Trifloxysulfuron-sodium is a post-emergence herbicide. It has a high aqueous solubility, is relatively volatile and, based on its chemical properties, is mobile and may leach to groundwater in some situations. It is moderately persistent in soil systems but is generally non-persistent in aquatic systems. It has a low mammalian toxicity and has a high potential to bioaccumulate. It is a skin and eye irritant. It is moderately toxic to birds, honeybees and earthworms but is less toxic to fish and daphnia. However, it is very toxic to aquatic plants and algae.
Data alerts
The following alerts are based on the data in the tables below. An absence of an alert does not imply the substance has no implications for human health, biodiversity or the environment but just that we do not have the data to form a judgement.
Environmental fate
Ecotoxicity
Human health
Environmental fate Moderate alert: Moderately persistent; GUS: Transition state; Drainflow: Moderately mobile; Potential for particle bound transport: Medium
Example manufacturers & suppliers of products using this active now or historically
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Example products using this active
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Formulation and application details
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ENVIRONMENTAL FATE
Property
Value
Source; quality score; and other information
Interpretation
Solubility - In water at 20 °C (mg l⁻¹)
25700
L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source
High
Solubility - In organic solvents at 20 °C (mg l⁻¹)
17000
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Acetone
-
3800
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Ethyl acetate
-
50000
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Methanol
-
1.0
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Toluene
-
Melting point (°C)
174
L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source
-
Boiling point (°C)
-
-
-
Degradation point (°C)
-
-
-
Flashpoint (°C)
-
-
-
Octanol-water partition coefficient at pH 7, 20 °C
P
3.80 X 10-01
Calculated
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Log P
-0.42
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Low
Fat solubility of residues
Solubility
-
-
-
Data type
-
-
-
Density (g ml⁻¹)
0.645
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
-
Dissociation constant pKa) at 25 °C
4.76
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
-
Weak acid
Vapour pressure at 20 °C (mPa)
0.001
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Low volatility
Henry's law constant at 25 °C (Pa m³ mol⁻¹)
2.6 X 10-05
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Non-volatile
Volatilisation as max % of applied dose lost
From plant surface
-
-
-
From soil surface
-
-
-
Maximum UV-vis absorption L mol⁻¹ cm⁻¹
-
-
-
Surface tension (mN m⁻¹)
-
-
-
Degradation
Property
Value
Source; quality score; and other information
Interpretation
General biodegradability
-
Soil degradation (days) (aerobic)
DT₅₀ (typical)
63.5
L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source
Moderately persistent
DT₅₀ (lab at 20 °C)
70
F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents / FAO data, IPCS INCHEM data (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source
Moderately persistent
DT₅₀ (field)
-
-
-
DT₉₀ (lab at 20 °C)
-
-
-
DT₉₀ (field)
-
-
-
DT₅₀ modelling endpoint
-
-
-
Note
Literature values DT₅₀ 45-80 days
Dissipation rate RL₅₀ (days) on plant matrix
Value
-
-
-
Note
-
Dissipation rate RL₅₀ (days) on and in plant matrix
Value
-
-
-
Note
-
Aqueous photolysis DT₅₀ (days) at pH 7
Value
18
P4 P = Other non-EU, UK or US Governments and Regulators 4 = Verified data
Slow
Note
-
Aqueous hydrolysis DT₅₀ (days) at 20 °C and pH 7
Value
20
L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source
Non-persistent
Note
-
Water-sediment DT₅₀ (days)
-
-
-
Water phase only DT₅₀ (days)
-
-
-
Sediment phase only DT₅₀ (days)
-
-
-
Air degradation
As this parameter is not normally measured directly, a surrogate measure is used: ‘Photochemical oxidative DT₅₀’. Where data is available, this can be found in the Fate Indices section below.
Decay in stored produce DT₅₀
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Soil adsorption and mobility
Property
Value
Source; quality score; and other information
Interpretation
Linear
Kd (mL g⁻¹)
-
L3 L = Pesticide manuals and hard copy reference books / other sources 3 = Unverified data of known source
Moderately mobile
Koc (mL g⁻¹)
306
Notes and range
General literature Koc range 29-584 mL g⁻¹; Other data source: 5000 mL g⁻¹ (US3)
Freundlich
Kf (mL g⁻¹)
-
-
-
Kfoc (mL g⁻¹)
-
1/n
-
Notes and range
-
pH sensitivity
-
Fate indices
Property
Value
Source; quality score; and other information
Interpretation
GUS leaching potential index
2.79
Calculated
Transition state
SCI-GROW groundwater index (μg l⁻¹) for a 1 kg ha⁻¹ or 1 l ha⁻¹ application rate
Value
2.38 X 10-01
Calculated
-
Note
-
Potential for particle bound transport index
Medium
Calculated
-
Potential for loss via drain flow
Moderately mobile
Calculated
-
Photochemical oxidative DT₅₀ (hrs) as indicator of long-range air transport risk
-
-
-
Bio-concentration factor
BCF (l kg⁻¹)
Low risk
Q3 Q = Miscellaneous data from online sources 3 = Unverified data of known source
Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242