bendiocarb (Ref: NC 6897) ** bendiocarbe ** bencarbate ** Translations

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SUMMARY

Bendiocarb is a carbamate insecticide and veterinary treatment that does not have EU regulatory approval for use. It has a moderate aqueous solubility, moderate volatility, is moderately mobile but, based on its chemical properties, would not be expected to leach to groundwater. It is highly toxic to mammals but tends not to bioaccumulate. It has a moderate to high toxicity for most aquatic organisms. It is highly toxic to birds and honey so but slightly less to earthworms.

GENERAL INFORMATION
for bendiocarb

Description: A carbamate insecticide with a wide range of uses including storage, soil-dwelling and some foliar pests. Also has some veterinary applications.

Example pests controlled: Beetles; Aphids; Mites; caterpillars; Spiders; Wasps; Ants; Flies

Example applications: Non-cropped areas including paths, railroads; Residences and commercial buildings; Turf; Ornamentals

Availability status: Current

Introduction & key dates: 1971

EC Regulation 1107/2009 (repealing 91/414):

Status	Not approved
Dossier rapporteur/co-rapporteur	-
Date inclusion expires	Expired

Approved for use () or known to be used () in the following European countries:

AT

BE

BG

CY

CZ

DE

DK

EE

EL

ES

FI

FR

HR

HU

IE

IT

LT

LU

LV

MT

NL

PL

PT

RO

SE

SI

SK

UK

Also used in: Australia, USA

General status:

Pesticide type	Insecticide, Veterinary substance
Substance group	Carbamate
Minimum active substance purity	-
Known relevant impurities	-
Substance origin	Synthetic
Mode of action	Systemic, with contact and stomach action resulting in rapid knock-down. Acetylcholinesterase (AChE) inhibitor.
CAS RN	22781-23-3
EC number	245-216-8
CIPAC number	232
US EPA chemical code	105201
Chiral molecule	No
Chemical formula	C11H13NO4
SMILES	O=C(Oc1cccc2OC(Oc12)(C)C)NC
International Chemical Identifier key (InChIKey)	XEGGRYVFLWGFHI-UHFFFAOYSA-N
International Chemical Identifier (InChI)	InChI=1S/C11H13NO4/c1-11(2)15-8-6-4-5-7(9(8)16-11)14-10(13)12-3/h4-6H,1-3H3,(H,12,13)
Structure diagram/image available?	Yes
Molecular mass (g mol-1)	223.23
PIN (Preferred Identification Name)	2,2-dimethyl-2H-1,3-benzodioxol-4-yl methylcarbamate
IUPAC name	2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate
CAS name	2,2-dimethyl-1,3-benzodioxol-4-yl methylcarbamate
Other status information	Marine Pollutant
Herbicide Resistance Classification (HRAC)	Not applicable
Herbicide Resistance Classification (WSSA)	Not applicable
Insecticide Resistance Classification (IRAC)	1A
Fungicide Resistance Classification (FRAC)	Not applicable
Examples of recorded resistance	Anopheles albimanus Aonidella aurantii Culex pipiens pipiens plus others
Physical state	White odoureless crystals
Related substances & organisms	-

Formulations:

Property	Value
Example manufacturers & suppliers of products using this active now or historically	Farnham Co Bayer Environmental Science FBC NOR-AM
Example products using this active	Multimet Sudoxin Tattoo Seedox Ficam Turcam Garvox
UK LERAP status	No UK approval for use or outside scope
Formulation and application details	Usually supplied in formulations for topical administration including impregnated collars .

