Unverified data of known source |
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> 5.0 | L3 L = Pesticide manuals and hard copy reference books / other sources Rat3 = Unverified data of known source |
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0.15 | L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source |
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Health issues |
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Harmful if swallowed |
Handling issues |
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Prevent generation of dust | |||
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Health: H302 Environment: H412 |
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Xn - Harmful: R22 N - Dangerous for the environment: R52, R53 |
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S2, S61 | |||
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III (Slightly hazardous) | |||
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oxycarboxin | ||
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oxycarboxine | ||
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Oxycarboxin | ||
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oxycarboxin | ||
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ossicarbossina | ||
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oxicarboxin | ||
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oksykarboksyna | ||
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oxycarboxine |
Record last updated: | 25/02/2021 |
Contact: | aeru@herts.ac.uk |
Please cite as: | Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242 |