Asulam sodium (Ref: AE F102789) |
![]() Last updated: 30/12/2020 |
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(Also known as: asulam; HOE 102789; sodium asulam; RPA 4143636; Hoe 102789; AE C518360) |
SUMMARY |
Asulam sodium is a carbamate herbicide that is not approved for use in the EU. It is highly soluble in water, volatile with a low risk of leaching to groundwater. It is not persistent in soils but may be persistent in water especially under dark conditions. Although it is not highly toxic there is a risk of bioaccumulation. It is a skin, eye and respiratory system irritant and may cause undesirable effects on reproduction. Asulam sodium is moderately toxic to birds, most aquatic organisms, honeybees and earthworms. |
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A translocated carbamate herbicide for control of problematic weeds in cropped and non-cropped situations | |
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Docks; Bracken; Ragwort | |
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Moorland; Amenity vegetation; Forestry; Spinach; Ornamentals including bulb production | |
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Current | |
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1965 |
UK regulatory status |
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Not approved | ||
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Expired | ||
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No UK approval for use |
EC Regulation 1107/2009 (repealing 91/414) |
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Not approved | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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UK | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Expired | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Not applicable | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Yes | ||||||||||||||||||||||||||||||||||||||||||||||||||||||||
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Also used in |
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Australia |
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Chemical structure |
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C₈H₉N₂O₄SNa₂ | |
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COC(=O)[N-]S(=O)(=O)C1=CC=C(C=C1)N.[Na+] | |
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No data | |
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PEXLHWBDBQUUOG-UHFFFAOYSA-M | |
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InChI=1S/C8H10N2O4S.Na/c1-14-8(11)10-15(12,13)7-4-2-6(9)3-5-7;/h2-5H,9H2,1H3,(H,10,11);/q;+1 | |
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Yes |
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Common Name | Relationship | Link |
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asulam | Parent | ![]() |
General status |
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Herbicide | |
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Carbamate | |
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876 g kg⁻¹ as sodium salt | |
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EU dossier - None declared | |
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Synthetic | |
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Selective system action, absorbed by leaves, shoots and roots. Inhibition of dihydropterate synthase causing slow chlorosis. | |
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2302-17-2 | |
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218-953-8 | |
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240 | |
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106902 | |
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61292 | |
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253.23 | |
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sodium (4-aminobenzenesulfonyl)(methoxycarbonyl)azanide | |
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sodium methyl (EZ)-sulfanilylcarbonimidate | |
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methyl [(4-aminophenyl)sulfonyl]carbamate monosodium salt | |
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Chemical subject to PIC regulations; PAN Listed as Highly Hazardous Chemical | |
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I | |
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18 | |
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Not applicable | |
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Not applicable | |
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Colourless to white crystals | |
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Formulations |
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Often available as a soluble liquid concentrate that is mixed with water and used as a spray |
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962000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
High | ||||||||
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0.07 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) n-Heptane5 = Verified data used for regulatory purposes |
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98 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Xylene5 = Verified data used for regulatory purposes |
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117000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Methanol5 = Verified data used for regulatory purposes |
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1100 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Acetone5 = Verified data used for regulatory purposes |
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230 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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104 | Q3 Q = Miscellaneous internet resources 3 = Unverified data of known source |
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230 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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Not expected to self ignite; Not highly flammable | Q3 Q = Miscellaneous internet resources 3 = Unverified data of known source |
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1.41 X 1000 | Calculated | - | |||||||
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0.15 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Low | ||||||||
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1.53 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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1.29 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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Strong acid; pKa(2) 4.68 | |||||||||||
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5.00 X 10-04 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Low volatility | ||||||||
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1.31 X 10-10 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Non-volatile | ||||||||
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292nm = 2750 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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71.5 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) at 20°C 89.6%5 = Verified data used for regulatory purposes |
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Degradation |
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4.6 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Non-persistent | |||||||
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4.6 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Non-persistent | ||||||||
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356 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Persistent | ||||||||
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19.5 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Non-persistent | ||||||||
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1000 | A3 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 3 = Unverified data of known source |
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EU dossier 2006 lab studies DT₅₀ range 2.66-11.1 days, DT₉₀ range 8.0-37.2 days, Soils=12; Field studies, DT₅₀ & DT₉₀ > 365 days; Other studies: DT₅₀ 6-14 days | ||||||||||
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1 | A4 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 4 = Verified data |
Moderately fast | |||||||
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DT₅₀ 0.78 days at pH 4, 1.56 days at pH 9 | ||||||||||
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Stable | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Stable | |||||||
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Stable at pH 5 to pH 9 | ||||||||||
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72 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Moderately fast | ||||||||
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63 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Stable |
Soil adsorption and mobility |