ENVIRONMENTAL FATE
for bendiocarb

Property		Value	Source/Quality Score/Other Information	Interpretation
Solubility - In water at 20oC (mg l-1)		280	B4	Moderate
Solubility - In organic solvents at 20oC (mg l-1)		250	L2 - Dichlorobenzene	-
		175000	L2 - Acetone	-
		40000	L3 - Ethanol	-
		225	L3 - n-Hexane	-
Melting point (oC)		126.7	L3	-
Boiling point (oC)		Decomposes before boiling	V3	-
Degradation point (oC)		-	-	-
Flashpoint (oC)		Not expected to self ignite; Not highly flammable	V3	-
Octanol-water partition coefficient at pH 7, 20oC	P	5.01 X 1001	Calculated	-
	Log P	1.7	B4	Low
Bulk density (g ml-1)/Specific gravity		1.29	B5	-
Dissociation constant (pKa) at 25oC		8.8	DW4	-
		Note: Very weak acid
Vapour pressure at 25oC (mPa)		4.6	B5	Volatile
Henry's law constant at 25oC (Pa m3 mol-1)		4.00 X 10-03	H4	Non-volatile
Henry's law constant at 20oC (dimensionless)		1.50 X 10-06	K3	Moderately volatile
GUS leaching potential index		0.99	Calculated	Low leachability
SCI-GROW groundwater index (μg l-1) for a 1 kg ha-1 or 1 l ha-1 application rate	Value	3.84 X 10-03	Calculated	-
	Note	-
Potential for particle bound transport index		-	Calculated	Low
Maximum UV-vis absorption L mol-1 cm-1		-	-	-
Surface tension (mN m-1)		-	-	-

Degradation:

Property		Value	Source/Quality Score/Other Information	Interpretation
Soil degradation (days) (aerobic)	DT50 (typical)	3.5	H4	Non-persistent
	DT50 (lab at 20oC)	5.0	Q3	Non-persistent
	DT50 (field)	3.5	H4	Non-persistent
	DT90 (lab at 20oC)	-	-	-
	DT90 (field)	-	-	-
	Note	Literature values vary from a few days to a few weeks depending on soil type
Plant matrix DT50 (days)	Value	6.1	R4	-
	Note	DT50 range 3.6 - 18.3 days, 7 plants/crops, various matrices
Aqueous photolysis DT50 (days) at pH 7	Value	13	K4	Moderately fast
	Note	-
Aqueous hydrolysis DT50 (days) at 20oC and pH 7	Value	25	K4	Non-persistent
	Note	Hydrolysed rapidly in alkali media, slows under acid and neutral conditions
Water-sediment DT50 (days)		2	K4	Fast
Water phase only DT50 (days)		2	K4	Moderately fast

Soil adsorption and mobility:

Property		Value	Source/Quality Score/Other Information	Interpretation
Linear	Kd	-	H3	Moderately mobile
	Koc	385
	Notes and range	Other sources Koc 570 mL/g (DW3)
Freundlich	Kf	-	-	-
	Kfoc	-
	1/n	-
	Notes and range	-
pH sensitivity		-

Key metabolites:

Metabolite		Formation medium	Estimated maximum occurrence fraction	91/414 relevancy
2,2-dimethyl-1,3-benzodioxol-4-ol (Ref: NC-7312)		Soil		-

