Aldicarb sulfone |
![]() Last updated: 22/12/2020 |
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(Also known as: aldoxycarb; aldoxycarbe; sulfocarb; ENT AI3 29261 ; UC 21865; aldicarb sulfure) |
SUMMARY |
Aldoxycarb is an insecticide with out approval for use in the EU. It is highly soluble in water, volatile and, based on its chemical properties, has a tendency to leach to groundwater. It is not persistent in soil systems but may be stable in aquatic systems under certain conditions. Aldoxycarb is toxic to mammals, most aquatic life and earthworms. |
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An insecticide and nematicide which is the sulfone analogue of aldicarb, currently used outside the EU to control honey locust and gall midge amongst others. Can also be a pesticide transformation product | |
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Honey locust; Gall midge; Nematodes | |
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Cotton; Potatoes; Sugarbeet; Ornamentals | |
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Current | |
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1965 |
UK regulatory status |
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Not approved | ||
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Not applicable | ||
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No UK approval for use |
EC Regulation 1107/2009 (repealing 91/414) |
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Not approved | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Not applicable | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Not applicable | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Not applicable | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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No | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Also used in |
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Australia; USA |
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Chemical structure |
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C₇H₁₄N₂O₄S | |
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CC(C)(C=NOC(=O)NC)S(=O)(=O)C | |
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CC(C)(/C=N/OC(=O)NC)S(=O)(=O)C | |
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YRRKLBAKDXSTNC-UHFFFAOYSA-N | |
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InChI=1S/C7H14N2O4S/c1-7(2,14(4,11)12)5-9-13-6(10)8-3/h5H,1-4H3,(H,8,10)/b9-5+ | |
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Yes |
General status |
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Insecticide, Nematicide, Metabolite | |
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Soil | |
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Carbamate | |
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- | |
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Synthetic | |
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Systemic. Acetylcholinesterase (AChE) inhibitor. | |
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1646-88-4 | |
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216-710-0 | |
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None allocated | |
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110801 | |
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9570093 | |
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222.26 | |
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(5E)-7,7-dimethyl-8,8-dioxo-4-oxa-8?6-thia-2,5-diazanon-5-en-3-one | |
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(EZ)-2-mesyl-2-methylpropionaldehyde O-methylcarbamoyloxime | |
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2-methyl-2-(methylsulfonyl)propanal O-[(methylamino)carbonyl]oxime | |
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- | |
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- | |
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Not applicable | |
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Not applicable | |
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1A | |
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Not applicable | |
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- | |
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Crystalline powder with slightly sulphurous odour | |
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Can be a metabolite of: |
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aldicarb | Soil | 0.2 | Major fraction, Relevancy unknown |
Formulations |
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10000 | F4 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) 4 = Verified data |
High | ||||||||
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- | - | - | ||||||||
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141 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source |
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Not expected to self ignite; Not highly flammable | V3 V = ChemID online databases / IPCS INCHEM (ChemID; IPCS INCHEM ) 3 = Unverified data of known source |
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2.69 X 10-01 | Calculated | - | |||||||
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-0.57 | K3 K = Research datasets, e.g. Pandora, Demetra 3 = Unverified data of known source |
Low | ||||||||
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1.35 | Q3 Q = Miscellaneous internet resources 3 = Unverified data of known source |
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12 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source |
Highly volatile | ||||||||
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2.87 X 10-06 | Q3 Q = Miscellaneous internet resources 3 = Unverified data of known source |
Non-volatile | ||||||||
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Degradation |
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21 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source |
Non-persistent | |||||||
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20 | Q3 Q = Miscellaneous internet resources 3 = Unverified data of known source |
Non-persistent | ||||||||
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Reported DT₅₀ of 2-4 weeks | ||||||||||
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14.9 | R3 R = Peer reviewed scientific publications 3 = Unverified data of known source |
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Sugarbeet leaves, n=1 | ||||||||||
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Stable | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) 3 = Unverified data of known source |
Stable | |||||||
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Soil adsorption and mobility |
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- | F4 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) 4 = Verified data |
Very mobile | |||||||
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10 | ||||||||||
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Fate indices |
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3.90 | Calculated | High leachability | ||||||||||||||||||||||||||
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5.44 X 10-01 | Calculated | - | |||||||||||||||||||||||||
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Low | Calculated | - | ||||||||||||||||||||||||||
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Very mobile | Calculated | - |
Other known metabolites |
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aldoxycarb oxime | - | Soil; Plant; Animal | - | - | |||||
aldoxycarb methylol | - | Plants | - | - |
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0.07 | Q2 Q = Miscellaneous internet resources Estimated2 = Unverified data of unknown source |
Low potential | |||||||
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Not available | - | |||||||||
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27 | Q4 Q = Miscellaneous internet resources Rat4 = Verified data |
High | ||||||||
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25.4 | F5 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Anas platyrhynchos5 = Verified data used for regulatory purposes |
High | ||||||||
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35.3 | F5 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Oncorhynchus mykiss5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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0.28 | F5 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Daphnia magna5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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> 50 | Q2 Q = Miscellaneous internet resources 2 = Unverified data of unknown source |
Moderate | |||||||
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0.236 | R4 R = Peer reviewed scientific publications Megachile rotundata4 = Verified data |
High | |||||||
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Oral | ||||||||||
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1.698 | R4 R = Peer reviewed scientific publications Nomia melanderi4 = Verified data |
Moderate | |||||||
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Oral | ||||||||||
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0.163 | F4 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Allolobophora caliginosa4 = Verified data |
High | ||||||||
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General |
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High (class III) | - | - | ||||||||
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27 | Q4 Q = Miscellaneous internet resources Rat4 = Verified data |
High | ||||||||
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1000 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Rat3 = Unverified data of known source |
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0.209 | F3 F = U.S. EPA ECOTOX database / U.S. EPA pesticide fate database / Miscellaneous WHO documents (US EPA Databases Related to Pesticide Risk Assessment ) Rat3 = Unverified data of known source |
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Health issues |
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Highly toxic May cause headache, dizziness, weakness, ataxia, diarrhea, convulsions and death |
Handling issues |
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No information available | |||
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Handling: H225, GHS02, GHS07 Health: H312, H319, H332 | |||
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T+ - Very toxic: R26/28 T - Toxic: R24 |
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S28, S36/37, S45 | |||
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O (Obsolete substance) | |||
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aldicarb sulfone | ||
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aldoxycarbe | ||
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Aldoxycarb | ||
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aldoxycarb | ||
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aldoxycarb | ||
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aldoxicarb | ||
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aldoksykarb | ||
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Record last updated: | 22/12/2020 |
Contact: | aeru@herts.ac.uk |
Please cite as: | Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242 |