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0.949 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
Mobile | |||||||
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25.4 | ||||||||||
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0.75 | ||||||||||
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EU dossier kf range 0.150-3.28 mL g⁻¹, Kfoc range 15.4-149.7 mL g⁻¹, 1/n range 0.66-0.87, Soils=10 | ||||||||||
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No |
Fate indices |
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6.62 | Calculated | High leachability | ||||||||||||||||||||||||||
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4.15 X 1001 | Calculated | - | |||||||||||||||||||||||||
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Low | Calculated | - | ||||||||||||||||||||||||||
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Mobile | Calculated | - |
Key metabolites |
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Soil | 0.139 | Major fraction, Relevant |
Other known metabolites |
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4-(N-methoxycarbonylsulphamoylacetic acid (Ref: AE 1388213) | malonyl-asulam | Plant | - | - | |||||
methyl ((4-acetamidophenyl)sulphonyl)carbamate | acetyl asulam | Animal; Plant; Soil | - | - | |||||
N-(4-sulpamoylphenyl)acetamide | acetyl-sulphanilamide | Rat; Hen (eggs); Soil | - | - | |||||
methyl(((4-formylamino)phenyl)sulfonyl)carbamate | formyl asulam | Plant | - | - | |||||
aminobenzenesulphonic acid | sulphanilic acid | Soil | - | - | |||||
N-(4-aminophenyl)formamide | AP Formamide | Water | - | - | |||||
(4-(4-methoxycarbonylaminophenyl)aminophenyl)carbamic acid | MCAPAP carbamic acid | Water | - | - | |||||
4-sulphamoylphenylcarbamoylacetic acid | malonyl sulphanilamide | Processing | - | - | |||||
methylphenylsulphonylcarbamate (Ref: MB022232) | desamino asulam; MBSC | Plant; Soil | - | - | |||||
benzenesulphonamide | - | Soil | - | - | |||||
benzenesulphonic acid | - | Soil | - | - | |||||
a-acetylbenzenesulphonamide | - | Plant | - | - |
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0.75 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Whole fish5 = Verified data used for regulatory purposes |
Low potential | |||||||
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Not available | - | |||||||||
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> 5000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
Low | ||||||||
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36 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
High | |||||||
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> 1826 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Colinus virginianus as asulam5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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> 91.3 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Lepomis macrochirus as asulam5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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119.1 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Oncorhynchus mykiss as asulam5 = Verified data used for regulatory purposes |
Low | ||||||||
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57.87 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Daphnia magna as asulam5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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6.4 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Daphnia magna as asulam5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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91.3 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Chironomus riparius as asulam5 = Verified data used for regulatory purposes |
Low | ||||||||
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0.27 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Lemna gibba as asulam5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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> 0.66 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Anabaena flos-aquae as asulam5 = Verified data used for regulatory purposes |
Moderate | ||||||||
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> 100 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) as asulam5 = Verified data used for regulatory purposes |
Low | |||||||
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> 123.7 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) as asulam5 = Verified data used for regulatory purposes |
Low | ||||||||
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1004 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Eisenia foetida as asulam5 = Verified data used for regulatory purposes |
Low | ||||||||
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180.7 | A2 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Eisenia foetida Reproduction as asulam2 = Unverified data of unknown source |
Low | ||||||||
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3.088 | 48 hour A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Aphidius rhopalosiphi as Asulox/ha5 = Verified data used for regulatory purposes |
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7.566 | 7 day A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Typhlodromus pyri as Asulox/ha5 = Verified data used for regulatory purposes |
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Nitrogen mineralisation: Up to -26% effect Carbon mineralisation: No significant adverse effect |
A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes Dose: 0.16 g asulam/kg soil 56 days |
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General |
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High (class III) | - | - | ||||||||
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> 5000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
Low | ||||||||
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2000 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
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> 5.46 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat5 = Verified data used for regulatory purposes |
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0.36 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Rat SF=1005 = Verified data used for regulatory purposes |
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1 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) Dog SF=1005 = Verified data used for regulatory purposes |
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0.046 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) 5 = Verified data used for regulatory purposes |
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0.5-3 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) concentration dependent5 = Verified data used for regulatory purposes |
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Low risk of dietary exposure and accidental exposure of residents or bystanders | |||||||||
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Risk of exposure acceptable under label recommendations for use for personal protection clothing and equipment | ||||||||||
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0.1 | A5 A = EU regulatory and evaluation data as published by EC, EFSA (RAR, DAR & Conclusion dossiers), EMA (e.g. EU Annex III PIC DGD) (EU - Pesticides database; EFSA Scientific Publications ) EU Dir 89/778/EC limit; Calc MAC=1080 µg l⁻¹5 = Verified data used for regulatory purposes |
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Health issues |
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Possible blood, thyroid and kidney toxicant |
Handling issues |
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Not explosive or oxidising | |||
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Health: H317 | |||
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Xn - Harmful: R43 N - Dangerous for the environment: R50, R53 |
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S24, S37, S35, S57, S60, S61 | |||
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U (Unlikely to present an acute hazard) | |||
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asulam sodium | ||
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asulame | ||
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Asulam | ||
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asulam | ||
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asulame | ||
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asulame | ||
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asulam sodowy | ||
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aszulam | ||
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asulam |
Record last updated: | 30/12/2020 |
Contact: | aeru@herts.ac.uk |
Please cite as: | Lewis, K.A., Tzilivakis, J., Warner, D. and Green, A. (2016) An international database for pesticide risk assessments and management. Human and Ecological Risk Assessment: An International Journal, 22(4), 1050-1064. DOI: 10.1080/10807039.2015.1133242 |