ECOTOXICOLOGY
for bendiocarb

Property		Value	Source/Quality Score/Other Information	Interpretation
Bio-concentration factor	BCF (l kg-1)	64.8	E3 Lepomis macrochirus	Low potential
	CT50 (days)	Not available		-
Mammals - Acute oral LD50 (mg kg-1)		34	B3 Rat	High
Mammals - Short term dietary NOEL	(mg kg-1)	0.75	B3 Rat	High
	(ppm diet)	-		-
Birds - Acute LD50 (mg kg-1)		> 3.1	L3 Anas platyrhynchos	High
Birds - Short term dietary (LC50/LD50)		-	-	-
Fish - Acute 96 hour LC50 (mg l-1)		> 1.55	L3 Oncorhynchus mykiss	Moderate
Fish - Chronic 21 day NOEC (mg l-1)		-	-	-
Aquatic invertebrates - Acute 48 hour EC50 (mg l-1)		0.03	J4 Daphnia magna	High
Aquatic invertebrates - Chronic 21 day NOEC (mg l-1)		-	-	-
Aquatic crustaceans - Acute 96 hour LC50 (mg l-1)		0.006	F3 Americamysis bahia	High
Sediment dwelling organisms - Acute 96 hour LC50 (mg l-1)		-	-	-
Sediment dwelling organisms - Chronic 28 day NOEC, static, water (mg l-1)		-	-	-
Sediment dwelling organisms - Chronic 28 day NOEC, sediment (mg kg-1)		-	-	-
Aquatic plants - Acute 7 day EC50, biomass (mg l-1)		-	-	-
Non-target plants		-	-	-
		-	-	-
Algae - Acute 72 hour EC50, growth (mg l-1)		> 1.71	K3 Unknown species	Moderate
Algae - Chronic 96 hour NOEC, growth (mg l-1)		0.32	Q2 Unknown species	Moderate
Honeybees	Contact acute 48 hour LD50 (μg bee-1)	-	-	-
	Oral acute 48 hour LD50 (μg bee-1)	> 0.1	E4	High
	Unknown mode acute 48 hour LD50 (μg bee-1)	-	-	-
Earthworms - Acute 14 day LC50 (mg kg-1)		188	F4 Eisenia foetida	Moderate
Earthworms - Chronic 14 day NOEC, reproduction (mg kg-1)		-	-	-
Other soil macro-organisms - e.g. Collembola	LR50 / EC50 / NOEC / % Effect	-	-	-
Other arthropod (1)	LR50 g ha-1	-	-	-
	% Effect	-	-	-
Other arthropod (2)	LR50 g ha-1	-	-	-
	% Effect	-	-	-
Soil micro-organisms		-	-	-
Mesocosm study data	NOEAEC mg l-1	-	-	-
	NOEAEC mg l-1	-	-	-

HUMAN HEALTH AND PROTECTION
for bendiocarb

General:

Property		Value	Source/Quality Score/Other Information	Interpretation
Threshold of Toxicological Concern (Cramer Class)		High (class III)	-	-
Mammals - Acute oral LD50 (mg kg-1)		34	B3 Rat	High
Mammals - Dermal LD50 (mg kg-1 body weight)		566	L3 Rat	-
Mammals - Inhalation LC50 (mg l-1)		0.55	L3 Rat	-
Other Mammal toxicity endpoints		-		-
ADI - Acceptable Daily Intake (mg kg-1bw day-1)		0.004	UK ACP 2002	-
ARfD - Acute Reference Dose (mg kg-1bw day-1)		-	-	-
AOEL - Acceptable Operator Exposure Level - Systemic (mg kg-1bw day-1)		-	-	-
Dermal penetration studies (%)		-	-	-
Dangerous Substances Directive 76/464		-	-	-
Exposure Limits		-	-	-
Exposure Routes	Public	-
	Occupational	-
European MRLs		Click here for the EU MRL pesticide database
Drinking Water MAC (μg l-1)		-	-	-

Health issues:

Carcinogen	Mutagen	Endocrine disrupter	Reproduction / development effects	Cholinesterase inhibitor	Neurotoxicant
		-
Respiratory tract irritant	Skin irritant	Skin sensitiser	Eye irritant	Phototoxicant
-		-		-
General human health issues		May cause hepatic and renal diseases May cause respiratory problems

: Yes, known to cause a problem
: No, known not to cause a problem
: Possibly, status not identified
- : No data found

Handling issues:

Property		Value	Source/Quality Score/Other Information	Interpretation
General		No information available
CLP classification 2013		Health: H301, H331, H312 Environment: H400, H410
EC Risk Classification		T - Toxic: R23/25 Xn - Harmful: R21 N - Dangerous for the environment: R50, R53
EC Safety Classification		S1/2, S22, S45, S61, S36/37, S60
WHO Classification		II	-	Moderately hazardous
US EPA Classification (formulation)		II	-	Warning - Moderately toxic
UN Number		2757
Waste disposal & packaging		-

TRANSLATIONS
for bendiocarb

Language	Name
English	bendiocarb
French	bendiocarbe
German	Bendiocarb
Danish	bendiocarb
Italian	bendiocarb
Spanish	bendiocarb
Greek	bendiocarb
Slovenian	bendiokarb
Polish	bendiokarb
Swedish	-
Hungarian	-
Dutch	bendiocarb

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Record last updated: Saturday 13 August 2016
Contact: aeru@herts.ac.uk